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note
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Since the concentration of Pd quoted in ppm/ppb is dependent on the amount of Pd initially added (lower levels at lower catalytic loadings) and the volume of solvent, Pd leaching will be quoted as a % of the initially added Pd.
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71
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35548969107
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The thiol content in both materials was determined by elemental analysis. Only materials with the same % thiol were compared
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72
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35549005205
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Note that these results were performed in air. The co-condensation-derived catalyst displays even less stability in argon
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35548950115
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note
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The catalysts are also somewhat sensitive to mechanical agitation.
-
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75
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35548991252
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note
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This effect is likely due to the protective effects of the grafting layer insulating the silica against attack by the aqueous base. The addition of a protective layer has been shown to dramatically improve the stability of this material (K. McEleney, C.M. Crudden, manuscript in preparation).
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78
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24944485087
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This test has been previously reported with amorphous silica supported thiol as a test of heterogeneity by and recently by J.M. Richardson, C.W. Jones, J. Catal. 251 (2007) 80
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