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Volumn 111, Issue 2, 2007, Pages 408-422

Single-ion solvation free energies and the normal hydrogen electrode potential in methanol, acetonitrile, and dimethyl sulfoxide

Author keywords

[No Author keywords available]

Indexed keywords

ACETONITRILE; ELECTROLYTES; FREE ENERGY; IONS; PROTONS; SOLVENTS; THERMODYNAMICS;

EID: 33847100452     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp0654031     Document Type: Article
Times cited : (445)

References (199)
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    • In several earlier papers where we used this thermochemical cycle, 7,56,111 the solvation free energies appearing in the vertical legs were denoted by a superscript asterisk, meaning transfer from a standard-state gas-phase concentration of 1 mol/L to a standard-state liquid-phase concentration of 1 mol/L, and the symbol for the free energy change associated with moving from a standard-state gas-phase pressure of 1 atm to a liquid-phase concentration of 1 mol/L was left out of the diagrams (but not the equations) for simplicity. In this paper, we use an equivalent and perhaps simpler convention in which the solvation free energies appearing in the vertical legs are denoted by a superscript open circle. The equations resulting from the thermochemical cycles that appear in this article are indentical to those equations appearing in our earlier papers
    • 7,56,111 the solvation free energies appearing in the vertical legs were denoted by a superscript asterisk, meaning transfer from a standard-state gas-phase concentration of 1 mol/L to a standard-state liquid-phase concentration of 1 mol/L, and the symbol for the free energy change associated with moving from a standard-state gas-phase pressure of 1 atm to a liquid-phase concentration of 1 mol/L was left out of the diagrams (but not the equations) for simplicity. In this paper, we use an equivalent and perhaps simpler convention in which the solvation free energies appearing in the vertical legs are denoted by a superscript open circle. The equations resulting from the thermochemical cycles that appear in this article are indentical to those equations appearing in our earlier papers.
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    • A full description of the steps required in going from eq 25 to eq 26 is given in ref 56
    • A full description of the steps required in going from eq 25 to eq 26 is given in ref 56.
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    • This value was also reported in: Cox, B. G, Hedwig, G. R, Parker, A. J, Watts, D. W. Aust. J. Chem. 1974, 27, 477
    • This value was also reported in: Cox, B. G.; Hedwig, G. R.; Parker, A. J.; Watts, D. W. Aust. J. Chem. 1974, 27, 477.


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