Chelating diphosphines that contain a rhenium stereocenter in the backbone: Applications in rhodium-catalyzed enantioselective ketone hydrosilylations and alkene hydrogenations

Organometallics

Volumn 21, Issue 20, 2002, Pages 4275-4280

  Kromm, Klemenz ^a   Osburn, Philip L ^a   Gladysz, J A ^a  

^a UNIVERSITY OF ERLANGEN NUREMBERG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

HYDROSILYLATIONS;

ADDITION REACTIONS; AMINO ACIDS; CATALYST ACTIVITY; CHELATION; HYDROGENATION; KETONES; OLEFINS; RHENIUM; RHODIUM;

STEREOCHEMISTRY;

EID: 0001610167     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om020432d     Document Type: Article

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67. The solvent was removed under vacuum, the residue was extracted with ether, and the extract was filtered through a silica gel plug. The solvent was removed from the filtrate, the residue extracted with ether (14a) or methanol (14b), and the extract passed through a syringe filter.