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The peaks at approximately 0.35 nm are most likely not single peaks, as can be seen from their asymmetric shape. It might indicate that the parts at larger angles indicate some correlation between different stacks.
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89
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Polarized optical microscopy did not yield any textures typical of chiral phases. Further efforts to identify lyotropic liquid-crystalline phases for complexes 4 and 5 in THF, CHCl3, DMF, DMSO, and NMP using a penetration scan technique were met without success.
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90
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14544290501
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The exact nature of the lamellar ordering (as indicated by the X-ray data) in the case of a dianionic surfactant-based system (complex 5) cannot be deduced from these data with absolute certainty. Complex polymeric structures would also be possible. For examples of the complexation of a dication with a tetra-anion to yield supramolecular polymeric fibers, please see: Guan, Y.; Yu, S.-H.; Antionietti, M.; Böttcher, C.; Faul, C. F. J. Chem.-Eur. J. 2005, 11, 1305-1311
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Accelrys Inc.: San Diego
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Cerius2, version 4.6; Accelrys Inc.: San Diego, 2001.
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Cerius2, Version 4.6
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