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The crystal data of 2 were collected at a Bruker X8APEX diffractometer with a CCD area detector and multi-layer mirror monochromated MoKα radiation. The structure was solved using direct methods, refined with the SHELX software package (G. Sheldrick, University of Göttingen, 1997) and expanded using Fourier techniques. All non-hydrogen atoms were refined anisotropically. Hydrogen atoms were assigned idealized positions and were included in structure factor calculations. Crystal data for 2: C51H81AlCl 3P2Pt, Mr, 1084.52, colorless plates, 0.35 x 0.25 x 0.08 mm3, triclinic space group P1, a, 11.0306(5, b, 19.0585(9, c, 24.4351(12) Å, a, 86.181(2, β, 84.304(2, γ, 87.857(2)°, V, 5097.7(4) Å3, Z, 4, ρcalcd, 1.413 g cm -3, μ, 3.023
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48
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PC|; for details on the virtual coupling constant N see J. P. Fackler, Jr., J. A. Fetchin, J. Mayhew, W. C. Seidel, T. J. Swift, M. Weeks, J. Am. Chem. Soc. 1969, 91, 1941-1947.
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