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Volumn 645, Issue 1-2, 2002, Pages 192-200

Ruthenium-catalyzed hydrosilylation of terminal alkynes: Stereodivergent synthesis of (E)- and (Z)-alkenylsilanes

Author keywords

Alkenylsilanes; Alkynes; Hydrosilylation; Ruthenium catalysts; Stereodivergent synthesis

Indexed keywords

ALKYNE DERIVATIVE; AMMONIUM FLUORIDE; CROSS LINKING REAGENT; RUTHENIUM; SILANE DERIVATIVE; TETRABUTYLAMMONIUM; TOLUENE DERIVATIVE;

EID: 0036159035     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0022-328X(01)01319-5     Document Type: Article
Times cited : (105)

References (35)
  • 24
    • 0008246520 scopus 로고    scopus 로고
    • An excess amount of alkyne is known to improve the stereoselectivity by suppressing isomerization of (Z)-alkenylsilane to thermodynamically more stable (E)-isomer [8a].
  • 25
    • 0008206057 scopus 로고    scopus 로고
    • Since no details of reaction conditions have been reported [9], we are uncertain the reported reaction to be checked precisely.
  • 26
    • 0008242429 scopus 로고    scopus 로고
    • 2Ph may proceed via process (v) which involves prior dissociation of phospine ligand (Scheme 2), while the detail of reaction could not be confirmed owing to the of 6b.
  • 27
    • 0008208442 scopus 로고    scopus 로고
    • Note that the present discussion never excludes the direct formation path of 5b from 4b and hydrosilane [9].


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.