메뉴 건너뛰기




Volumn 46, Issue 7, 2007, Pages 2373-2387

Synthesis, structural characterization, and multifrequency electron paramagnetic resonance studies of mononuclear thiomolybdenyl complexes

Author keywords

[No Author keywords available]

Indexed keywords

MOLYBDENUM; THIOL DERIVATIVE;

EID: 34247166613     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic060585j     Document Type: Article
Times cited : (28)

References (95)
  • 1
  • 2
    • 0002957432 scopus 로고    scopus 로고
    • 2nd ed, Reedijk, J, Bouwman, E, Eds, Marcel Dekker: New York
    • Pilato, R. S.; Stiefel, E. I. In Bioinorganic Catalysis, 2nd ed.; Reedijk, J., Bouwman, E., Eds.; Marcel Dekker: New York, 1999; pp 81-152.
    • (1999) Bioinorganic Catalysis , pp. 81-152
    • Pilato, R.S.1    Stiefel, E.I.2
  • 3
    • 0003527329 scopus 로고    scopus 로고
    • Sigel, A, Sigel, H, Eds, Marcel Dekker: New York
    • Metal Ions in Biological Systems; Sigel, A., Sigel, H., Eds.; Marcel Dekker: New York, 2002; Vol. 39.
    • (2002) Metal Ions in Biological Systems , vol.39
  • 4
    • 78651401065 scopus 로고    scopus 로고
    • McCleverty, J. A, Meyer, T. J, Eds, Elsevier Pergamon: Amsterdam, Chapter 8.18, pp
    • Tunney, J. M.; McMaster, J.; Garner, C. D. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Pergamon: Amsterdam, 2004; Vol. 8, Chapter 8.18, pp 459-477.
    • (2004) Comprehensive Coordination Chemistry II , vol.8 , pp. 459-477
    • Tunney, J.M.1    McMaster, J.2    Garner, C.D.3
  • 5
    • 30744456424 scopus 로고    scopus 로고
    • King, R. B, Ed, Wiley: Chichester, U.K
    • Young, C. G. In Encyclopedia of Inorganic Chemistry 2; King, R. B., Ed.; Wiley: Chichester, U.K., 2005; Vol. V, pp 3321-3340.
    • (2005) Encyclopedia of Inorganic Chemistry 2 , vol.5 , pp. 3321-3340
    • Young, C.G.1
  • 6
    • 34247108992 scopus 로고    scopus 로고
    • General reviews include the following: Bray, R. C. In Biological Magnetic Resonance; Reuben, J., Berliner, L. J., Eds.; Plenum Press: New York, 1980; pp 45-84.
    • General reviews include the following: Bray, R. C. In Biological Magnetic Resonance; Reuben, J., Berliner, L. J., Eds.; Plenum Press: New York, 1980; pp 45-84.
  • 9
  • 19
    • 0028023353 scopus 로고    scopus 로고
    • For DMSO reductase: Bennett, B.; Benson, N.; McEwan, A. G.; Bray, R. C. Eur. J. Biochem. 1994, 225, 321.
    • For DMSO reductase: Bennett, B.; Benson, N.; McEwan, A. G.; Bray, R. C. Eur. J. Biochem. 1994, 225, 321.
  • 28
    • 0036366683 scopus 로고    scopus 로고
    • Sigel, A, Sigel, H, Eds, Marcel-Dekker: New York
    • Dobbek, H.; Huber, R. In Metal Ions In Biological Systems; Sigel, A., Sigel, H., Eds.; Marcel-Dekker: New York, 2002; Vol. 39, pp 227-263.
    • (2002) Metal Ions In Biological Systems , vol.39 , pp. 227-263
    • Dobbek, H.1    Huber, R.2
  • 35
    • 0000929769 scopus 로고
    • Wilkinson, G, Gillard, R. D, McCleverty, J. A, Eds, Pergamon: Oxford, Chapter 36.4, pp
    • Garner, C. D.; Charnock, J. M. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, 1987; Vol. 3, Chapter 36.4, pp 1329-1374.
    • (1987) Comprehensive Coordination Chemistry , vol.3 , pp. 1329-1374
    • Garner, C.D.1    Charnock, J.M.2
  • 36
    • 3142759067 scopus 로고    scopus 로고
    • McCleverty, J. A, Meyer, T. J, Eds, Elsevier Pergamon: Amsterdam, Chapter 4.7, pp
    • Young, C. G. In Comprehensive Coordination Chemistry II; McCleverty, J. A., Meyer, T. J., Eds.; Elsevier Pergamon: Amsterdam, 2004; Vol. 4, Chapter 4.7, pp 415-527.
    • (2004) Comprehensive Coordination Chemistry II , vol.4 , pp. 415-527
    • Young, C.G.1
  • 51
    • 0001328963 scopus 로고    scopus 로고
    • X2-Y2-based ground state.)
    • X2-Y2-based ground state.)
  • 74
    • 0003462939 scopus 로고
    • Report ORNL-5138; Oak Ridge National Laboratory: Oak Ridge, TN
    • Johnson, C. K. ORTEPII; Report ORNL-5138; Oak Ridge National Laboratory: Oak Ridge, TN, 1976.
    • (1976) ORTEPII
    • Johnson, C.K.1
  • 75
    • 33646767009 scopus 로고    scopus 로고
    • ORTEP-3 for Windows, v1.08
    • Farrugia, L. J. ORTEP-3 for Windows, v1.08. J. Appl. Crystallogr. 1997, 30, 565.
    • (1997) J. Appl. Crystallogr , vol.30 , pp. 565
    • Farrugia, L.J.1
  • 76
    • 34247163980 scopus 로고    scopus 로고
    • Gnuplot maybe obtained from www.gnuplot.info.
    • Gnuplot maybe obtained from www.gnuplot.info.
  • 79
    • 34247105268 scopus 로고    scopus 로고
    • It was assumed that any effects due to a change of molecular environment upon freezing or due to the influence of the asymmetry in A Pilbrow, J. R. Transition Ion Electron Paramagnetic Resonance; Clarendon Press: Oxford, 1990; §3.7 and §5.3.4
    • It was assumed that any effects due to a change of molecular environment upon freezing or due to the influence of the asymmetry in A (Pilbrow, J. R. Transition Ion Electron Paramagnetic Resonance; Clarendon Press: Oxford, 1990; §3.7 and §5.3.4.
  • 80
    • 49549167361 scopus 로고
    • 381, were of a similar magnitude to the overall uncertainty in the EPR simulations
    • Belford, R. L.; Pilbrow, J. R. J. Magn. Reson. 1973, 11, 381.) were of a similar magnitude to the overall uncertainty in the EPR simulations.
    • (1973) J. Magn. Reson , vol.11
    • Belford, R.L.1    Pilbrow, J.R.2
  • 82
    • 0001229538 scopus 로고
    • Wilkinson, G, Gillard, R. D, McCleverty, J. A, Eds, Pergamon: Oxford, Chapter 16.1, pp
    • Müller, A.; Diemann, E. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, 1987; Chapter 16.1, pp 515-550.
    • (1987) Comprehensive Coordination Chemistry , pp. 515-550
    • Müller, A.1    Diemann, E.2
  • 84
    • 34247144459 scopus 로고    scopus 로고
    • 2, and Tp*MoS(tdt) revealed the presence of an additional minor species (<4%) which may be attributed to unreacted starting material.
    • 2, and Tp*MoS(tdt) revealed the presence of an additional minor species (<4%) which may be attributed to unreacted starting material.
  • 85
    • 34247173480 scopus 로고    scopus 로고
    • To reiterate, we use the (x,y,z) coordinate system to identify the principal directions of the g matrix and (x′,y′, z′) to identify those of the A matrix. The molecular coordinate system is defined by the X,Y,Z axes (Figure 1).
    • To reiterate, we use the (x,y,z) coordinate system to identify the principal directions of the g matrix and (x′,y′, z′) to identify those of the A matrix. The molecular coordinate system is defined by the X,Y,Z axes (Figure 1).
  • 90
    • 34247173859 scopus 로고    scopus 로고
    • In making such comparisons, it must be borne in mind that there may be differences between the solid state and solution molecular structures
    • In making such comparisons, it must be borne in mind that there may be differences between the solid state and solution molecular structures.
  • 91
    • 34247171644 scopus 로고    scopus 로고
    • Note that this does not imply that SOC to LMCT donor orbitals provide g shifts arising purely from angular orbital momentum in the molecular X direction, because β is large and therefore x̂ is expected to deviate substantially from X̂. The orientation of the g and A matrices relative to the molecular axes and a discussion of the assignment of principal components will be discussed in detail ref 47.
    • Note that this does not imply that SOC to LMCT donor orbitals provide g shifts arising purely from angular orbital momentum in the molecular X direction, because β is large and therefore x̂ is expected to deviate substantially from X̂. The orientation of the g and A matrices relative to the molecular axes and a discussion of the assignment of principal components will be discussed in detail ref 47.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.