Rapid phosphodiester hydrolysis by an ammonium-functionalized copper(II) complex. A model for the cooperativity of metal ions and NH-acidic groups in phosphoryl transfer enzymes

Journal of the American Chemical Society

Volumn 118, Issue 50, 1996, Pages 12704-12709

  Kövári, Endre ^a   Krämer, Roland ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPLEX;

ARTICLE; CRYSTALLOGRAPHY; ELECTRON SPIN RESONANCE; ENZYME ACTIVITY; HYDROLYSIS; MODEL;

EID: 0030482393     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962806y     Document Type: Article

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61. 2)Cu, but a detailed kinetic analysis was complicated by rapid Cu(II)-Cu(I) reduction. The reason for the reduction sensitivity of this complex is not clear.