Acetonitrile hydration and ethyl acetate hydrolysis by pyrazolate-bridged cobalt(II) dimers containing hydrogen-bond donors

Inorganic Chemistry

Volumn 46, Issue 24, 2007, Pages 10120-10132

  Zinn, Paul J ^a   Sorrell, Thomas N ^b   Powell, Douglas R ^a   Day, Victor W ^a   Borovik, A S ^a,c  

^a UNIVERSITY OF KANSAS   (United States)

^b University of North Carolina at Chapel Hill   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETIC ACID DERIVATIVE; ACETIC ACID ETHYL ESTER; ACETONITRILE; ACETONITRILE DERIVATIVE; COBALT; ORGANOMETALLIC COMPOUND; PYRAZOLE DERIVATIVE;

ARTICLE; CHEMICAL STRUCTURE; CHEMISTRY; HYDROGEN BOND; HYDROLYSIS;

ACETATES; ACETONITRILES; COBALT; HYDROGEN BONDING; HYDROLYSIS; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; PYRAZOLES;

EID: 37249078130     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic700685g     Document Type: Article

References (62)

1. Kukushkin, V. Y.; Pombeiro, A. J. L. Inorg. Chim. Acta 2005, 358, 1-21 and references cited therein.
2. (a) Parkins, A. W. Platinum Met. Rev. 1996, 40, 169-174 and references cited therein.
3. (b) Ghaffar, T.; Parkins, A. W. J. Mol. Catal. A: Chem. 2000, 160, 249-261.
4. (c) Murahashi, S.-I.; Takaya, H. Acc. Chem. Res. 2000, 33, 225-233.
5. II metal salts have been used: (a) Clarke, C. R.; Hay, R. W. Dalton Trans. 1974, 2148-2152.
6. (b) Segl'a, P.; Jamnicky, M.; Koman, M.; Sima, J.; Glowiak, T. Polyhedron 1998, 17, 4525-4533.
7. (c) Kopylovich, M. N.; Kukushkin, V. Y.; Guedes da Silva, M. F. C.; Haukka, M.; Fraústo da Silva, J. J. R.; Pombeiro, A. J. L. J. Chem. Soc., Perkin Trans. 1 2001, 1569-1573.
8. (a) Sträter, N.; Lipscomb, W. N.; Klabunde, T.; Krebs, B. Angew. Chem., Int. Ed. Engl. 1996, 35, 2024-2055.
9. (b) Wilcox, D. E. Chem. Rev. 1996, 96, 2435-2458.
10. (a) Vobeda, A.; Lahm, A.; Sakiyama, F.; Suck, D. EMBO J. 1991, 10, 1607-1618.
11. (b) Chevrier, B.; Schalk, C.; D'Orchymont, H.; Rondeau, J.-M.; Moras, D.; Tarnus, C. Structure 1994, 2, 283-291.
12. (c) Romier, C.; Dominguez, R.; Lahm, A.; Dahl, O.; Suck, D. Proteins 1998, 32, 414-424.
13. (d) Desmarais, W. T.; Bienvenue, D. L.; Bzymek, K. P.; Holz, R. C.; Petsko, G. A.; Ringe, D. Structure 2002, 10, 1063-1072.
14. (e) Bzymek, K. P.; Moulin, A.; Swierczek, S. I.; Ringe, D.; Petsko, G. A.; Bennett, B.; Holz, R. C. Biochemistry 2005, 44, 12030-12040.
15. (f) Bzymek, K. P.; Swierczek, S. I.; Bennett, B.; Holz, R. C. Inorg. Chem. 2005, 44, 8574-8580.
16. For recent examples, see: (a) Wada, A.; Harata, M.; Hasegawa, K.; Jitsukawa, K.; Masuda, H.; Mukai, M.; Kitagawa, T.; Einaga, H. Angew. Chem., Int. Ed. 1998, 37, 798-799.
17. (b) Matsu-ura, M.; Tani, F.; Nakayama, S.; Nakamura, N.; Naruta, Y. Angew. Chem., Int. Ed. 2000, 39, 1989-1991.
18. (c) Grotjahn, D. B.; Incarvito, C. D.; Rheingold, A. L. Angew. Chem., Int. Ed. 2001, 40, 3884-3887.
19. (d) Garner, D. K.; Fitch, S. B.; McAlexander, L. H.; Bezold, L. M.; Arif, A. M.; Berreau, L. M. J. Am. Chem. Soc. 2002, 124, 9970-9971.
20. (e) Chang, C. J.; Chng, L. L.; Nocera, D. G. J. Am. Chem. Soc. 2003, 125, 1866-1876.
21. (f) Rivera, G.; Crabtree, R. H. J. Mol. Catal. A: Chem. 2004, 222, 59-73.
22. Dinuclear complex: Allred, R. A.; Doyle, K.; Arif, A. M.; Berreau, L. M. Inorg. Chem. 2006, 45, 4097-4108.
23. Mononuclear complexes: (a) Kövári, E.; Krämer, R. J. Am. Chem. Soc. 1996, 118, 12704-12709.
24. (b) Krämer, R. Coord. Chem. Rev. 1999, 182, 243-261.
25. (c) Wall, M.; Linkletter, B.; Williams, D.; Lebuis, A.-M.; Hynes, R. C.; Chin, J. J. Am. Chem. Soc. 1999, 121, 4710-4711.
26. (d) Forconi, M.; Williams, N. H. Angew. Chem., Int. Ed. 2002, 41, 849-852.
27. (e) Ait-Haddou, H.; Sumaoka, J.; Wiskur, S. L.; Folmer-Andersen, J. F.; Anslyn, E. V. Angew. Chem., Int. Ed. 2002, 41, 4014-4016.
28. (f) Livieri, M.; Mancin, F.; Tonellato, U.; Chin, J. Chem. Commun. 2004, 24, 2862-2863.
29. (g) Feng, G.; Mareque-Rivas, J. C.; Martin de Rosales, R. T.; Williams, N. H. J. Am. Chem. Soc. 2005, 127, 13470-13471.
30. Feng, G.; Mareque-Rivas, J. C.; Williams, N. H. Chem. Commun. 2006, 1845-1847.
31. (a) Hammes, B. S.; Young, V. G., Jr.; Borovik, A. S. Angew. Chem., Int. Ed. 1999, 38, 666-669.
32. (b) MacBeth, C. E.; Golombek, A. P.; Young, V. G., Jr.; Yang, C.; Kuczera, K.; Hendrich, M. P.; Borovik, A. S. Science 2000, 289, 938-941.
33. (c) Larsen, P. L.; Gupta, R.; Powell, D. R.; Borovik, A. S. J. Am. Chem. Soc. 2004, 126, 6522-6523.
34. (d) MacBeth, C. E.; Gupta, R.; Mitchell-Koch, K. R.; Young, V. G., Jr.; Lushington, G. H.; Thompson, W. H.; Hendrich, M. P.; Borovik, A. S. J. Am. Chem. Soc. 2004, 126, 2556-2567.
35. (e) Borovik, A. S. Acc. Chem. Res. 2005, 38, 54-61.
36. (f) Lucas, R. L.; Powell, D. R.; Borovik, A. S. J. Am. Chem. Soc. 2005, 127, 11596-11597.
37. MacBeth, C. E.; Hammes, B. S.; Young, V. G., Jr.; Borovik, A. S. Inorg. Chem. 2001, 40, 4733-4741.
38. Zinn, P. J.; Powell, D. R.; Day, V. W.; Hendrich, M. P.; Sorrell, T. N.; Borovik, A. S. Inorg. Chem. 2006, 45, 3484-3486.
39. Another dinucleating ligand containing H-bond donors has been reported: Arii, H.; Funahashi, Y.; Jitsukawa, K.; Masuda, H. Dalton Trans. 2003, 2115-2116.
40. Perrin, D. D.; Armarego, W. L. F. Purification of Laboratory Chemicals, 3rd ed.; Pergamon Press: Elmsford, NY, 1988.
41. Grotjahn, D. B.; Van, S.; Combs, D.; Lev, D. A.; Schneider, C.; Rideout, M.; Meyer, C.; Hernandez, G.; Mejorado, L. J. Org. Chem. 2002, 67, 9200-9209.
42. Lucas, R. L. Ph.D. Dissertation, University of Kansas, Lawrence, KS, 2005.
43. Röder, J. C.; Meyer, F.; Pritzkow, H. Organometallics 2001, 20, 811-817.
44. (a) Kitajima, N.; Hikichi, S.; Taniaka, M.; Moro-oka, Y. J. Am. Chem. Soc. 1993, 115, 5496-5508.
45. (b) He, C.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 105-113.
46. (c) Singh, U. P.; Babbar, P.; Sharma, A. K. Inorg. Chim. Acta 2005, 358, 271-278.
47. (a) Jeffrey, G. A. An Introduction to Hydrogen Bonding; Oxford University Press, Inc.: New York, 1997.
48. (b) Desiraju, G. R.; Steiner, T. The Weak Hydrogen Bond In Structural Chemistry and Biology; Oxford University Press Inc.: New York, 1999.
49. Meyer, F.; Kaifer, E.; Kircher, P.; Heinze, K.; Pritzkow, H. Chem. - Eur. J. 1999, 5, 1617-1630.
50. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 5th ed.; John Wiley: New York, 1997.
51. (a) Curtis, N. J.; Hagen, K. S.; Sargeson, A. M. J. Chem. Soc., Chem. Commun. 1984, 1571-1573.
52. (b) Alcock, N. W.; Creaser, I. I.; Curtis, N. J.; Roecker, L.; Sargeson, A. M.; Willis, A. C. Aust. J. Chem. 1990, 43, 643-654.
53. Bauer, C. B.; Concolino, T. E.; Eglin, J. L.; Rogers, R. D.; Staples, R. J. J. Chem. Soc., Dalton Trans. 1998, 2813-2817.
54. Brown, D. A.; Errington, W.; Glass, W. K.; Haase, W.; Kemp, T. J.; Nimir, H.; Ostrovsky, S. M.; Werner, R. Inorg. Chem. 2001, 40, 5962-5971.
55. (a) Hazell, A.; Jensen, K. B.; McKenzie, C. J.; Toftlund, H. Inorg. Chem. 1994, 33, 3127-3134.
56. (b) Wilkinson, E. C.; Dong, Y.; Que, L., Jr. J. Am. Chem. Soc. 1994, 116, 8394-8395.
57. (c) Duboc-Toia, C.; Menage, S.; Vincent, J.-M.; Averbuch-Pouchot, M. T.; Fontecave, M. Inorg. Chem. 1997, 36, 6148-6149.
58. Frey, S. T.; Murthy, N. N.; Weintraub, S. T.; Thompson, L. K.; Karlin, K. D. Inorg. Chem. 1997, 36, 956-957.
59. (a) McKenzie, C. J.; Robson, R. J. Chem. Soc., Chem. Commun. 1988, 112-114.
60. (b) Hoskins, B. F.; McKenzie, C. J.; MacDonald, I. A. S.; Robson, R. J. Chem. Soc., Dalton Trans. 1996, 2227-2232.
61. Chen, G.; Edwards, T.; D'souza, V. M.; Holz, R. C. Biochemistry 1997, 36, 4278-4286.
62. Addison, A. W.; Rao, T. N.; Reedijk, J.; van Rijin, J.; Verschoor, G. C. J. Chem. Soc., Dalton Trans. 1984, 1349-1356.