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33645209517
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note
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The fluorescence lifetimes of ZnPc and PDI were determined as 3.2 and 4.2 ns in deaerated PhCN, respectively.
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27
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33645202447
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note
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The triplet energy was determined from phosphorescence spectrum. See Supplementary Information S2.
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28
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33645192788
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0842303778
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Photoexcitation of zinc porphyrin-napthalenediimide also affords the CS state, the lifetime of which can be altered by the coordination of metal ions to the naphthalenediimide moiety; see: K. Okamoto, Y. Mori, H. Yamada, H. Imahori and S. Fukuzumi, Chem. Eur. J., 2004, 10, 474.
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2+; see: S. Fukuzumi, K. Ohkubo and T. Okamoto, J. Am. Chem. Soc., 2002, 124, 14147.
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33645196827
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note
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2+ ions bind to two carbonyl oxygens at the same side.
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37
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