Solvent effects on the conversion of dicopper(II) μ-η2: η2-peroxo to bis-μ-oxo dicopper(III) complexes: Direct probing of the solvent interaction

Inorganic Chemistry

Volumn 43, Issue 14, 2004, Pages 4115-4117

  Liang, Hong Chang ^a   Henson, Mark J ^b   Hatcher, Lanying Q ^a   Vance, Michael A ^b   Zhang, Christiana Xin ^a   Lahti, David ^c   Kaderli, Susan ^c   Sommer, Roger D ^d   Rheingold, Arnold L ^d   Zuberbühler, Andreas D ^c   Solomon, Edward I ^b   Karlin, Kenneth D ^a  

^a JOHNS HOPKINS UNIVERSITY   (United States)

^b STANFORD UNIVERSITY   (United States)

^c UNIVERSITY OF BASEL   (Switzerland)

^d UNIVERSITY OF DELAWARE   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; BIS MU OXO DICOPPER COMPLEX; BORON; CALIXARENE; COPPER COMPLEX; DICOPPER MU ETA2:ETA2 PEROXO COMPLEX; ETHER; FLUORINE; LIGAND; METHYL CHLORIDE; OXYGEN; PEROXIDE; SOLVENT; TETRAHYDROFURAN; TRIDENTATE LIGAND; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL CONVERSION; CHEMICAL REACTION; CHEMOREACTIVITY; KINETICS; RAMAN SPECTROMETRY; SOLVENT EFFECT; THERMODYNAMICS; ULTRAVIOLET SPECTROSCOPY;

EID: 3142710163     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0498283     Document Type: Article

References (22)

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9. AN = 3,3′-Iminobís(N,N-dimethylpropylamine).
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12. See Supporting Information.
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15. To our knowledge, this is the second lowest known v(O-O) in dicopper(II) side-on peroxo systems.
16. Unpublished results for acetone.
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22. Besides PYAN, this effect has been seen in the MeAN system (ref 10; see also Figure S4 in Supporting Information). Large shifts for the side-on peroxo but not bis-μ-oxo complexes have also been seen in other peroxo/oxo systems (Mahadevan, V.; Henson, M. J.; Stack, T. D. P.; Solomon, E. I. Unpublished results).