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Volumn 127, Issue 18, 2005, Pages 6766-6779

A charge-transfer-induced spin transition in a discrete complex: The role of extrinsic factors in stabilising three electronic isomeric forms of a cyanide-bridged Co/Fe cluster

Author keywords

[No Author keywords available]

Indexed keywords

CHARGE TRANSFER; COMPLEXATION; CRYSTALLINE MATERIALS; ELECTRONIC STRUCTURE; ISOMERS; MOSSBAUER SPECTROSCOPY; PHASE TRANSITIONS; SOLVENTS; X RAY CRYSTALLOGRAPHY;

EID: 18644366410     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja043162u     Document Type: Article
Times cited : (145)

References (99)
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    • published online February 9
    • Beltran, L. M. C.; Long, J. R. Acc. Chem. Res. 2005, published online February 9, http://dx.doi.org/10.1021/ar040158e.
    • (2005) Acc. Chem. Res.
    • Beltran, L.M.C.1    Long, J.R.2
  • 64
    • 18644369833 scopus 로고    scopus 로고
    • Ph.D. Dissertation, Texas A&M University, College Station, TX
    • Berlinguette, C. P. Ph.D. Dissertation, Texas A&M University, College Station, TX, 2004.
    • (2004)
    • Berlinguette, C.P.1
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    • 18644363475 scopus 로고    scopus 로고
    • Bruker AXS, Inc.: Madison, WI
    • Bruker. SMART Software for Windows NT; Bruker AXS, Inc.: Madison, WI, 2001.
    • (2001) SMART Software for Windows NT
  • 69
    • 18644363341 scopus 로고    scopus 로고
    • Bruker AXS, Inc.: Madison, WI
    • Bruker. SADABS; Bruker AXS, Inc.: Madison, WI, 2001.
    • (2001) SADABS
  • 73
    • 18644375839 scopus 로고    scopus 로고
    • note
    • Weak diffraction powder patterns of the blue and red solids precluded structural investigations of these phases.
  • 82
    • 18644375759 scopus 로고    scopus 로고
    • note
    • 3-.
  • 83
    • 18644384370 scopus 로고    scopus 로고
    • note
    • -1.
  • 86
    • 18644367008 scopus 로고    scopus 로고
    • note
    • Spectra collected on samples that were placed under vacuum for various time intervals are submitted as Supporting Information.
  • 91
    • 18644364633 scopus 로고    scopus 로고
    • note
    • Measurements on the red crystals were carried out by placing an MeCN suspension of the crystals in a gelatin capsule and coating it with eicosane to prevent MeCN evaporation in the vacuum atmosphere of the SQUID chamber. The layer of MeCN prevented contact of the sample with the warm eicosane (mp 34 °C). To properly fit the data, it was necessary to measure the sample and solvent without eicosane at T < 220 K (the mp of MeCN).
  • 93
    • 18644367589 scopus 로고    scopus 로고
    • note
    • The blue and red solid phases can be produced reversibly by exposure to humidity/vacuum.
  • 97
    • 18644362962 scopus 로고    scopus 로고
    • note
    • The spectrum of the red solid form of 1 does not reveal a band in the visible range due to the fact that the sample prepared in the KBr pellet was too dilute.
  • 99
    • 0003652233 scopus 로고
    • Kluwer Academic Publishers: Dordrecht
    • Hendrickson, D. N. NATO ASI Series C (Kluwer Academic Publishers: Dordrecht) 1991, 343, 67-90.
    • (1991) NATO ASI Series C , vol.343 , pp. 67-90
    • Hendrickson, D.N.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.