Reactions of hydroborating reagents with phosphinorhodium hydride complexes: Molecular structures of a Rh2B3 metallaborane cluster, an L2Rh(η2-H2BR2) complex and a mixed valence Rh dimer containing a semi-bridging Bcat (cat=1,2-O2C6H4) group

Polyhedron

Volumn 23, Issue 17, 2004, Pages 2665-2677

  Westcott, Stephen A ^a   Marder, Todd B ^b   Baker, R Thomas ^c,d   Harlow, Richard L ^d   Calabrese, Joseph C ^d   Lam, King Chung ^e   Lin, Zhenyang ^e  

^a MOUNT ALLISON UNIVERSITY   (Canada)

^b DURHAM UNIVERSITY   (United Kingdom)

^c LOS ALAMOS NATIONAL LABORATORY   (United States)

^d DUPONT COMPANY   (United States)

^e HONG KONG UNIVERSITY OF SCIENCE AND TECHNOLOGY   (Hong Kong)

Author keywords

Bridging boryls; Catalyzed hydroborations; Rhodium hydrides

Indexed keywords

BORON COMPOUNDS; CATALYSIS; DIMERS; HYDRIDES; PHOSPHORUS COMPOUNDS; SINGLE CRYSTALS;

ALKYL GROUPS; BORON-CONTAINING; BRIDGING BORYLS; CATALYZED HYDROBORATION; DIMETHYLSULPHIDE; HYDRIDE COMPLEXES; HYDROBORATING REAGENT; HYDROBORATION; METALLABORANES; MIXED VALENCE;

RHODIUM COMPOUNDS;

1,2 BIS(DIISOPROPYLPHOSPHINO)ETHANE; AMPHOLYTE; AZELAIC ACID; BORANE DERIVATIVE; BORON; CARBON; DIMER; ETHANE; HYDROGEN; OXYGEN; REAGENT; RHODIUM; UNCLASSIFIED DRUG;

ADDITION REACTION; CATALYSIS; CLUSTER ANALYSIS; COMPLEX FORMATION; CONFERENCE PAPER; HYDROBORATION; MOLECULE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SUBSTITUTION REACTION; X RAY DIFFRACTION;

EID: 8644269538     PISSN: 02775387     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.poly.2004.05.012     Document Type: Conference Paper

References (75)

1. Burgess K., Ohlmeyer M.J. Chem. Rev. 91:1991;1179
2. Beletskaya I., Pelter A. Tetrahedron. 53:1997;4957
3. Crudden C.M., Edwards D. Eur. J. Org. Chem. 2003;4695. and references therein
4. Harrison K.N., Marks T.J. J. Am. Chem. Soc. 114:1992;9220
5. Kulkarni S.A., Koga N. Theochem. 461-462:1999;297
6. Muhoro C.N., He X., Hartwig J.F. J. Am. Chem. Soc. 121:1999;5033
7. Lantero D.R., Ward D.L., Smith III M.R. J. Am. Chem. Soc. 119:1997;9699
8. Desurmont G., Dalton S., Giolando D.M., Srebnik M. J. Org. Chem. 62:1997;8907
9. Pender M.J., Wideman T., Carroll P.J., Sneddon L.G. J. Am. Chem. Soc. 120:1998;9108
10. He X., Hartwig J.F. J. Am. Chem. Soc. 118:1996;1696
11. Muhoro C.N., Hartwig J.F. Organometallics. 19:2000;30
12. Kono H., Ito K., Nagai Y. Chem. Lett. 1975;1095
13. Männig D., Nöth H. Angew. Chem., Int. Ed. Eng. 24:1985;878
14. Dorigo A.E., von R. Schleyer P. Angew. Chem., Int. Ed. Engl. 34:1995;115
15. Burgess K., van der Donk W.A., Westcott S.A., Marder T.B., Baker R.T., Calabrese J.C. J. Am. Chem. Soc. 114:1992;9350
16. Brown J.M., Lloyd-Jones G.C. J. Chem. Soc., Chem. Commun. 1992;710
17. Musaev D.G., Mebel A.M., Morokuma K. J. Am. Chem. Soc. 116:1994;10693
18. Westcott S.A., Marder T.B., Baker R.T. Organometallics. 12:1993;975
19. Westcott S.A., Blom H.P., Marder T.B., Baker R.T. J. Am. Chem. Soc. 114:1992;8863
20. Coapes R.B., Souza F.E.S., Thomas R.L., Hall J.J., Marder T.B. Chem. Commun. 2003;614
21. Huang X., Lin Z. Maseras F., Lledos A. Computational Modelling of Homogeneous Catalysis. 2002;189-212 Kluwer Academic Publishers, Amsterdam
22. Widauer C., Grützmacher H., Ziegler T. Organometallics. 19:2000;209
23. Fryzuk M.D., Piers W.E. Organomet. Synth. 3:1986;128
24. Fryzuk M.D., Jones T., Einstein F.W.B. Organometallics. 3:1984;185
25. Busetto C., D'Alfonso A., Maspero F., Perego G., Zazetta A. J. Chem. Soc., Dalton Trans. 1977;1828
26. Sheldrick G.M. SHELX. 1986;University of Gottingen, Gottingen, Germany
27. Cromer D.T., Ibers J.A. International Tables for X-ray Crystallography. vol. IV:1974;Kynoch Press, Birmingham, England. Table 2.3.2
28. Cromer D.T., Waber J.T. International Tables for X-ray Crystallography. vol. IV:1974;Kynoch Press, Birmingham, England. Table 2.2B
29. Becke A.D. Phys. Rev. A. 38:1988;3098
30. Miehlich B., Savin A., Stoll H., Preuss H. Chem. Phys. Lett. 157:1989;200
31. Lee C., Yang W., Parr G. Phys. Rev. B. 37:1988;785
32. Hay P.J., Wadt W.R. J. Chem. Phys. 82:1985;299
33. Gordon M.S. Chem. Phys. Lett. 76:1980;163
34. Hariharan P.C., Pople J.A. Theoret. Chim. Acta. 28:1997;213
35. Binning R.C. Jr., Curtiss L.A. J. Comput. Chem. 11:1990;1206
36. Huzinaga S. Gaussian Basis Sets for Molecular Calculations. 1984;Elsevier, Amsterdam
37. Frisch M.J., Trucks G.W., Schlegel H.B., Scuseria G.E., Robb M.A., Cheeseman J.R., Zakrzewski V.G., Montgomery J.A. Jr., Stratmann R.E., Burant J.C., Dapprich S., Millam J.M., Daniels A.D., Kudin K.N., Strain M.C., Farkas O., Tomasi J., Barone V., Cossi M., Cammi R., Mennucci B., Pomelli C., Adamo C., Clifford S., Ochterski J., Petersson G.A., Ayala P.Y., Cui Q., Morokuma K., Malick D.K., Rabuck A.D., Raghavachari K., Foresman J.B., Cioslowski J., Ortiz J.V., Stefanov B.B., Liu G., Liashenko A., Piskorz P., Komaromi I., Gomperts R., Martin R.L., Fox D.J., Keith T., Al-Laham M.A., Peng C.Y., Nanayakkara A., Gonzalez C., Challacombe M., Gill P.M.W., Johnson B., Chen W., Wong M.W., Andres J.L., Gonzalez C., Head-Gordon M., Replogle E.S., Pople J.A. GAUSSIAN-98 (Revision A.9). 1998;Gaussian, Inc., Pittsburgh, PA
38. Interactive MOPLOT: a package for the interactive display and analysis of molecular wave functions, incorporating the programs MOPLOT (D. Lichtenberger), PLOTDEN (R.F.W. Bader, D.J. Kenworthy, P.M. Beddal, G.R. Runtz, S.G. Anderson), SCHUSS (R.F.W. Bader, G.R. Runtz, S.G. Anderson, F.W. Biegler-Koenig) and EXTREM (R.F.W. Bader, F.W. Bieger-Koenig) by P. Sherwood and P.J. MacDougall, 1989
39. Schaftenaar G. MOLDEN v3.7: CAOS/CAMM Center Nijmegen. 2001;Toernooiveld, Nijmegen, Netherlands
40. Baker R.T., Ovenall D.W., Calabrese J.C., Westcott S.A., Taylor N.J., Williams I.D., Marder T.B. J. Am. Chem. Soc. 112:1990;9399
41. Westcott S.A., Blom H.P., Marder T.B., Baker R.T., Calabrese J.C. Inorg. Chem. 32:1993;2175
42. Lei X., Shang M., Fehlner T.P. J. Am. Chem. Soc. 115:1998;4908
43. Fehlner T.P. Liebman J.F., Greenberg A., Williams R.E. Advances in Boron and the Boranes. 1988;265 VCH Publishers, New York. (Chapter 12)
44. Grebenik P.D., Green M.L.H., Kelland M.A., Leach J.B., Mountford P. J. Chem. Soc., Chem. Commun. 1989;1397
45. Grebenik P.D., Green M.L.H., Kelland M.A., Leach J.B., Mountford P. J. Chem. Soc., Chem. Commun. 1990;1234
46. Wade K. Adv. Inorg. Radiochem. 18:1976;1
47. Baker R.T., Ovenall D.W., Harlow R.L., Westcott S.A., Taylor N.J., Marder T.B. Organometallics. 9:1990;3028
48. Fryzuk M.D., Piers W.E., Einstein F.W.B., Jones T. Can. J. Chem. 67:1989;883
49. 2): Gilbert T.M., Hollander F.J., Bergman R.G. J. Am. Chem. Soc. 107:1985;3508
50. 2): Carreno R., Ruiz M.A., Jeannin Y., Philoche-Levisalles M. J. Chem. Soc., Chem. Commun. 1990;15
51. 2)]: Carreno R., Riera V., Ruiz M., Bois C., Jeannin Y. Organometallics. 12:1993;1946
52. Marks T.J., Kolb J.R. Chem. Rev. 77:1977;263
53. Bulky phosphine ligands can be used to stabilize certain tetrahydroborate complexes of Rh, Ru and Ir, see: Letts J.B., Mazanec T.J., Meek D.W. J. Am. Chem. Soc. 104:1982;3898. and references therein
54. 12)]: Rifat A., Laing V.E., Kociok-Köhn G., Mahon M.F., Ruggiero G.D., Weller A.S. J. Organomet. Chem. 680:2003;127
55. 3): Essalah K., Barthelat J.-C., Montiel V., Lachaize S., Donnadieu B., Chaudret B., Sabo-Etienne S. J. Organomet. Chem. 680:2003;182
56. 10] Long J.A., Marder T.B., Hawthorne M.F. J. Am. Chem. Soc. 106:1984;3004
57. Smith III M.R. Prog. Inorg. Chem. 48:1999;505
58. Lam W.H., Shimada S., Batsanov A.S., Lin Z., Marder T.B., Cowan J.A., Howard J.A.K., Mason S.A., McIntyre G.J. Organometallics. 22:2003;4557
59. Curtis D., Lesley M.J.G., Norman N.C., Orpen A.G., Starbuck J. J. Chem. Soc., Dalton Trans. 1999;1687
60. Korostylev A., Gridnev I., Brown J.M. J. Organomet. Chem. 680:2003;329
61. Muir K.W., Ibers J.A. Inorg. Chem. 8:1969;1921
62. Bader R.F.W. Atoms in Molecules: A Quantum Theory. 1990;Oxford University Press, Oxford
63. Lam K.C., Lam W.H., Lin Z., Marder T.B., Norman N.C. Inorg. Chem. 43:2004;2541
64. For recent reviews see: Hartwig J.F., Waltz K.M., Muhoro C.N., He X., Eisenstein O., Bosque R., Maseras F. Siebert W. Advances of Boron Chemistry, Special Publication No. 201. 1997;373-396 Royal Society of Chemistry, Cambridge, UK
65. Wadepohl H. Angew. Chem., Int. Ed. Engl. 36:1997;2441
66. Irvine G.J., Lesley M.L.G., Marder T.B., Norman N.C., Rice C.R., Robins E.G., Roper W.R., Whittell G.R., Wright L.J. Chem. Rev. 98:1998;2685
67. Braunschweig H. Angew. Chem., Int. Ed. Engl. 37:1998;1786
68. Braunschweig H., Colling M. Coord. Chem. Rev. 223:2001;1
69. Webster C.E., Fan Y.B., Hall M.B., Kunz D., Hartwig J.F. J. Am. Chem. Soc. 125:2003;858
70. Dai C.Y., Robins E.G., Scott A.J., Clegg W., Yufit D.S., Howard J.A.K., Marder T.B. Chem. Commun. 1998;1983
71. Westcott S.A., Taylor N.J., Marder T.B., Baker R.T., Jones N.J., Calabrese J.C. J. Chem. Soc., Chem. Commun. 1991;304
72. C.Y. Dai, A.J. Scott, W. Clegg, A.K. Hughes, M.A. Fox, T.B. Marder, unpublished results
73. Nolte M.J., Gafner G. Acta Crystallogr., Sect. B. 30:1974;738
74. Albano P., Aresta M., Manassero M. Inorg. Chem. 19:1980;1069
75. Männig D., Nöth H. J. Chem. Soc., Dalton Trans. 1985;1689