Comparing a mononuclear Zn(II) complex with hydrogen bond donors with a dinuclear Zn(II) complex for catalysing phosphate ester cleavage

Chemical Communications

Volumn , Issue 17, 2006, Pages 1845-1847

  Feng, Guoqiang ^a   Mareque Rivas, Juan C ^b   Williams, Nicholas H ^a  

^a UNIVERSITY OF SHEFFIELD   (United Kingdom)

^b UNIVERSITY OF EDINBURGH   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; ORGANOPHOSPHATE; ZINC COMPLEX;

ARTICLE; CATALYSIS; CATALYST; COMPLEX FORMATION; CONCENTRATION (PARAMETERS); HYDROGEN BOND; HYDROLYSIS; MICHAELIS MENTEN KINETICS; PKA; REACTION ANALYSIS; TRANSESTERIFICATION;

EID: 33646908505     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b514328d     Document Type: Article

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29. Note that the rate acceleration relative to free Zn(ii) ions in solution is about 20 fold as the core ligand 2 reduces the activity of the ion
30. This analysis assumes that the ground state binding mode is also the productive mode leading to reaction