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33745893979
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The only exception is (S,S)-13 below (δ = 4.78-5.54). Here, the crystal structure shows a distance of 4.145 Å between the centroid of the PPh3 phenyl ring syn to the cyclopentadienyl ligand and the closest cyclopentadienyl carbon (α to the Pd-C bond). In contrast, the three other crystallographically characterized palladacycles show distances of 3.735-3.878 Å.
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d) J. Park, M. G. Kim, Y. Jun, J. S. Lee, W. Lee, J. Cheon, J. Am. Chem. Soc. 2004, 126, 9072;
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Park, J.1
Kim, M.G.2
Jun, Y.3
Lee, J.S.4
Lee, W.5
Cheon, J.6
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94
-
-
0031580837
-
-
A. F. Burchat, J. M. Chong, N. Nielsen, J. Organomet. Chem. 1997, 542, 281.
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J. Organomet. Chem.
, vol.542
, pp. 281
-
-
Burchat, A.F.1
Chong, J.M.2
Nielsen, N.3
-
95
-
-
33845550978
-
-
2/benzene is recommended: A. T. Patton, C. E. Strouse, C. B. Knobler, J. A. Gladysz, J. Am. Chem. Soc. 1983, 105, 5804.
-
(1983)
J. Am. Chem. Soc.
, vol.105
, pp. 5804
-
-
Patton, A.T.1
Strouse, C.E.2
Knobler, C.B.3
Gladysz, J.A.4
-
96
-
-
33745915998
-
-
note
-
FAB, 3-NBA, m/z (%); the peaks correspond to the most intense signal of the isotope envelope.
-
-
-
-
97
-
-
0002572655
-
-
F. Agbossou, E. J. O'Connor, C. M. Garner, N. Quirós Méndez, J. M. Fernández, A. T. Patton, J. A. Ramsden, J. A. Gladysz, Inorg. Synth. 1992, 29, 211.
-
(1992)
Inorg. Synth.
, vol.29
, pp. 211
-
-
Agbossou, F.1
O'Connor, E.J.2
Garner, C.M.3
Méndez, N.Q.4
Fernández, J.M.5
Patton, A.T.6
Ramsden, J.A.7
Gladysz, J.A.8
-
98
-
-
33745920937
-
-
note
-
2, toluene/hexanes (1:1 v/v)) was performed.
-
-
-
-
99
-
-
33745893381
-
-
note
-
6.
-
-
-
-
100
-
-
33745906097
-
-
note
-
Measured gravimetrically inside a glove box (difference in mass between loaded and discharged syringe).
-
-
-
-
101
-
-
33745883419
-
-
note
-
2 signals.
-
-
-
-
102
-
-
33745907991
-
-
note
-
1H NMR spectra of (S,S)-10b and were assigned to the meso diastereomer.
-
-
-
-
103
-
-
33745892789
-
-
note
-
These (broadened) resonances were tentatively assigned to both syn and anti isomers (overlapping signals). However, in some cases non-overlapping signals of the minor isomer may have been be too broad or too weak to observe.
-
-
-
-
104
-
-
33745897777
-
-
note
-
13C NMR signals were too weak to observe.
-
-
-
-
105
-
-
33745892539
-
-
note
-
It was not possible to assign signals to the RePPh3 vs PdPPh3 phenyl groups; the designations ilo/m/p and i′/oPrime;/m′/p′ are arbitrary.
-
-
-
-
106
-
-
33745917574
-
-
note
-
2 phosphorus atom and the methyl group of the cis acetate ligand.
-
-
-
-
107
-
-
33745898690
-
-
Doctoral Dissertation, Universität Erlangen-Nürn-berg, The synthesis is analogous to that of the racemate.[9a]
-
S. Eichenseher, Doctoral Dissertation, Universität Erlangen-Nürn-berg, 2005. The synthesis is analogous to that of the racemate.[9a]
-
(2005)
-
-
Eichenseher, S.1
-
108
-
-
33745921074
-
-
13C NMR signal was detected
-
13C NMR signal was detected.
-
-
-
-
109
-
-
33745904323
-
-
note
-
This signal overlaps with one of (S,S)-10b. Therefore, the intensity reflects the theoretical rather than a measured value.
-
-
-
-
110
-
-
33745930676
-
-
note
-
When the crystals were dried by either vacuum or a nitrogen stream, the solvent of crystallization was removed.
-
-
-
-
112
-
-
0031059866
-
-
Macromolecular Crystallography, Part A, 307
-
b) "Scalepack" data processing software: Z. Otwinowski, W. Minor, Methods in Enzymology 1997, 276 (Macromolecular Crystallography, Part A), 307.
-
(1997)
Methods in Enzymology
, pp. 276
-
-
Otwinowski, Z.1
Minor, W.2
-
114
-
-
0003872738
-
-
(Eds.: J. A. Ibers, W. C. Hamilton), Kynoch, Birmingham, UK
-
D. T. Cromer, J. T. Waber, in International Tables for X-ray Crystallography (Eds.: J. A. Ibers, W. C. Hamilton), Kynoch, Birmingham, UK, 1974.
-
(1974)
International Tables for X-ray Crystallography
-
-
Cromer, D.T.1
Waber, J.T.2
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