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The presence of nodes at the imido nitrogens in the HOMO and LUMO of the PDI molecule prevents electronic coupling between subunits. when such subunits are attached through the PDI imido positions
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The presence of nodes at the imido nitrogens in the HOMO and LUMO of the PDI molecule prevents electronic coupling between subunits. when such subunits are attached through the PDI imido positions.
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However, the 'H NMR spectrum (see the Supporting Information) shows that 5 is still aggregated at higher concentrations (3 mM).
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However, the 'H NMR spectrum (see the Supporting Information) shows that 5 is still aggregated at higher concentrations (3 mM).
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