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As an example, the crystallographic data of 3b: colorless crystal (fragment, dimensions 0.47 x 0.39 x 0.20 mm3, orthorhombic, space group P212121, Z, 4, a, 9.3604(15, b, 9.9285(16, c, 17.935(3) Å, V, 1666.8(5) Å3, ρ, 1.440 g cm-3, T, 200(2) K, Θmax, 28.33°, MoKα radiation, λ, 0.71073 Å, 0.3°ω scans with CCD area detector, covering a whole sphere in reciprocal space; 16742 reflections measured, 4145 unique (Rint, 0.0320, 3813 observed (I > 2σI, intensities were corrected for Lorentz and polarization effects; an empirical absorption correction was applied using SADABS, 14] μ, 0.11 mm-1, Tmin, 0.95, Tmax, 0.98, structure solved by direct methods and refined against F
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3. CCDC-641967 (3b), CCDC-641968 (8), CCDC-641969 (10), CCDC-641970 (12), and CCDC-641971 (16) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/ data_request/cif.
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