A charge-transfer-induced spin transition in the discrete cyanide-bridged complex {[Co(tmphen)2]3[Fe(CN)6]2}

Journal of the American Chemical Society

Volumn 126, Issue 20, 2004, Pages 6222-6223

  Berlinguette, Curtis P ^a   Dragulescu Andrasi, Alina ^b   Sieber, Andreas ^c   Galán Mascarós, José Ramón ^d   Güdel, Hans Ulrich ^c   Achim, Catalina ^b   Dunbar, Kim R ^a  

^a TEXAS A AND M UNIVERSITY   (United States)

^b CARNEGIE MELLON UNIVERSITY   (United States)

^c UNIVERSITY OF BERN   (Switzerland)

^d UNIVERSITY OF VALENCIA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

3,4,7,8 TETRAMETHYL 1,10 PHENANTHROLINE; CYANIDE; FERROCYANIDE; PHENANTHROLINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; COMPLEX FORMATION; CRYSTAL STRUCTURE; FOURIER TRANSFORMATION; ISOMERISM; MOSSBAUER SPECTROSCOPY; STRUCTURE ANALYSIS; SURFACE CHARGE; TEMPERATURE MEASUREMENT;

EID: 2442685399     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja039451k     Document Type: Article

References (24)

1. Dunbar, K. R.; Heintz, R. A. Prog. Inorg. Chem. 1997, 45, 283-391.
2. Holmes, S. M.; Girolami, G. S. J. Am. Chem. Soc. 1999, 121, 5593-5594.
3. Beauvais, L. G.; Long, J. R. J. Am. Chem. Soc. 2002, 124, 12096-12097.
4. Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Science 1996, 272, 704-705.
5. Zhong, Z. J.; Seino, H.; Mizobe, Y.; Hidai, M.; Fujishima, A.; Ohkoshi, S.; Hashimoto, K. J. Am. Chem. Soc. 2000, 122, 2952-2953.
6. Larionova, J.; Gross, M.; Pilkington, M.; Andres, H.; Stoeckli-Evans, H. ; Güdel, H. U.; Decurtins, S. Angew. Chem., Int. Ed. 2000, 39, 1605-1609.
7. Berlinguette, C. P.; Vaughn, D.; Canada-Vilalta, C.; Galá n-Mascarós, J. R.; Dunbar, K. R. Angew. Chem., Int. Ed. 2003, 42, 1523-1526.
8. Lescouezec, R.; Vaissermann, J.; Ruiz-Perez, C.; Lloret, F.; Carrasco, R.; Julve, M.; Verdaguer, M.; Dromzee, Y.; Gatteschi, D.; Wernsdorfer, W. Angew. Chem., Int. Ed. 2003, 42, 1483-1486.
9. Bernhardt, P. V.; Macpherson, B. P.; Martinez, M. J. Chem. Soc., Dalton Trans. 2002, 1435-1441.
10. Bernhardt, P., V.; Macpherson, B. P.; Martinez, M. Inorg. Chem. 2000, 39, 5203-5208.
11. Oshio, H.; Onodera, H.; Tamada, O.; Mizutani, H.; Hikichi, T.; Ito, T. Chem.-Eur. J. 2000, 6, 2523-2530.
12. Shimamoto, N.; Ohkoshi, S.; Sato, O.; Hashimoto, K. Inorg. Chem. 2002, 41, 678-684.
13. The synthesis of 1 is available in the Supporting Information.
14. -1, F(000) = 4468, 38 768 measured reflections, 12 433 unique reflections, λ = 0.71073 Å, 1379 parameters for 12 433 independent reflections with I > 4σ(I) gave R1 = 0.0765, wR2 = 0.2234.
15. -1, F(000) = 4576, 45 873 measured reflections, 12 158 unique reflections, λ = 0.71073 Å, 1399 parameters for 12 158 independent reflections with I > 4σ(I) gave R1 = 0.0760, wR2 = 0.2058.
16. 2O molecules) in voids for which the size does not vary with temperature.
17. Sieber, R.; Decurtins, S.; Stoeckli-Evans, H.; Wilson, C.; Yufit, D.; Howard, J. A. K.; Capelli, S. C.; Hauser, A. Chem.-Eur. J. 2000, 6, 361-368.
18. Berlinguette, C. P.; Galán-Mascarós, J. R.; Dunbar, K. R. Inorg. Chem. 2003, 42, 3416-3422.
19. Bernhardt, P. V.; Martinez, M. Inorg. Chem. 1999, 38, 424-425.
20. Greenwood, N. N.; Gibb, T. C. Mössbauer Spectroscopy; Chapman and Hall: New York, 1971; p 656.
21. III ratio varies between 40:60 and 60:40 depending on the size of the red crystals.
22. Zimmermann, R.; Münck, E.; Brill, W. J.; Shah, V. K.; Henzl, M. T.; Rawlings, J.; Orme-Johnson, W. H. Biochim. Biophys. Acta 1978, 537, 185-207.
23. 2O.
24. II.