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For simplicity, the complex is expressed as BPTA-PDI/ATP throughout the text, which does not mean the exact ratio of the two components in the complex
-
For simplicity, the complex is expressed as BPTA-PDI/ATP throughout the text, which does not mean the exact ratio of the two components in the complex.
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1H NMR spectra of the BPTA-PDI/ATP complex (Figure S3) further support this conclusion. At room temperature, no well-resolved proton resonances originated from ATP and BPTA-PDI can be observed. With increasing temperature, the dissociation of the chiral BPTA-PDI/ATP superstructure yields considerable downfield shift of the aromatic protons (Ha and Hb protons in the PDI and the 8-H and 2-H protons in the adenine moiety) and the 1′-H proton in the D-ribose moiety by accompanying the sharpening of these peaks, indicating die significant contribution of π-π stacking between aromatic moieties.
-
1H NMR spectra of the BPTA-PDI/ATP complex (Figure S3) further support this conclusion. At room temperature, no well-resolved proton resonances originated from ATP and BPTA-PDI can be observed. With increasing temperature, the dissociation of the chiral BPTA-PDI/ATP superstructure yields considerable downfield shift of the aromatic protons (Ha and Hb protons in the PDI and the 8-H and 2-H protons in the adenine moiety) and the 1′-H proton in the D-ribose moiety by accompanying the sharpening of these peaks, indicating die significant contribution of π-π stacking between aromatic moieties.
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Powder X-ray diffraction analyses in the pristine solid state were performed to reveal further details of the structure of the BPTA-PDI/ATP complex, Figure S4 The reflection at 0.34 nm corresponds to the typical π-π stacking distance of the perylene moieties
-
Powder X-ray diffraction analyses in the pristine solid state were performed to reveal further details of the structure of the BPTA-PDI/ATP complex. (Figure S4) The reflection at 0.34 nm corresponds to the typical π-π stacking distance of the perylene moieties.
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