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ed by N. Auner and J. Weis, VCH, Weinheim for 1e and 1f, see: Ref. 4
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It is well established that an α-silyl group stabilizes an adjacent carbanionic center by hyper conjugation with the σ*(Si-C) orbitals. Similarly, silyl anion is also stabilized by the silyl groups
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It is well established that an α-silyl group stabilizes an adjacent carbanionic center by hyper conjugation with the σ*(Si-C) orbitals. Similarly, silyl anion is also stabilized by the silyl groups.
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note
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2 forms dimeric structure and each lithium atom is coordinated by two THF molecules. However, the refinement failed.
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