A new class of chiral pyrrolidine for asymmetric Michael addition reactions. New mechanism via simple 4+2 type attack of the enamine on the trans-nitrostyrene

Tetrahedron

Volumn 63, Issue 3, 2007, Pages 740-747

  Diez, David ^a   Jose Gil, M ^a   Moro, Rosalina F ^a   Marcos, Isidro S ^a   Garcia P ^a   Basabe, P ^a   Garrido, Narciso M ^a   Broughton, Howard B ^b   Urones, J G ^a  

^a UNIVERSITY OF SALAMANCA   (Spain)

^b DCRandT   (Spain)

Author keywords

Cycloaddition 4+2; DFT; Michael addition; Organocatalysis; Proline; Pyrrolidines; Transition state

Indexed keywords

ALKENE DERIVATIVE; ENAMINE; KETONE DERIVATIVE; PYRROLIDINE DERIVATIVE; STYRENE DERIVATIVE;

ARTICLE; CATALYST; MICHAEL ADDITION; MOLECULAR MODEL; PRIORITY JOURNAL;

EID: 33845347873     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2006.10.083     Document Type: Article

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