Estimating the specific heat capacity of starch-water-glycerol systems as a function of temperature and compositions

Starch/Staerke

Volumn 56, Issue 1, 2004, Pages 6-12

  Tan, Ihwa ^a   Wee, Chong C ^b   Sopade, Peter A ^a   Halley, Peter J ^a  

^a UNIVERSITY OF QUEENSLAND   (Australia)

^b DEPARTMENT OF ELECTRONICS AND COMPUTER ENGINEERING   (Singapore)

Author keywords

Amylose; MTDSC; Plasticizers; Thermoplastic starch

Indexed keywords

COMPOSITION; DIFFERENTIAL SCANNING CALORIMETRY; GLYCEROL; PLASTICIZERS; REGRESSION ANALYSIS; SPECIFIC HEAT; TEMPERATURE; THERMOPLASTICS; WATER;

AMYLOSE; MODULATED TEMPERATURE DIFFERENTIAL SCANNING CALORIMETER; THERMOPLASTIC STARCH;

STARCH;

ZEA MAYS;

EID: 1542305565     PISSN: 00389056     EISSN: None     Source Type: Journal    
DOI: 10.1002/star.200300209     Document Type: Article

References (40)

1. K. Arévalo-Niño, C. F. Sandoval, L. J. Galan, S. H. Imam, S. H. Gordon, R. V. Greene: Starch-based extruded plastic films and evaluation of their biodegradable properties. Biodegradation 1996, 7, 231-237.
2. R. L. Shogren: Starch: Properties and Materials Applications, in Biopolymers from Renewable Resources (Ed. D. L. Kaplan), Springer, Medford, USA, 1998.
3. R. L. Shogren, G. F. Fanta, W. M. Doane: Development of starch based plastics - A reexamination of selected polymer systems in historical perspective. Starch/Stärke 1993, 45, 276-280.
4. A. K. Mohanty, M. Misra, G. Hinrichsen: Biofibres, biodegradable polymers and biocomposites: An overview. Macromol. Mater. Eng. 2000, 276-277, 1-24.
5. D. Lourdin, L. Coignard, H. Bizot, P. Colonna: Influence of equilibrium relative humidity and plasticizer content and glass transition of starch materials. Polymer 1997, 38, 5401-5406.
6. D. Demirgroz, C. Elvira, J. F. Mano, A. M. Cunha, E. Piskin, R. L. Reis: Chemical modification of starch based biodegradable polymeric blends: effects on water uptake, degradation behaviour and mechanical properties. Polym. Degrad. Stabil. 2000, 70, 161-170.
7. A. L. M. Smits, S. H. D. Hulleman, J. J. G. Van Soest, H. Feil, J. F. G. Vliegenthart: The influence of polyols on the molecular organization in starch-based plastics. Polym. Advan. Technol. 1999, 10, 570-573.
8. P. H. Kruiskamp, A. L. M. Smits, J. J. G. Van Soest, J. F. G. Vliegenthart: The influence of plasticiser on molecular organisation in dry amylopectin measured by differential scanning calorimetry and solid state nuclear magnetic resonance spectroscopy. J. Ind. Microbiol. Biot. 2001, 26, 90-93.
9. P. B. Shah, S. Bandopadhyay, J. R. Bellare: Environmentally degradable starch filled low density polyethylene. Polym. Degrad. Stabil. 1995, 47, 165-173.
10. T. Seidenstücker, H. G. Fritz: Innovative biodegradable materials based upon starch and thermoplastic poly(esterurethane) (TPU). Polym. Degrad. Stabil. 1998, 59, 279-285.
11. M. Liang, H. E. Huff, F. H. Hsieh: Evaluating energy consumption and efficiency of a twin-screw extruder. J. Food Sci. 2002, 67, 1803-1807.
12. R. V. Chiruvella, Y. Jaluria, M. V. Karwe: Numerical simulation of the extrusion process for food materials in a single screw extruder. J. Food Eng. 1994, 30, 449-467.
13. L. Levine: Estimating moisture flash upon discharge from an extrusion die. Cereal Food World 1997, 42, 144.
14. R. P. Singh, D. R. Heldman: Introduction to food engineering, Academic Press Inc., San Diego, 1993.
15. D. N. Njie, T. R. Rumsey, R. P. Singh: Thermal properties of cassava, yam and plantain. J. Food Eng. 1998, 37, 63-76.
16. P. A. Sopade, G. A. LeGrys: Specific heat capacity of starch-sucrose systems. Food Control 1991, 2, 50-52.
17. T. R. Noel, S. G. Ring: A study of the heat-capacity of starch water mixtures. Carbohydr. Res. 1992, 227, 203-213.
18. V. P. Yur'ev, A. N. Danilenko, I. E. Nemirovskaya, N. D. Lukin, A. N. Zhushman, V. G. Karpov: Molar heat capacity, solubility, and water-retaining capacities of starch samples isolated from various cultivars of potato (Solanum tuberosum). Appl. Biochem. Microb. 1998, 34, 97-100.
19. M. Pyda: Conformational heat capacity of interacting systems of polymer and water. Macromolecules 2002, 35, 4009-4016.
20. M. Pyda: Conformational contribution to the heat capacity of the starch and water system. J. Polym. Sci. Pol. Phys. 2001, 39, 3038-3054.
21. P. Colonna, J. Tayeb: Extrusion cooking of starch and starchy products, in Extrusion cooking (Eds. C. Mercier, P. Linko, J. M. Harper), American Association of Cereal Chemists, Minnesota, USA, 1989.
22. B. Wunderlich, A. Boller, I. Okazaki, K. Ishikiriyama: Heat capacity determination by temperature-modulated DSC and its separation from transition effects. Thermochim. Acta 1997, 304/305, 125-136.
23. V. M. F. Lai, C. Y. Lii: Effects of modulated differential scanning calorimetry (MDSC) variables on thermodynamic and kinetic characteristics during gelatinisation of waxy rice starch. Cereal Chem. 1999, 76, 519-525.
24. TA Instruments: DSC 2920 Operator's Manual, TA Instruments, New Castle, DE 197270, 1996.
25. B. Cuq, C. Icard-Verniere: Characterisation of glass transition of durum wheat semolina using modulated differential scanning calorimetry. J. Cereal Sci. 2001, 33, 213-221.
26. P. De Meuter, H. Rahier, B. Van Mele: The use of modulated temperature differential scanning calorimetry for the characterisation of food systems. Int. J. Pharm. 1999, 192, 77-84.
27. AOAC: Food composition; Additives; Natural contaminants, in Official methods of analysis, Vol. 2, 15th, Association of Official Analytical Chemists, Virginia, 1990.
28. W. Yang, S. Sokhansanj, J. Tang, P. Winter: Determination of thermal conductivity, specific heat and thermal diffusivity of borage seeds. Biosyst. Eng. 2002, 82, 169-176.
29. G. Nashed, R. P. G. Rutgers, P. A. Sopade: The plasticisation effect of glycerol and water on the gelatinisation of wheat starch. Starch/Stärke 2003, 55, 131-137.
30. I. D. Evans, D. R. Haisman: The effect of solutes on the gelatinization temperature range of potato starch. Starch/Stärke 1982, 34, 224-231.
31. R. I. Derby, B. S. Miller, B. R. Miller, H. B. Trimbo: Visual observation of wheat-starch gelatinization in limited water systems. Cereal Chem. 1975, 52, 702-713.
32. R. P. H. Gasser, W. G. Richards: An Introduction to Statistical Thermodynamics, World Scientific Publishing Co. Pte. Ltd., River Edge, N.J., 1995.
33. P. J. Jenkins, A. M. Donald: Gelatinisation of starch: a combined SAXS/WAXS/DSC and SANS study. Carbohydr. Res. 1998, 308, 133-147.
34. P. J. Jenkins, A. M. Donald: The influence of amylose on starch granule structure. Int. J. Biol. Macromol. 1995, 17, 315-321.
35. P. A. Perry, A. M. Donald: SANS study of the distribution of water within starch granules. Int. J. Biol. Macromol. 2000, 28, 31-39.
36. N. W. H. Cheetham, L. Tao: Variation in crystalline type with amylose content in maize starch granules: an X-ray powder diffraction study. Carbohydr. Polym. 1998, 36, 277-284.
37. Y. Marcus: Some thermodynamic and structural aspects of mixtures of glycerol with water. Phys. Chem. Chem. Phys. 2000, 2, 4891-4896.
38. J. Mottaz, L. Bruyas: Optimised thermal performance in extrusion, in Extrusion cooking. Technologies and applications (Ed. R. Guy), Woodhead Publishing Limited, Cambridge, Eng., 2001.
39. D. G. Baird and C. M. Reed: Transport properties of food doughs, in Extrusion cooking (Eds. C. Mercier, P. Linko, J. M. Harper), American Association of Cereal Chemists, Inc., St Paul, Minnesota, USA, 1989.
40. M. C. Righetti, G. Salvetti, E. Tombari: Heat capacity of glycerol from 298 to 383 K. Thermochem. Acta 1998, 316, 193-195.