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Volumn 46, Issue 41, 2007, Pages 7782-7784

Interaction between d- and p-block metals: Synthesis and structure of platinum-alane adducts

Author keywords

Alanes; Aluminum; Coordination modes; Lewis bases; Platinum

Indexed keywords

ALUMINUM COMPOUNDS; CHEMICAL BONDS; METAL ANALYSIS; PLATINUM COMPOUNDS;

EID: 35348984066     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200702726     Document Type: Article
Times cited : (107)

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    • The crystal data of 2 were collected at a Bruker X8APEX diffractometer with a CCD area detector and multi-layer mirror monochromated MoKα radiation. The structure was solved using direct methods, refined with the SHELX software package (G. Sheldrick, University of Göttingen, 1997) and expanded using Fourier techniques. All non-hydrogen atoms were refined anisotropically. Hydrogen atoms were assigned idealized positions and were included in structure factor calculations. Crystal data for 2: C51H81AlCl 3P2Pt, Mr, 1084.52, colorless plates, 0.35 x 0.25 x 0.08 mm3, triclinic space group P1, a, 11.0306(5, b, 19.0585(9, c, 24.4351(12) Å, a, 86.181(2, β, 84.304(2, γ, 87.857(2)°, V, 5097.7(4) Å3, Z, 4, ρcalcd, 1.413 g cm -3, μ, 3.023
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.