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2 catalyst system has also been shown to be effective for room-temperature catalytic amination of aryl chlorides; see ref 9a.
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Ligands 2 and 4 are now commercially available from Strem Chemical Co.
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No catalyst has been reported which is effective for Suzuki coupling reactions to form biaryls with four ortho substituents; to the best of our knowledge, only one isolated yield (12%) has been for the synthesis of a tetrasubstituted biaryl (using Suzuki coupling) has been reported. See ref 15c.
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A detailed mechanistic study on both Suzuki coupling and catalytic animation will be reported separately.
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Reactions in which argon purges were used instead of the evacuation/ backfill cycles (at all points required in the procedure) gave similar results.
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