Oxidation of mixed-valence CoIII/FeII complexes reversed at high pH: A kinetico-mechanistic study of water oxidation

Inorganic Chemistry

Volumn 43, Issue 22, 2004, Pages 7187-7195

  Bernhardt, Paul V ^a   Bozoglian, Fernando ^b   Macpherson, Brendan P ^a   Martínez, Manuel ^b   Merbach, André E ^c   González, Gabriel ^b,e   Sienra, Beatriz ^d  

^a UNIVERSITY OF QUEENSLAND   (Australia)

^b UNIVERSITY OF BARCELONA   (Spain)

^c Institut de chimie moleculaire et biologique Ecole Polytechnique Federale de Lausanne   (Switzerland)

^d UNIVERSIDAD DE LA REPÚBLICA   (Uruguay)

^e INSTITUTE OF CHEMICAL RESEARCH OF CATALONIA ICIQ   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

COBALT COMPLEX; CYANIDE; HYDROGEN PEROXIDE; IRON COMPLEX; METAL COMPLEX; NITROGEN; OXYGEN; WATER;

ARTICLE; COMPLEX FORMATION; ELECTROCHEMISTRY; ELECTRON TRANSPORT; HYDROGEN BOND; KINETICS; OXIDATION REDUCTION REACTION; PH; STOICHIOMETRY; SYNTHESIS; ULTRAVIOLET SPECTROSCOPY; X RAY CRYSTALLOGRAPHY;

EID: 7244238205     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0493191     Document Type: Article

References (55)

1. Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247-422.
2. Lescouezec, R.; Vaissermann, J.; Ruiz-Pérez, C.; Lloret, F.; Carrasco, R.; Julve, M.; Verdager, M.; Dromzee, Y.; Gatteschi, D.; Wernsdorfer, W. Angew. Chem., Int. Ed. 2003, 42, 1483-1486.
3. Toma, L. M.; Lescouezec, R.; Lloret, F.; Julve, M.; Vaissermann, J.; Verdager, M. Chem. Commun. 2003, 1850-1851.
4. Rosseinsky, D. R.; Mortimer, R. J. Adv. Mater. 2001, 13, 783-793.
5. Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391-444.
6. Haim, A. Comments Inorg. Chem. 1985, 4, 113-149.
7. Khoshtariya, D. E.; Bajaj, H. C.; Tregloan, P.; van Eldik, R. J. Phys. Chem. A 2000, 104, 5535-5544.
8. Almaraz, A. E.; Gentil, L. A.; Baraldo, L. M.; Olabe, J. A. Inorg. Chem. 1996, 35, 7718-7727.
9. Parise, A. R.; Baraldo, L. M.; Olabe, J. A. Inorg. Chem. 1996, 35, 5080-5086.
10. Bernhardt, P. V.; Macpherson, B. P.; Martínez, M. Inorg. Chem. 2000, 39, 5203-5208.
11. Bernhardt, P. V.; Macpherson, B. P.; Martínez, M. J. Chem. Soc., Dalton Trans. 2002, 1435-1441.
12. Bernhardt, P. V.; Martinez, M. Inorg. Chem. 1999, 38, 424-425.
13. Alzouibi, B. M.; Bernhardt, P. V.; Macpherson, B. P.; Martínez, M.; Tregloan, P.; van Eldik, R. Unpublished results.
14. López-Pérez, G.; Prado-Gotor, R.; Sánchez, F.; López-López, M.; González-Arjona, D.; Pérez-Tejeda, P.; Bozoglián, F.; González, G.; Martínez, M. Submitted.
15. Bernhardt, P. V.; Bozoglián, F.; Macpherson, B. P.; Martínez, M.; Gonzalez, G.; Sienra, B. Eur. J. Inorg. Chem. 2003, 2512-2518.
16. Bernhardt, P. V.; Bozoglián, F.; Macpherson, B. P.; Martínez, M. Dalton Trans. 2004, 2582-2587.
17. Warren, R. M. L.; Lappin, A. G.; Tatehata, A. Inorg. Chem. 1992, 31, 1566-1574.
18. Murray, R. S. J. Chem. Soc., Dalton Trans. 1974, 2381-2383.
19. Wilkins, R. G. Kinetics and Mechanisms of Reactions of Transition Metal Complexes; VCH: Weinheim, 1991.
20. Lawrance, G. A.; Martínez, M.; Skelton, B. W.; White, A. H. Aust. J. Chem. 1991, 44, 113-121.
21. Perkampus, H. H. UV-Vis Spectroscopy and Its Applications; Springer: Berlin, 1992.
22. Binstead, R. A.; Zuberbühler, A.; Jung, B. SPECFIT [3.0.34], 2003.
23. Farrugia, L. J. J. Appl. Crystallogr. 1999, 32, 837-838.
24. Sheldrick, G. M. SHELX-97: Programs for Crystal Structure Analysis [Release 97-2], Institut für Anorganishe Chemie, Universität Göttingen: Germany, 1998.
25. Farrugia, L. J. J. Appl. Crystallogr. 1997, 30, 565.
26. Martínez, M.; Pitarque, M.; van Eldik, R. Inorg. Chim. Acta 1997, 250, 51-59.
27. Bugnon, P.; Laurency, G.; Ducommun, Y.; Sauvegeat, P.; Merbach, A. E. Anal. Chem. 1996, 68, 3045-3049.
28. Jiang, Z. Y.; Woollard, A. C. S.; Wolff, S. P. Lipids 1991, 26, 853-586.
29. Nourooz-Zadeh, J.; Tajaddini-Sarmadi, J.; Wolff, S. P. Anal. Biochem. 1994, 220, 406-409.
30. Marsh, R. E. Acta Crystallogr. 1995, B51, 897-907.
31. Fagalde, F.; Katz, N. E.; Povse, V. G.; Olabe, J. A. Polyhedron 1998, 18, 25-31.
32. Marusak, R. A.; Osvath, P.; Kemper, M.; Lappin, A. G. Inorg. Chem. 1989, 28, 1542-1548.
33. Bhakare, H. A.; Rao, C. V. N. J. Indian Chem. Soc 1974, 51, 543-544.
34. Thusius, D. D.; Taube, H. J. Am. Chem. Soc. 1966, 88, 850-851.
35. Anbar, M.; Pecht. I. J. Am. Chem. Soc. 1967, 89, 2553-2556.
36. Lancanster, J. M.; Murray, R. S. J. Chem. Soc. A 1971, 2755-2758.
37. Eaton, D. R.; Pankratz, M. Can. J. Chem. 1985, 63, 793-797.
38. Sharpe, A. G. The Chemistry of Cyano Complexes of the Transition Metals: Academic Press: London, 1976.
39. Gallego, C.; González, G.; Martínez, M.; Merbach, A. E. Organometallics 2004, 23, 2434-2438.
40. Geselowitz, D. A.; Hammershoi, A.; Taube, H. Inorg. Chem. 1987, 26, 1842-1845.
41. Martínez, M.; Pitarque, M.; van Eldik, R. J. Chem. Soc., Dalton Trans. 1994, 3159-3163.
42. Martínez, M.; Pitarque, M. A. J. Chem. Soc., Dalton Trans. 1995, 4107-4111.
43. González, G.; Martínez, M.; Rodríguez, E. Eur. J. Inorg. Chem. 2000, 1333-1338.
44. Feig, A. L.; Becker, M.; Schindler, S.; van Eldik, R.; Lippard, S. J. Inorg. Chem. 1996, 35, 2590-2601.
45. Hambley, T. W.; Lawrance, G. A.; Martínez, M.; Skelton, B. W.; White, A. W. J. Chem. Soc., Dalton Trans. 1992, 1643-1648.
46. Schilt, A. J. Am. Chem. Soc. 1960, 82, 3000-3005.
47. Hickel, B.; Sehested, K. J. Phys. Chem. 1991, 95, 744-747.
48. Wander, R.; Gall, B. L.; Dorfman, L. M. J. Phys. Chem. 1970, 74, 1819-1821.
49. Simic, M.; Hoffman, M. Z.; Ebert, M. J. Phys. Chem. 1973, 77, 1117-1120.
50. Autrey, T.; Brown, A. K.; Camaioni, D. M.; Dupuis, M.; Foster, N. S.; Getty, A. J. Am. Chem. Soc. 2004, 126, 3680-3681.
51. Chaterjee, D. Polyhedron 1999, 18, 1767-1771.
52. Benzo, F.; Bernhardt, P. V.; Gonzalez, G.; Martínez, M. J. Chem. Soc., Dalton Trans. 1999, 3973-3979.
53. Bernhardt, P. V.; Gallego, C.; Martínez, M.; Parella, T. Inorg. Chem. 2002, 41, 1747-1754.
54. Ooi, B.; Sykes, A. G. Inorg. Chem. 1988, 27, 310-315.
55. García-Basallote, M.; Martínez, M. Unpublished results.