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When dimethylsulfide was used, the reduction was rather slow.
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Stereocenter C7 of aldehydes 12 and 14 is stereogenic; for identical side arms this center becomes chirotopic; local chirality is discussed in: (formula presented)
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The use of TBS-chloride for O-silylation was totally ineffective; we explain this fact with the intramolecular hydrogen bonding of the alcohol group (cf. Figure 2)
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The use of TBS-chloride for O-silylation was totally ineffective; we explain this fact with the intramolecular hydrogen bonding of the alcohol group (cf. Figure 2).
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