Hydrogen-bonding cavities about metal ions: A redox pair of coordinatively unsaturated paramagnetic Co - OH complexes

Angewandte Chemie - International Edition

Volumn 38, Issue 5, 1999, Pages 666-669

  Hammes, Brian S ^a   Young Jr , Victor G ^b   Borovik, Andrew S ^a  

^a UNIVERSITY OF KANSAS   (United States)

^b UNIVERSITY OF MINNESOTA   (United States)

Author keywords

Cobalt; Hydrogen bonds; Hydroxo ligands; Ligand effects

Indexed keywords

COBALT; HYDROGEN; LIGAND; METAL ION; METALLOPROTEIN;

ARTICLE; CHEMICAL BINDING; CHEMICAL STRUCTURE; COMPLEX FORMATION; COVALENT BOND; HYDROGEN BOND; LIGAND BINDING; MOLECULAR STABILITY; REGULATORY MECHANISM; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 0033104657     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3773(19990301)38:5<666::aid-anie666>3.0.co;2-x     Document Type: Article

References (35)

1. 6-1 has been reported: C. Rapsos, M. Almaraz, M. Martín, V. Weinrich, M. L. Mussóns, V. Alcázar, M. C. Caballero, J. R. Morán, Chem. Lett. 1995, 759-760.
2. R. H. Holm, P. Kennepohl, E. I. Solomon, Chem. Rev. 1996, 96, 2239-2314.
3. a) Y. Lu, J. S. Valentine, Curr. Opin. Struct. Biol. 1997, 7, 495-500;
4. b) L. Regan, TIBS 1995, 20, 280-285.
5. B. A. Springer, S. G. Sligar, J. S. Olsen, G. N. Philips, Chem. Rev. 1994, 94, 699-714.
6. Porphyrin systems: a) G. E. Wuenshell, C. Tetreau, D. Lavalette, C. A. Reed, J. Am. Chem. Soc. 1992, 114, 3346-3355;
7. b) J. P. Collman, X. Zhang, K. Wong, J. I. Brauman, J. Am. Chem. Soc. 1994, 116, 6245-6251;
8. c) M. Momenteau, C. A. Reed, Chem. Rev. 1994, 94, 659-698.
9. d) C. K. Chang, Y. Liang, G. Avilés, S.-M. Peng, J. Am. Chem. Soc. 1995, 117, 4191-4192; non-heme systems:
10. e) J. E. Kickham, S. J. Loeb, S. L. Murphy, J. Am. Chem. Soc. 1993, 115, 7031-7032;
11. f) D. M. Rudkevich, W. Verboom, Z. Brzozka, M. J. Palys, W. P. R. V. Stauthamer, G. J. Van Hummel, S. M. Franken, S. Harkema, J. F. J. Engbersen, D. N. Reinhoudt, J. Am. Chem. Soc. 1994, 116, 4341-4351;
12. g) N. Kitajima, H. Komatsuzaki, S. Hikichi, M. Osawa, Y. Moro-oka, J. Am. Chem. Soc. 1994, 116, 11596-11597;
13. h) P. H. Walton, K. N. Raymond, Inorg. Chim. Acta 1995, 240, 593-601;
14. i) W. Yao, R. H. Crabtree, Inorg. Chem. 1996, 35, 3007-3011;
15. j) L. M. Berreau, S. Mahapatra, J. A. Halfen, V. G. Young, W. B. Tolman, Inorg. Chem. 1996, 35, 6339-6342;
16. k) A. Wada, M. Harata, K. Hasegawa, K. Jitsukawa, H. Masuda, M. Mukai, T. Kitagawa, H. Einaga, Angew. Chem. 1998, 110, 874-875;
17. Angew. Chem. Int. Ed. Engl. 1998, 37, 798-799.
18. a) M. Ray, G. P. A. Yap, A. L. Rheingold, A. S. Borovik, Chem. Commun. 1995, 1777-1778;
19. b) M. Ray, A, Golombek, M. Hendrich, V. G. Young, A. S. Borovik, J. Am. Chem. Soc. 1996, 118, 6084-6085;
20. c) B. S. Hammes, D. Maldonado-Ramos, G. P. A. Yap, L. Liable-Sands, A. L. Rheingold, A. S. Borovik, Inorg. Chem. 1997, 36, 3210-3211;
21. Z. Shirin, V. G. Young, A. S. Borovik, Chem. Commun. 1997, 4, 1840-1841;
22. e) M. Ray, B. S. Hammes, G. P. A. Yap, A. L. Rheingold, A. S. Borovik, Inorg. Chem. 1998, 37, 1527-1532.
23. 4- pair: N. N. Greenwood, A. Earnshaw, The Chemistry of the Elements, Pergamon Press, Oxford, 1984, pp. 1302-1303.
24. 2-2 has a potassium ion (K1) positioned at a distance of 2.798 (3) Å from O1.
25. In 2 the O1 ⋯ N5 and O1 ⋯ N7 distances are 2.747(4) and 2.779(4) Å, while an O1 ⋯ N3 distance of 3.019(3) Å is observed for the non-hydrogen-bonded arm.
26. D. A. Buckingham, C R. Clark in Comprehensive Coordination Chemistry, Vol. 4 (Eds.: G. Wilkinson, R. D. Guillard, J. A. McCleverty), Pergamon Press, New York, 1987, pp. 635-900.
27. - ligands: a) M. Ardon, A. Bino, Inorg. Chem. 1985, 24, 1343-1347;
28. b) M. Ardon, A. Bino, Polyhedron 1987, 6, 181-187.
29. A. Orlandini, L. Sacconi, Inorg. Chem. 1976, 15, 78-85.
30. S. E. Kucharski, B. W. Skelton, A. H. White, Aust. J. Chem. 1978, 31, 47-51.
31. III complexes with trigonal-bypyramidal stereochemistry: a) C. A. McAuliffe, S M. Godfrey, A. G. Mackie, R. G. Pritchard, Angew. Chem. 1992, 104, 932-934;
32. Angew. Chem. Int. Ed. Engl. 1992, 31, 919-921;
33. b) B. S. Jaynes, T. Ren, S. Liu, S. J. Lippard, J. Am. Chem. Soc. 1992, 114, 9670-9671.
34. R. Drago, Physical Methods in Inorganic Chemistry, Saunders, Philadelphia, 1977, chap. 11.
35. For examples relevant to M - OH complexes in biology, see I. Bertini, C. Luchinat in Bioinorganic Chemistry (Eds.: I. Bertini, H. B. Gray, S. J. Lippard, J. S. Valentine), University Science Books, Mill Valley, 1994, pp. 37-106.