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2-S). The reaction is the only example of the generation of an oxothio - Mo(VI) complex via clean oxygen atom transfer to a thio - Mo(IV) complex. Laughlin, L. J.; Colmanet, S.; Scrofani, S. D. B.; Young, C. G. Unpublished results.
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+ [L = hydrobis(3-isopropylpyrazol-1-yl)(5-isopropylpyrazol-1-yl)borate] complexes were generated by ferrocenium oxidation of the corresponding Mo(IV) complexes. The thio - Mo(V) complexes have lower isotropic g values than their oxo analogues (1.961 vs 1.963 for E = S and E = O. respectively, when R = Pr′). See ref 31
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55
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85086290744
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31P for the dithiophosphinate complexes.
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3 molecule from the coordination sphere provides sufficient steric protection from aquation, permitting the chelation of the dithiophosphinate ligand in this case. Laughlin, L. J.; Eagle, A. A.; Tiekink, E. R. T.; Young, C. G. Unpublished results.
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