Directed assembly of metal-cyanide cluster magnets

Accounts of Chemical Research

Volumn 38, Issue 4, 2005, Pages 325-334

  Beltran, Lianne M C ^a   Long, Jeffrey R ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 20344392400     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar040158e     Document Type: Article

References (28)

1. 4]. J. Am. Chem. Soc. 1993, 115, 1804-1816.
2. (b) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Magnetic Bistability in a Metal-Ion Cluster. Nature 1993, 365, 141-143.
3. Long, J. R. Molecular Cluster Magnets. In Chemistry of Nanostructured Materials; Yang, P., Ed.; World Scientific: Hong Kong, 2003; pp 291-315 and references therein.
4. 4]. Inorg. Chem. Commun. 2001, 4, 511-514.
5. Weihe, H.; Güdel, H. U. Magnetic Exchange Across the Cyanide Bridge. Comments Inorg. Chem. 2000, 22, 75-103.
6. (a) Ferlay, S.; Mallah, T.; Ouahès, R.; Veillet, P.; Verdaguer, M. A Room-Temperature Organometallic Magnet Based on Prussian Blue. Nature 1995, 378, 701-703.
7. 2O: A Crystalline Molecule-Based Magnet with a Magnetic Ordering Temperature Above 100°C. J. Am. Chem. Soc. 1999, 121, 5593-5594.
8. 6 Complex with a Low-Lying S = 15/2 Ground State. J. Chem. Soc., Chem. Commun. 1995, 61-62.
9. 6 (S = 39/2) with a Full-Capped Cubane Structure. J. Am. Chem. Soc. 2000, 122, 2952-2953.
10. v Molecular Cluster with a S = 51/2 Ground State and Ferromagnetic Intercluster Ordering at Low Temperatures. Angew. Chem., Int. Ed. 2000, 39, 1605-1609.
11. 2}. Angew. Chem., Int. Ed. 2003, 42, 1523-1526.
12. 12 Clusters. Chem. Commun. 1998, 1231-1232.
13. 24 Cage with a Face-Centered Cubic Geometry. J. Am. Chem. Soc. 2000, 122, 9655-9662.
14. 4+, an "Organometallic Box". Angew. Chem., Int. Ed. 1998, 37, 1694-1696.
15. +. J. Am. Chem. Soc. 1999, 121, 2705-2711.
16. 3] (M = Cr, Fe, Co) Complexes. Inorg. Chem. 2003, 42, 1403-1419.
17. 25 Complex with a Record S = 51/2 Spin for a Molecular Species. J. Am. Chem. Soc. 2004, 126, 4766-4767.
18. 3]. J. Am. Chem. Soc. 2002, 124, 2279-2292.
19. Schmitt, E. A. Ph.D. Thesis, University of Illinois, 1995.
20. 42 Cluster Incorporating Three Forms of Cyanonickelate. Angew. Chem., Int. Ed. 2001, 40, 236-239.
21. 48 Species. Inorg. Chem. 2002, 41, 3052-3054.
22. 9 Chain Compound. J. Solid State Chem. 2001, 159, 293-301.
23. Shores, M. P.; Long, J. R. Tetracyanide-Bridged Divanadium Complexes: Redox Switching Between Strong Antiferromagnetic and Strong Ferromagnetic Coupling. J. Am. Chem. Soc. 2002, 124, 3512-3513.
24. 5-. J. Am. Chem. Soc. 2002, 124, 2110-2111.
25. 18 Cluster. J. Am. Chem. Soc. 2002, 124, 7656-7657.
26. Note that it is not always possible to extract the sign of D from magnetization data, and here its assignment as negative is inferred from the observation of slow relaxation of the magnetization.
27. Miyasaka, H.; Matsumoto, N.; Okawa, H.; Re, N.; Gallo, E.; Floriani, C. Complexes Derived from the Reaction of Manganese(III) Schiff Base Complexes and Hexacyanoferrate(III): Syntheses, Multidiminensional Network Structures, and Magnetic Properties. J. Am. Chem. Soc. 1996, 118, 981-994.
28. + Units. Inorg. Chem. 2004, 43, 1606-1608.