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19
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0037076070
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In our previous article [S. Ohkoshi, H. Tokoro, M. Utsunomiya, M. Mizuno, M. Abe, and K. Hashimoto, J. Phys. Chem. B 106, 2423 (2002)], we interpreted this phase transition is due to the spin transition between a high-spin state (S = 5/2) and an intermediate-spin state (S = 3/2) of Mn(II) ion. However, the recent results of synchrotron-radiation x-ray powder diffraction and extended x-ray absorption fine structure experiments suggested that the electronic state of the LT phase in Mn(III)(S = 2)-NC-Fe(II)(S = 0) [Y. Moritomo, K. Kato, A. Kuriki, M. Taketa, M. Sakata, H. Tokoro, S. Ohkoshi, and K. Hashimoto, J. Phys. Soc. Jpn. 71, 2078 (2002) and T. Yokoyama, H. Tokoro, S. Ohkoshi, K. Hashimoto, K. Okamoto, and T. Ohta, Phys. Rev. B 66, 184111 (2002)]. Hence, we corrected our model that the phase transition is caused by the change from Mn(II)(S = 5/2)-NC-Fe(III)(S=1/2) to Mn(III)(S = 2)-NC-Fe(II)(S = 0) states with decreasing temperature.
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Ohkoshi, S.1
Tokoro, H.2
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Mizuno, M.4
Abe, M.5
Hashimoto, K.6
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20
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0036919828
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-
In our previous article [S. Ohkoshi, H. Tokoro, M. Utsunomiya, M. Mizuno, M. Abe, and K. Hashimoto, J. Phys. Chem. B 106, 2423 (2002)], we interpreted this phase transition is due to the spin transition between a high-spin state (S = 5/2) and an intermediate-spin state (S = 3/2) of Mn(II) ion. However, the recent results of synchrotron-radiation x-ray powder diffraction and extended x-ray absorption fine structure experiments suggested that the electronic state of the LT phase in Mn(III)(S = 2)-NC-Fe(II)(S = 0) [Y. Moritomo, K. Kato, A. Kuriki, M. Taketa, M. Sakata, H. Tokoro, S. Ohkoshi, and K. Hashimoto, J. Phys. Soc. Jpn. 71, 2078 (2002) and T. Yokoyama, H. Tokoro, S. Ohkoshi, K. Hashimoto, K. Okamoto, and T. Ohta, Phys. Rev. B 66, 184111 (2002)]. Hence, we corrected our model that the phase transition is caused by the change from Mn(II)(S = 5/2)-NC-Fe(III)(S=1/2) to Mn(III)(S = 2)-NC-Fe(II)(S = 0) states with decreasing temperature.
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J. Phys. Soc. Jpn.
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Moritomo, Y.1
Kato, K.2
Kuriki, A.3
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Sakata, M.5
Tokoro, H.6
Ohkoshi, S.7
Hashimoto, K.8
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21
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0012581203
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In our previous article [S. Ohkoshi, H. Tokoro, M. Utsunomiya, M. Mizuno, M. Abe, and K. Hashimoto, J. Phys. Chem. B 106, 2423 (2002)], we interpreted this phase transition is due to the spin transition between a high-spin state (S = 5/2) and an intermediate-spin state (S = 3/2) of Mn(II) ion. However, the recent results of synchrotron-radiation x-ray powder diffraction and extended x-ray absorption fine structure experiments suggested that the electronic state of the LT phase in Mn(III)(S = 2)-NC-Fe(II)(S = 0) [Y. Moritomo, K. Kato, A. Kuriki, M. Taketa, M. Sakata, H. Tokoro, S. Ohkoshi, and K. Hashimoto, J. Phys. Soc. Jpn. 71, 2078 (2002) and T. Yokoyama, H. Tokoro, S. Ohkoshi, K. Hashimoto, K. Okamoto, and T. Ohta, Phys. Rev. B 66, 184111 (2002)]. Hence, we corrected our model that the phase transition is caused by the change from Mn(II)(S = 5/2)-NC-Fe(III)(S=1/2) to Mn(III)(S = 2)-NC-Fe(II)(S = 0) states with decreasing temperature.
-
(2002)
Phys. Rev. B
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, pp. 184111
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Yokoyama, T.1
Tokoro, H.2
Ohkoshi, S.3
Hashimoto, K.4
Okamoto, K.5
Ohta, T.6
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24
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0012584581
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note
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2O exhibits antiferro-magnetic behaviors with Néel temperature of 12.5 K. To understand this unusual antiferromagnetic behavior, we are planning to measure the neutron diffraction of the HT phase.
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