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Conjugate addition reaction in organic synthesis
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For our pan, we have confirmed the implication of enamine in the addition of 3,3-dimethylbutyraldehyde catalyzed by pyrrolidine, which showed the presence of the corresponding enamine by GC-MS
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Bui, T.; Barbas, C. F., III. Tetrahedron Lett. 2000, 41, 6951. For our pan, we have confirmed the implication of enamine in the addition of 3,3-dimethylbutyraldehyde catalyzed by pyrrolidine, which showed the presence of the corresponding enamine by GC-MS.
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Bui, T.1
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25
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0042269938
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Dinitro-adduct: (Equation Presented)
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Dinitro-adduct: (Equation Presented)
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26
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0042771119
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note
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The best enantioselectivity for addition of acetone to nitrostyrene was obtained with the more sterically hindered N-cyclohexyl-2,2′-bipyrrolidine in the presence of pTSA (0.15 equiv) (89%, 30% ee).
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28
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0003091207
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31
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0043272401
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note
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For the determination of the absolute configuration, see Supporting Information.
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32
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0032104248
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Zhu, J.; Withers, S. G.; Reichardt, P. B.; Treadwell, E.; Clausen, T. P. Biochem. J. 1998, 332, 367-371.
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