A high-spin cyanide-bridged Mn9W6 cluster (S = 39/2) with a full- capped cubane structure [5]

Journal of the American Chemical Society

Volumn 122, Issue 12, 2000, Pages 2952-2953

  Zhong, Zhuang Jin ^a   Seino, Hidetake ^b   Mizobe, Yasushi ^b   Hidai, Masanobu ^a   Fujishima, Akira ^a   Ohkoshi, Shin Ichi ^c   Hashimoto, Kazuhito ^a,c  

^a UNIVERSITY OF TOKYO   (Japan)

^b INSTITUTE OF INDUSTRIAL SCIENCE   (Japan)

^c UNIVERSITY OF TOKYO   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CUBANE DERIVATIVE; CYANIDE;

CRYSTAL STRUCTURE; LETTER; MAGNETISM; REACTION ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 0000230530     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja992622u     Document Type: Letter

References (28)

1. Kahn, O. Molecular Magnetism; VCH: New York, 1993.
2. Miller, J. S.; Epstein, A. J. Angew. Chem., Int. Ed. Engl. 1994, 33, 385.
3. Gatteschi, D. et al. Magnetic Molecular Materials; Kluwer: Dordrecht, 1991.
4. Tamaki, H.; Zhong, Z. J.; Matsumoto, N.; Kida, S.; Koikawa, M.; Achiwa, N.; Hashimoto, Y.; Okawa, H. J. Am. Chem. Soc. 1992, 114, 6974.
5. Mallah, T.; Thiebaut, S.; Verdaguer, M.; Veillet, P. Science 1993, 262, 1554.
6. William, R. E.; Girolami, G. S. Inorg. Chem. 1994, 33, 5165.
7. Ohkoshi, S.; Fujishima, K.; Hashimoto, K. J. Am. Chem. Soc. 1998, 120, 5349.
8. (a) Sato, O.; Iyoda, T.; Fujishima, A.; Hashimoto, K. Science 1996, 272, 704.
9. (b) Ohkoshi, S.; Yorozu; S.; Sato, O.; Iyoda, T.; Fujishima, K.; Hashimoto, K. Appl. Phys. Lett. 1997, 70, 1040.
10. Gütlich, P.; Hauser, A.; Spiering, H. Angew. Chem., Int. Ed. Engl. 1994, 33, 2024.
11. Ferlay, S.; Mallah, T.; Quahes, R.; Veillet, P.; Verdaguer, M. Nature 1995, 378, 701.
12. (a) Awschalom, D. D.; Di Vicenzo, D. P. Phys. Today 1995, 48, 43.
13. (b) Dahlberg, E. D.; Zhu, J.-G. Phys. Today 1995, 48, 34.
14. (a) Sessoli, R.; Tsai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D., Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804.
15. (b) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 365, 141.
16. (c) Thomas, L.; Lionti, F.; Ballou, R.; Gatteschi, D.; Sessoli, R.; Babara, B. Nature 1996, 383, 145.
17. Aubin, S. M. J.; Dilley, N. R.; Pardi, L.; Krzystek, J.; Wemple, M. W.; Brunel, L.-C.; Maple, M. B.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1998, 120, 4991.
18. Barra, A. L.; Debrunner, P.; Gatteschi, D.; Schultz, C. E.; Sessoli, R. Europhys. Lett. 1996, 35, 133.
19. Pilawa, B.; Kelemen, M. T.; Wanka, S.; Geisselmann, A.; Barra, A. L. Europhys. Lett. 1998, 43, 7.
20. (a) Abbati, G. L.; Cornia, A.; Fabretti, A. C.; Caneschi, A.; Gatteschi, D. Inorg. Chem. 1998, 37, 1430.
21. (b) Caneschi, A.; Gatteschi, D.; Laugier, J.; Rey, P.; Sessoli, R.; Zanchini, C. J. Am. Chem. Soc. 1988, 110, 2759.
22. (c) Aromi, G.; Claude, J.-P.; Knapp, M. J.; Huffman, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1998, 120, 2977.
23. Scuillier, A.; Mallah, T.; Verdaguer, M.; Nivorozkhin; Tholence, J. L.; Veillet, P. New J. Chem. 1996, 20, 1.
24. Goldberg, D. P.; Caneschi, A.; Delfs, C. D.; Sessoli, R.; Lippard, S. J. J. Am. Chem. Soc. 1995, 117, 5789.
25. Powell, A. K.; Heath, S. L.; Gatteschi, D.; Pardi, L.; Sessoli, R.; Spina, G.; Giallo, F. D.; Pieralli, F. J. Am. Chem. Soc. 1995, 117, 2491.
26. Leipoldt, J. G.; Bok, L. D. C.; Cilliers, P. J. Z. Anorg. Allg. Chem. 1974, 407, 350.
27. w)= 0.047 (0.043) using 251.3 reflections with I > 3.00 σ(I). The non-hydrogen atoms were refined anisotropically, and the hydrogen atoms were included at calculated positions. All calculations were performed using the teXan crystallographic software package of Molecular Structure Corporation.
28. Castro, S. L.; Sun, Z.; Grant, C. M.; Bollinger, J. C.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 1998, 120, 2365.