[(Tp)8(H2O)6CuII 6FeIII8(CN)24]4+: A cyanide-bridged face-centered-cubic cluster with single-molecule-magnet behavior

Angewandte Chemie - International Edition

Volumn 43, Issue 44, 2004, Pages 5940-5943

  Wang, Shi ^a   Zuo, Jing Lin ^a   Zhou, Hong Cai ^b   Choi, Hye Jin ^c   Ke, Yanxiong ^b   Long, Jeffrey R ^c   You, Xiao Zeng ^a  

^a NANJING UNIVERSITY   (China)

^b MIAMI UNIVERSITY   (United States)

^c UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

Cluster compounds; Cyanides; Iron; Magnetic properties; Single molecule magnets

Indexed keywords

COPPER COMPOUNDS; IRON COMPOUNDS; MAGNETIC ANISOTROPY; SYNTHESIS (CHEMICAL);

ANIONIC PRECURSORS; HYDROTRIS; SINGLE-MOLECULE-MAGNETS;

COMPLEXATION;

BORIC ACID; COPPER; CYANIDE; HYDROTRIS(PYRAZOLYL)BORATE; IRON; UNCLASSIFIED DRUG; WATER;

ANISOTROPY; ARTICLE; CHEMICAL STRUCTURE; MAGNETISM; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

COPPER; CRYSTALLOGRAPHY, X-RAY; IRON; MAGNETICS; MODELS, MOLECULAR; ORGANOMETALLIC COMPOUNDS; TEMPERATURE;

EID: 9244236525     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461515     Document Type: Article

References (39)

1. E. D. Dahlberg, J.-G. Zhu, Phys. Today 1995, 48, 34.
2. a) G. P. Berman, G. D. Doolen, D. D. Holm, V. I. Tsifrinovich, Phys. Lett. A 1994,193, 444;
3. b) D. A. Garanin, E. M. Chudnovsky, Phys. Rev. B 1997, 56, 11102.
4. a) J. R. Friedman, M. P. Sarachik, J. Tejada, R. Ziolo, Phys. Rev. Lett. 1996, 76, 3830;
5. b) W. Wernsdorfer, R. Sessoli, Science 1999, 284, 133.
6. a) G. Christou, D. Gatteschi, D. N. Hendrickson, R. Sessoli, MRS Bull. 2000, 25, 66;
7. b) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278; Angew. Chem. Int. Ed. 2003, 42, 268.
8. b) D. Gatteschi, R. Sessoli, Angew. Chem. 2003, 115, 278; Angew. Chem. Int. Ed. 2003, 42, 268.
9. a) A. L. Barra, P. Debrunner, D. Gatteschi, C. E. Schultz, R. Sessoli, Europhys. Lett. 1996, 35, 133;
10. b) A. L. Barra, P. Debrunner, R. Sessoli, Chem. Eur. J. 2000, 6, 1608.
11. S. L. Castro, Z. M. Sun, C. M. Grant, J. C. Bollinger, D. N. Hendrickson, G. Christou, J. Am. Chem. Soc. 1998, 120, 2365.
12. a) E. C. Yang, D. N. Hendrickson, W. Wernsdorfer, M. Nakano, L. N. Zakharov, R. D. Sommer, A. L. Rheingold, M. Ledezmagairaud, G. Christou, J. Appl. Phys. 2002, 91, 7382;
13. b) M. Murrie, S. J. Teat, H. Stœckli-Evans, H. U. Güdel, Angew. Chem. 2003, 115, 4801; Angew. Chem. Int. Ed. 7003, 42, 4653.
14. b) M. Murrie, S. J. Teat, H. Stœckli-Evans, H. U. Güdel, Angew. Chem. 2003, 115, 4801; Angew. Chem. Int. Ed. 2003, 42, 4653.
15. a) S. T. Ochsenbein, M. Murrie, E. Rusanov, H. Stœckli-Evans, C. Sekine, H. U. Güdel, Inorg. Chem. 2002, 41, 5133;
16. b) H. Andres, R. Basler, A. J. Blake, C. Cadiou, G. Chaboussant, C. M. Grant, H. U. Güdel, M. Murrie, S. Parsons, C. Paulsen, F. Semadini, V. Villar, W. Wernsdorfer, R. E. P. Winpenny, Chem. Eur. J. 2002, 8, 4867.
17. H. Weihe, H. U. Güdel, Comments Inorg. Chem. 2000, 22, 75.
18. a) T. Maliah, C. Auberger, M. Verdaguer, P. Veillet, J. Chem. Soc. Chem. Commun. 1995, 61;
19. b) V. Marvaud, C. Decroix, A. Scuiller, C. Guyard-Duhayon, J. Vaissermann, F. Gonnet, M. Verdaguer, Chem. Eur. J. 2003, 9, 1677.
20. a) J. L. Heinrich, P. A. Berseth, J. R. Long, Chem. Commun. 1998, 1231;
21. b) P. A. Berseth, J. J. Sokol, M. P. Shores, J. L. Heinrich, J. R. Long, J. Am. Chem. Soc. 2000, 122, 9655;
22. c) M. P. Shores, J. J. Sokol, J. R. Long, J. Am. Chem. Soc. 2002, 124, 2279;
23. d) J. Y. Yang, M. P. Shores, J. J. Sokol, J. R. Long, Inorg. Chem. 2003, 42, 1403.
24. a) K. K. Klausmeyer, T. B. Rauchfuss, S. R. Wilson, Angew. Chem. 1998, 110, 1808; Angew. Chem. Int. Ed. 1598, 37, 1694;
25. a) K. K. Klausmeyer, T. B. Rauchfuss, S. R. Wilson, Angew. Chem. 1998, 110, 1808; Angew. Chem. Int. Ed. 1998, 37, 1694;
26. b) E. J. Schelter, A. V. Provirin, W. M. Reiff, K. R. Dunbar Angew. Chem. 2004,116, 5020; Angew. Chem. Int. Ed. 2004, 43, 4912.
27. b) E. J. Schelter, A. V. Provirin, W. M. Reiff, K. R. Dunbar Angew. Chem. 2004,116, 5020; Angew. Chem. Int. Ed. 2004, 43, 4912.
28. a) J. J. Sokol, A. G. Hee, J. R. Long, J. Am. Chem. Soc. 2002, 124, 7656;
29. b) C. P. Berlinguette, D Vaughn, C. Cañada-Vilalta, J. R. Galán-Mascarós, K. R. Dunbar, Angew. Chem. 2003, 115, 1561; Angew. Chem. Int Ed. 2003, 42, 1523;
30. b) C. P. Berlinguette, D Vaughn, C. Cañada-Vilalta, J. R. Galán-Mascarós, K. R. Dunbar, Angew. Chem. 2003, 115, 1561; Angew. Chem. Int Ed. 2003, 42, 1523;
31. c) H. J. Choi, J. J. Sokol, J. R. Long, Inorg. Chem. 2004, 43, 1606.
32. R. Lescouëzec, J. Vaissermann, F. Lloret, M. Juive, M. Verdaguer, Inorg. Chem. 2002, 41, 5943.
33. S. Wang, J.-L. Zuo, S. Gao, Y. Song, H.-C. Zhou, Y.-Z. Zhang, X.-Z. You, J. Am. Chem. Soc. 2004, 720, 8900.
34. 2 = 0.1363 (I> 2σ(I)) for 23664 data (3882 independent), 470 parameters, and 15 restrains. Data were collected on a Bruker Apex CCD diffractometer. Absorption corrections were applied for 2 using SADABS supplied by Bruker. The structure was solved by direct methods and refined by full-matrix least-squares methods using SHELXTL-97. In the structure of 2, all the atoms of the Tp ligands and some hydrogen atoms are disordered. CCDC-246475 (2) contains the supplementary Crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/ retrieving.html (or from the Cambridge Crystallographic Data Centre, 12 Union Road. Cambridge CB21EZ, UK; fax: (+44)1223-336-033; or deposit@ccdc.cam.ac.uk).
35. J. J. Borrás-Almenar, J. M. Clemente-Juan, E. Coronado, B. S. Tsukerblat, J. Comput. Chem. 2001, 22, 985.
36. a) H.-Z. Kou, D-Z. Liao, P. Cheng, Z.-H. Jiang, S.-P. Yan, G.-L. Wang, X.-K. Yao, H.-G. Wang, J. Chem. Soc. Dalton Trans. 1997, 1503;
37. b) M. Salah El Fallah, J. Ribas, X. Solans, M. Font-Bardia, J. Chem. Soc. Dalton Trans. 2001, 247;
38. c) H. Oshio, M. Yamamoto, T. Ito, Inorg. Chem. 2002, 41, 5817;
39. d) M. K. Saha, F. Lloret, I. Bernal, Inorg. Chem. 2004, 43, 1969.