Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes

Journal of Organometallic Chemistry

Volumn 690, Issue 24-25, 2005, Pages 5938-5947

  Andavan, Gurusamy Thangavelu Senthil ^a   Bauer, Eike B ^a   Letko, Christopher S ^a   Hollis, T Keith ^a   Tham, Fook S ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Carbene complex; Free bis carbene; Hydrosilylation; N heterocyclic carbene; Pincer complex; Rhodium complex

Indexed keywords

BENZENE; BINARY MIXTURES; CATALYSTS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; ORGANOMETALLICS; SOLUTIONS; SPECTROSCOPIC ANALYSIS; STEREOCHEMISTRY; SYNTHESIS (CHEMICAL);

CARBENE COMPLEX; FREE BIS-CARBENE; HYDROSILYLATION; N-HETEROCYCLIC CARBENE; PINCER COMPLEX; RHODIUM COMPLEX;

COMPLEXATION;

EID: 27744475029     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.jorganchem.2005.07.088     Document Type: Article

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