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Similar complexes have been detected in related pincer chemistry using NCN-platinum complexes and polar coordinating solvents: Gossage, R. A.; Ryabov, A. D.; Spek, A. L.; Stufkens, D. J.; Beck, J. A. M.; van Eldik, R.; van Koten, G. J. Am. Chem. Soc. 1999, 121, 2488.
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20
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0011513165
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note
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2 = 0.048, GOF = 0.983.
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21
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0034654764
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25
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85170216929
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For a catalyst system that works efficiently at room temperature see: Littke, A. F.; Fu, G. C. J. Am. Chem. Soc. 2001, 123, 6869.
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Littke, A.F.1
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0000576638
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van de Kuil, L. A.; Luitjes, H.; Grove, D. M.; Zwikker, J. W.; van der Linden, J. G. M.; Roelofsen, A. M.; Jenneskens, L.W.; Drenth, W.; van Koten, G. Organometallics 1994, 13, 468.
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Van Koten, G.9
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29
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0011503078
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unpublished results
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Related Pd(CNC) complexes were found to be hygroscopic as well: Miecznikowski, J. R.; Crabtree, R. H. unpublished results.
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Miecznikowski, J.R.1
Crabtree, R.H.2
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0001271448
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