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Volumn 71, Issue 3, 1998, Pages 741-747

Lithiosilanes with Si-Si Bonds: Synthesis and 6Li, 7Li, and 29Si NMR Studies

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EID: 0000472480     PISSN: 00092673     EISSN: None     Source Type: Journal    
DOI: 10.1246/bcsj.71.741     Document Type: Article
Times cited : (31)

References (33)
  • 20
    • 1542641516 scopus 로고
    • f) D. A. Bravo-Zhivotovskii, S. D. Pigaev, O. A. Vyazankina, and N. S. Vyazankin, Izv. Akad. Nauk SSSR, Ser. Khim., 1984, 2414; Chem. Abstr., 102, 132171 (1985).
    • (1985) Chem. Abstr. , vol.102 , pp. 132171
  • 24
    • 84955743196 scopus 로고    scopus 로고
    • ed by N. Auner and J. Weis, VCH, Weinheim for 1e and 1f, see: Ref. 4
    • Unsolvated 1d, 1e, and 1f exist as dimer in the solid state determined by X-ray diffraction. For 1d, see: a) K. W. Klinkhammer, G. Becker, and W. Schwarz, "Organosilicon Chemistry II, From Molecules to Materials," ed by N. Auner and J. Weis, VCH, Weinheim (1996), pp. 493-498; for 1e and 1f, see: Ref. 4.
    • (1996) Organosilicon Chemistry II, from Molecules to Materials , pp. 493-498
    • Klinkhammer, K.W.1    Becker, G.2    Schwarz, W.3
  • 25
    • 85034464711 scopus 로고    scopus 로고
    • It is well established that an α-silyl group stabilizes an adjacent carbanionic center by hyper conjugation with the σ*(Si-C) orbitals. Similarly, silyl anion is also stabilized by the silyl groups
    • It is well established that an α-silyl group stabilizes an adjacent carbanionic center by hyper conjugation with the σ*(Si-C) orbitals. Similarly, silyl anion is also stabilized by the silyl groups.
  • 31
    • 85034475345 scopus 로고    scopus 로고
    • note
    • 2 forms dimeric structure and each lithium atom is coordinated by two THF molecules. However, the refinement failed.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.