X-ray absorption spectroscopy and anomalous wide angle X-ray scattering: Two basic tools in the analysis of heterogeneous catalysts

Oil and Gas Science and Technology

Volumn 58, Issue 6, 2003, Pages 667-683

  Bazin, D ^a   Lynch, J ^b   Ramos Fernandez, M ^b  

^a UNIVERSITÉ PARIS SACLAY   (France)

^b IFP ENERGIES NOUVELLES   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ABSORPTION SPECTROSCOPY; SYNCHROTRON RADIATION; X RAY SCATTERING; X RAY SPECTROSCOPY;

ATOMIC LEVELS; X-RAY ABSORPTION SPECTROSCOPY (XAS);

CATALYSTS;

CATALYST; PHYSICOCHEMICAL PROPERTY;

EID: 1242332811     PISSN: 12944475     EISSN: None     Source Type: Journal    
DOI: 10.2516/ogst:2003047     Document Type: Article

References (166)

1. Somorjai, G.A (1994) Principles of Surface Chemistry and Catalysis. Ed. J. Wiley, New York.
2. Thomas, J.M., Johnson, B.F.G., Raja, R., Sankar, G. and Midgley, P.A. (2002) High-Performance Nanocatalysts for Single-Step Hydrogenations. Acc. Chem. Res., accepted.
3. Somorjai, G.A. and McCrea, K. (2001) Roadmap for Catalysis Science in the 21st Century: A Personal View of Building the Future on Past and Present Accomplishments. Applied Catalysis A, 222, 3.
4. Jacobs, P.W. and Somorjai, G.A. (1998) Conversion of Heterogeneous Catalysis from Art to Science: The Surface Science of Heterogeneous Catalysis. Journal of Molecular Catalysis A: Chemical, 131, 5.
5. Bazin, D. and Guczi, L. (1999) New Opportunities to Understand the Properties on Nanomaterials Through S.R. and Theoretical Calculations. Recent Res. Dev. Phys. Chem., 3, 387.
6. Boudart, M. (2000) Model Catalysts: Reductionism for Understanding. Topics in Catalysis, 13, 147.
7. Sinfelt, J.H. (2002) Role of Surface Science in Catalysis. Surface Science, 500, 923.
8. Frenkel, A.I., Hills, C.W. and Nuzzo, R.G. (2001) A View from the Inside: Complexity in the Atomic Scale Ordering of Supported Metal Nanoparticles. J. Phys. Chem. B., 105, 12689.
9. Garin, F. (2001) Mechanism of NOx Decomposition. Applied Catalysis A: General, 222, 183.
10. Sautet, Ph. (2000) Theoretical Chemistry as a Tool for Interpreting Catalysts Selectivities. Topics in Catalysis, 13, 219.
11. 2 Induced by Working Conditions: a Theoretical Study. Journal of Catalysis, 207, 76.
12. Benco, L., Demuth, T., Hafner, J., Hutschka, F. and Toulhoat, H. (2002) Extraframework Aluminum Species in Zeolites: Ab Initio Molecular Dynamics Simulation of Gmelinite. Journal of Catalysis, 209, 480.
13. Raybaud, P., Digne, M., Iftimie, R., Wellens, W., Toulhoat, H. and Euzen, P. (2001) Morphology and Surface Properties of Boehmite (-A1OOH): A Density Functional Theory Study. Journal of Catalysis, 201, 236.
14. Henry, C. (1998) Surface Studies of Supported Model Catalysts. Surf. Sci. Rep., 31, 231.
15. Bazin, D., Mottet, C., Treglia, G. and Lynch, J. (2000) New Trends in Heterogeneous Catalysis Processes on Metallic Clusters from Synchrotron Radiation and Theoretical Studies. Applied Surf. Sci., 164, 140.
16. Bazin, D., Mottet, C. and Treglia, G. (2000) New Opportunities to Understand Heterogeneous Catalysis Processes through Synchrotron Radiation Studies and Theoretical Calculations of Density of States: the Case of Nanometer Scale Bimetallic Particles. Applied Catalysis: General A, 200, 47.
17. Bazin, D. (2002) Solid State Concepts to Understand Catalysis Using Nanoscale Metallic Particles. Topics in Catalysis, 18, 79.
18. Desjonqueres, M.C. and Spanjaard, D. (1995) Concepts in Surface Physics, Ed. Springer.
19. Mottet, C. (1997) Étude par simulation numérique d'agrégats libres mono- et bi-métalliques. PhD Thesis, Université Aix-Marseille II.
20. Bertsch, P.M. and Hunter, D.B. (2001) Applications of Synchrotron-Based X-ray Microprobes. Chem. Rev., 101, 1809.
21. Lynch, J. and Maire, G. (1993) Catalyse hétérogène et SOLEIL, in: Projet SOLEIL : argumentation scientifique, Chandesris, D., Morin, P. and Nenner, I. (Eds), Les Éditions de Physique, Les Ulis, 173-178.
22. Lynch, J. (2002) Development of Structural Characterisation Tools for Catalysts. Oil & Gas Science and Technology, 57, 281.
23. Bazin, D., Dexpert, H. and Lynch, J. (1995) In Situ XAFS Measurements of Catalysts. Y. Iwasawa, Xas for Catalyts and Surfaces (Ed., World Scientific).
24. Bottger, I., Schedel-Niedrig, T., Timpe, O., Gottschall, R., Havecker, M., Ressler, T. and Schlogl, R. (2000) Catalytic Methanol Oxidation Over Copper: Observation of Reaction-Induced Nanoscale Restructuring by Means of In Situ Time-Resolved X-Ray Absorption Spectroscopy. Chemistry - A European Journal, 6, 1870.
25. 3. Cat. Let., 71, 155.
26. Khodakov, A., Barbouth, N., Oudar, J., Villain, F., Bazin, D., Dexpert, H. and Schulz, P. (1996) Investigation of Dispersion and Localisation of Pt Species in Mazzite Using Exafs. J. of Phys. Chem., 101, 766.
27. Moonen, J., Lefferts, L., Slot, J., Bazin, D. and Dexpert, H. (1995) The Influence of Polydispersity and Inhomogeneity on Exafs of Bimetallic Catalysts. Physica B, 208, 689.
28. Makishima, H., Tanaka, Y., Kato, Y., Kure, S., Shimada, H., Matsubayashi, N., Nishijima, A. and Nomura, M. (1996) Characterization of Aromatics Saturation Catalysts used in a One-Year Commercial HDS Run. Catalysis Today, 29, 267.
29. Bazin, D., Triconnet, A. and Moureaux, P. (1995) An Exafs Characterisation of the Highly Dispersed Bimetallic PtPd Catalytic System. NIM B. 97, 41.
30. 4 Supported on Alumina. J. Phys. Chem. B, 104, 9828.
31. 3-Cl. J. de Physique, C4-6, 947.
32. 2, Materials. A XAFS Study. J. of the American Chemical Society, 120, 2059.
33. Chester, A.W., Absil, R.P.A., Kennedy, G.J., Lagarde, P. and Flank, A.M. (1999) X-Ray Absorption Spectroscopy of Transition Aluminas. J. Synchrotron Rad., 6, 448.
34. McBreen, J. and Sansone, M. (1994) In Situ X-Ray Absorption Spectroscopic Study of Adsorbed Pb on Carbon-Supported Pt. Journal of Electroanalytical Chemistry, 373, 227.
35. Bazin, D. and Guczi, L. (2001) Soft X-Ray Absorption Spectroscopy and Heterogeneous Catalysis. Applied Catalysis General A, 213, 147.
36. Bazin, D., Guczi, L. and Lynch, J. (2002) AWAXS in Heterogeneous Catalysis. Applied Catalysis General A, 87, 226.
37. Hodeau, J.L., Favre-Nicolin, V., Bos, S., Renevier, H., Lorenzo, E. and Berar, J.F. (2001) Resonant Diffraction. Chem. Rev., 101, 1843.
38. Védrine, J.C. (2000) Industrial Features. Catalysis Today, 56, 333.
39. Lynch, J. (1994) Characterisation of Industrial Catalysts by EXAFS. Journal de Physique III, 4-C9, 253.
40. Plazenet, G., Payen, E., Lynch, J. and Rebours, B. (2002) Study by EXAFS, Raman, and NMR Spectroscopies of the Genesis of Oxidic Precursors of Zeolite-Supported HDS Catalysts. J. Phys. Chem. B., 106, 7013.
41. Marcilly, C.R. (2000) Where and How Shape Selectivity of Molecular Sieves Operates in Refining and Petrochemistry Catalytic Processes. Topics in Catalysis, 13, 357.
42. 2 Catalysts in the Treatment of Nitrogen-Containing Pollutants. Catalysis Today, 75, 29.
43. Del Angel, P., Dominguez, J.M., Del Angel, G., Montoya, J.A., Lamy-Pitara, E., Labruquere, S. and Barbier, J. (2000) Aggregation State of Pt-Au/C Bimetallic Catalysts Prepared by Surface Redox Reactions. Langmuir, 16, 7210.
44. Demirci, Ü.B. and Garin, F. (2002) Kinetic Study of n-heptane Conversion on Sulfated Zirconia-Supported Platinum Catalyst: The Metal-Proton Adduct is the Active Site. Journal of Molecular Catalysis A: Chemical, 188, 233.
45. 2 Subshell as Analyzed by XAFS Spectroscopy. J. Phys. Chem. B., 105, 4810.
46. 2 Catalysts. Journal of Catalysis, 143, 155.
47. Marecot, P., Fakche, A., Pirault, L., Geron, C., Mabilon, G., Prigent, M. and Barbier, J. (1994) Effect of the Preparation Procedure on the Properties of Three-Way Automotive PtRh/Alumina-Ceria Catalysts. Applied Catalysis B: Environmental, 5, 43.
48. 2 as Potential Catalysts for Reforming Applications. I. Physicochemical Characterization Study. Journal of Catalysis, 198, 208.
49. Didillon, B., Bachir, R., Marecot, P. and Barbier, J. (1997) Isoprene Hydrogenation on Supported Pd-Fe Catalysts. Influence of the Catalyst Preparation Procedure. Applied Catalysis A: General, 164, 313.
50. Kerkeni, S., Lamy-Pitara, E. and Barbier, J. (2002) Copper-Platinum Catalysts Prepared and Characterized by Electro-Chemical Methods for the Reduction of Nitrate and Nitrite. Catalysis Today, 75, 35.
51. Epron, F., Gauthard, F. and Barbier, J. (2002) Influence of Oxidizing and Reducing Treatments on the Metal-Metal Interactions and on the Activity for Nitrate Reduction of a Pt-Cu Bimetallic Catalyst. Applied Catalysis A: General, 237, 253.
52. Garin, F., Girard, P., Ringler, S., Maire, G. and Davias, N. (1999) Mechanistic Studies of NO(x) Reduction Reactions under Oxidative Atmosphere on Alumina Supported 1 wt% Pt and 1 wt% Pt-0.5 wt% Zn Catalysts (Part I). Applied Catalysis B: Environmental, 20, 205.
53. Védrine, J.C., Coudurier, G., Ouqour, A., Pries de Oliveira, P.G. and Volta, J.C. (1996) Niobium Oxide Based Materials as Catalysts for Acidic and Partial Oxidation Type Reactions. Catalysis Today, 28, 3.
54. 2 Catalysts. Applied Catalysis B: Environmental, 35, 1.
55. Delage, M., Didillon, B., Huiban, Y., Lynch, J. and Uzio, D. (2000) Highly Dispersed Pd Based Catalysts for Selective Hydrogenation Reactions. Studies in Surface Science and Catalysis, 130, 1019.
56. Euzen, P., Le Gal, J.H., Rebours, B. and Martin, G. (1999) Deactivation of Palladium Catalyst in Catalytic Combustion of Methane. Catalysis Today, 47, 19.
57. 3 Catalysts: Relationship between Particle Size and Structure. Journal of Catalysis, 159, 178.
58. 2 (X=Mo,W), as Reforming Catalysts for Hydrocarbon Compounds. Catalysis Today, 65, 179.
59. Marécot, P., Mahoungou, J.R. and Barbier, J. (1993) Benzene Hydrogenation on Platinum and Iridium Catalysts. Variation of the Toxicity of Sulfur with the Nature of the Support. Applied Catalysis A: General, 101, 143.
60. Locatelli, F., Didillon, B., Uzio, D., Niccolai, G., Candy, J.P. and Basset, J.M. (2000) Preparation and Characterization of Small Silica-Supported Iridium Particles from Iridium Trisacetylacetonate Precursor. Journal of Catalysis, 193, 154.
61. 3 Systems. Physica B, 208, 677.
62. Shelimov, B., Lambert, J.F., Che, M. and Didillon, B. (1999) Initial Steps of the Alumina-Supported Platinum Catalyst Preparation: a Molecular Study by 195Pt NMR, UV-Visible, EXAFS, and Raman Spectroscopy. Journal of Catalysis, 185, 462.
63. 3 Bimetallic Catalysts Prepared by Surface Redox Reactions. Journal of Molecular Catalysis A: Chemical, 164, 253.
64. Leyrit, P., Cseri, T., Marchal, N., Lynch, J. and Kasztelan, S. (2001) Aromatic Reduction Properties of Molybdenum Sulfide Clusters in HY Zeolite. Catalysis Today, 65, 249.
65. Payen, E., Plazenet, G. and Lynch J. (2002) Cobalt-Molybdenum Interaction in Oxidic Precursors of Zeolite-Supported HDS Catalysts. Physical Chemistry Chemical Physics, 4, 3924.
66. 2 Crystallites: an In Situ EXAFS Study. Physical Chemistry Chemical Physics, 3, 246.
67. 3 Hydrodesulfurization Catalysts Prepared in Aqueous Solution. Journal of Catalysis, 204, 495.
68. 3 Catalysts. Adsorption Science and Technology, 18, 541.
69. 3 Hydrodesulfurization Catalysts Prepared in Aqueous Solution. Journal of Catalysis, 204, 495.
70. Gaborit, V., Allali, N., Geantet, C., Breysse, M., Vrinat, M. and Danot, M. (2000) Niobium Sulfide as a Dopant for Hydrotreating NiMo Catalysts. Catalysis Today, 57, 267.
71. Enache, D.I., Rebours, B., Roy-Auberger, M. and Revel, R. (2002) In situ XRD Study of the Influence of Thermal Treatment on the Characteristics and the Catalytic Properties of Cobalt-Based Fischer-Tropsch Catalysts. Journal of Catalysis, 205, 346.
72. Khodakov, A., Ducreux, O., Lynch, J., Rebours, B. and Chaumette, P. (1999) Structural Modification of Cobalt Catalysts: Effect of Wetting Studied by X-Ray and Infrared Techniques. Oil and Gas Science and Technology, 54, 525.
73. Bazin, D., Sayers, D. and Rehr, J. (1997) Comparison between Xas, Awaxs, Asaxs & Dafs Applied to Nanometer Scale Metallic Clusters. J. Phys. Chem., 101, 11040.
74. Bazin, D. and Sayers, D. (1993) Comparison between Xas & Awaxs Applied to Nanometer Scale Supported Bimetallic Clusters. Jpn J. Appl. Phys., 32-2, 249.
75. Wong, J., George, G.N., Pickering, I.J., Rek, Z.U., Rowen, M., Tanaka, T., Via, G.H., DeVries B., Vaughan, D.E.W., and Brown, G.E., Jr. (1994) New Opportunities in XAFS Investigation in the 1-2 keV Region. Solid State Communications, 92, 559.
76. de Groot, F. (2001) High-Resolution X-ray Emission and X-ray Absorption Spectroscopy. Chem. Rev., 101, 1779.
77. Denbeaux, G., Andersona, E., Chaoa, W., Eimüller, T., Johnson, L., Köhler, M., Larabell, C.M., Legrosa, M., Fischer, P., Pearson, A., Schützc, G., Yager, D. and Attwood, D. (2001) Soft X-Ray Microscopy to 25 nm with Applications to Biology and Magnetic Materials. NIM A, 467-468, 841.
78. Schedel-Niedrig, Th., Hävecker, M., Knop-Gericke, A., Reinke, P., Schlöl, R. and Lux-Steiner, M.Ch. (2001) In situ X-Ray Absorption Spectroscopy in the Soft Energy Range: Novel Prospects for the Chemical Characterization of Solid State Surfaces at High Pressure and High Temperature. Materials Research Society Symposium - Proceedings. 678, EE8.3.
79. Hävecker, M., Knop-Gericke, A. and Schedel-Niedrig, Th. (1999) High-Pressure Soft X-Ray Absorption Spectroscopy: Application of a New In Situ Spectroscopic Method in Catalysis Research. Applied Surface Science, 142, 438.
80. Srivastava, P. and Baberschke, K. (2000) New Opportunities in Soft X-Ray Absorption to Characterise the Adsorbate Bonding. Topics in Catalysis, 10, 199.
81. Jun, K., Yoshinobu, M., Tetsuro, S., Makoto, S., Tohru, H., Yoshihisa, H., Yoichi, I. Akiko, F., Masami, F., Masamitsu, W., Kuniko, M., Shik, S. and Yohichi, G. (2000) High Resolution Soft X-Ray Absorption Spectroscopy for the Chemical State Analysis of Mn. Spectrochimica Acta - Part B Atomic Spectroscopy, 55, 1385.
82. Havecker, M., Knop-Gericke, A., Schedel-Niedrig, T. and Schlogl, R. (1998) High-Pressure Soft X-Ray Absorption Spectroscopy: a Contribution to Overcoming the "Pressure Gap" in the Study of Heterogeneous Catalytic Processes. Angewandte Chemie - International Edition, 37, 1939.
83. Chen, J.G. (1997) NEXAFS Investigations of Transition Metal Oxides, Nitrides, Carbides, Sulfides and Other Interstitial Compounds. Surf. Sci. Report, 30, 1.
84. Knop-Gericke, A., Havecker, M., Schedel-Niedrig, Th. and Schlog, R. (2000) Topics in Catalysis, 10, 187.
85. Srivastava, P., Baberschke, K (2000) New Opportunities in Soft X-Ray Absorption to Characterise the Adsorbate Bonding. Topics in Catalysis, 10, 199.
86. Shimada, H. (2000) Characterization of Coke Deposited on Catalysts by Carbon K-Edge near Edge X-Ray Absorption Fine Structure (NEXAFS) Spectroscopy. Topics in Catalysis, 10, 265.
87. Mayer, R.W. (2001) Investigation of Ammonia Oxidation over Copper with In Situ NEXAFS in the Soft X-Ray Range: Influence of Pressure on the Catalyst Performance. Catalysis Letters, 74, 119.
88. Van Bokhoven, J.A., Sambe, H., Ramaker, D.E. and Koningsberger, D.C. (1999) Al K-Edge Near-Edge X-Ray Absorption Fine Structure (NEXAFS) Study on the Coordination Structure of Aluminum in Minerals and Y Zeolites. J. Phys. Chem. B., 103, 7557.
89. Van Bokhoven, J.A., Koningsberger, D.C., Kunkeler, P. and van Bekkum, H. (2002) Influence of Steam Activation on Pore Structure and Acidity of Zeolite Beta: An Al K Edge XANES Study of Aluminum Coordination. J. of Catalysis, 211, 540.
90. Okajima, T., Teramoto, K., Mitsumoto, R., Oji, H., Yamamoto, Y., Mori, I., Ishii, H., Ouchi, Y. and Seki, K. (1998) J. Phys. Chem. A., 102, 7093.
91. Parent, Ph., Laffon, C., Tourillon, G. and Cassuto, A. (1995) J. Phys. Chem., 99, 5058.
92. Terada, S., Yokoyama, T., Sakano, M., Imanishi, A., Kitajima, Y., Kiguchi, M., Okamoto, Y., Ohta, T. (1998) Thiophene Adsorption on Pd(111) and Pd(100) Surfaces Studied by Total-Reflection S K-Edge X-Ray Absorption Fine-Structure Spectroscopy. Surface Science, 414, 107.
93. 2 of Supported Co Catalysts Through the L Absorption Edges. J. Syn. Rad. News, 6, 430.
94. Abbate, M., Pen, H., Czyyk, M.T., de Groot, F.M.F., Fuggle, J.C., Ma, Y.J., Chen, C.T., Sette, F., Fujimori, A., Ueda, Y. and Kosuge, K. (1993) Soft X-Ray Absorption Spectroscopy of Vanadium Oxides. J. of Electron Spectroscopy and Related Phenomena, 62, 185.
95. Amemiya, K., Kondoh, H., Yokoyama, T. and Ohta, T. (2002) A Soft X-Ray Beamline for Surface Chemistry at the Photon Factory. J. of Electron Spectroscopy and Related Phenomena, 124, 151.
96. Pompa, M., Flank, A.M., Lagarde, P., Rife, J., Stekhin, I., Nakazawa, M., Ogasawara, H. and Kotani, A. (1997) Experimental and Theoretical Comparison between Absorption, Total Electron Yield and Fluorescence Spectra of the Thumllium M5 edge. J. de Phys. IV, C2-III, 159.
97. Cabaret, D., Sainctavit, Ph., Ildefonse, Ph. and Flank, A.M. (1997) Determination of Mg Site Geometry in Pyroxenes by Full Multiple Scattering Calculations. J. de Phys. IV, C2-III, 157.
98. Parent, Ph., Laffon, C., Tourillon, G. and Cassuto, A. (1995) Adsorption of Acrylonitrile on Pt(111) and Au(111) at 95 K in the Monolayer and Multilayer Ranges Studied by NEXAFS, UPS, and FT-IR. J. Phys. Chem., 99, 5058-5066.
99. 3 Powder: Nexafs Study at Nitrogen K edge. Cat. Let., 74, 189.
100. Rompel, A, Cinco, R.M., Robblee, J.H., Latimer, M.J., McFarlane, K.L., Huang, J., Walters, M.A. and Yachandra, V.K. (2001) S K- and Mo L-Edge X-Ray Absorption Spectroscopy to Determine Metal-Ligand Charge Distribution in Molybdenum-Sulfur Compounds. J. of Synchrotron Radiation, 8, 1006.
101. Izumi, Y., Glaser, T., Rose, K., McMaster, J., Basu, P., Enemark, J.H., Hedman, B., Hodgson, K.O. and Solomon, E.I. (1999) Ligand K-Edge and Metal L-Edge X-Ray Absorption Spectroscopy and Density Functional Calculations of Oxomolybdenum Complexes with Thiolate and Related Ligands: Implications for Sulfite Oxidase. J. of the American Chemical Society, 121, 10035.
102. Glaser, T., Rose, K., Shadle, S.E., Hedman, B., Hodgson, K. O. and Solomon. E.I., (2001) S K-Edge X-Ray Absorption Studies of Tetranuclear Iron-Sulfur Clusters: M-Sulfide Bonding and its Contribution to Electron Delocalization. J. of the American Chemical Society, 123, 442.
103. Farrell, S.P. and Fleet, M.E. (2001) Sulfur K-Edge XANES Study of Local Electronic Structure in Ternary Monosulfide Solid Solution (Fe, Co, Ni)0.923S. Physics and Chemistry of Minerals, 28, 17.
104. Waldo, G.S., Carlson, R.M.K., Moldowan, J.M., Peters, K.E. and Penner-Hahn J.E. (1991) Geochim. et Cosmochim. Acta, 55, 801.
105. Lynch, J., Everlien, G., Leblond, C., Bazin, D. (1999) Evolution of Sulphur During Pyrolysis of Petroleum Kerogens, J. of Synchrotron Radiation, 6, 661.
106. Guczi, L., Schay, G., Stefler, G. and Mizukami, F. (1999) Bimetallic Catalysis: CO hydrogenation over PdCo Catalysts Prepared by Sol/Gel Method. J. Mol. Catal. A., 141, 177.
107. Guczi, L., Borkó, L., Koppány, Zs. and Mizukami, F. (1998) Catal. Lett., 54, 33.
108. Guczi, L., Sundararajan, R., Koppány, Zs., Zsoldos, Z., Schay, Z., Mizukami, F. and Niwa, S. (1997) Structure and Characterization of Supported RuCo Bimetallic Catalysts. J. Catal., 167, 482.
109. Udayan D. (2002) Studies on Some Advanced Materials and Use of the Singapore Synchrotron Light Source. NIM B, in press.
110. Clausen, B.S. (1998) Combined (Q)EXAFS/XRD: Technique and Applications. Catalysis Today, 39, 293.
111. Meneau, F., Sankar, G., Morgante, N., Cristol, S., Catlow, C.R.A., Thomas, J.M. and Greaves, G.N. (2002) Characterization of Zinc Oxide Nanoparticles Encapsulated into Zeolite-Y: An In Situ Combined X-Ray Diffraction, XAFS, and SAXS Study. NIM B, in press.
112. Thomas, J.M. and Sankar, G (2001) The Role of Synchrotron-Based Studies in the Elucidation and Design of Active Sites in Titanium-Silica Epoxidation Catalysts. Accounts of Chemical Research, 34, 571.
113. Grunwaldt, J.D., Molenbroek, A.M., Topsøe, N.Y., Topsøe, H. and Clausen, B.S. (2000) In Situ Investigations of Structural Changes in Cu/ZnO Catalysts. Journal of Catalysis, 194, 452.
114. Dent, A.J., Oversluizen, M., Greaves. G.N., Roberts, M.A., Sankar, G., Catlow, C.R. and Thomas, J.M. (1995) A Furnace Design for Use in Combined X-Ray Absorption and Diffraction up to a Temperature of 1200°C: Study of Cordierite Ceramic Formation Using Fluorescence QEXAFS/ XRD. Physica B: Condensed Matter, 208-209, 253.
115. Epple, M., Sankar, G. and Thomas, J.M. (1997) Solid-State Polymerization Reaction by Combined In-Situ X-ray Diffraction and X-ray Absorption Spectroscopy (XRD-EXAFS). Chem. Mater., 9, 3127.
116. Evans, J. and Newton, M.A. (2002) Towards a Structure-Activity Relationship for Oxide Supported Metals. J. of Molecular Catalysis A: Chemical, 182, 351
117. Cimini, F. and Prins, R. (1997) QEXAFS Investigation of the Particle Growth of PtRh Clusters Supported on NaY. J. Phys. Chem. B., 101, 5277.
118. 2O3-F Catalysts. J. of Catalysis, 201, 258.
119. Sun, M., Bürgi, T., Cattaneo, R. and Prins, R. (2001) TPS, XPS, and QEXAFS Investigation of the Sulfidation Behavior of Tungsten on Fluorine-Promoted Alumina. J. of Catalysis, 197, 172.
120. Lamberti, C., Prestipino, C., Bonino, F., Capello, L., Bordiga, S., Spoto, G., Zecchina, A., Moreno, S.D., Cremaschi, B., Garilli, M., Marsella, A., Carmello, D., Vidotto, S. and Leofanti, G. (2002) The Chemistry of the Oxychlorination Catalyst: an In Situ, Time-Resolved XANES Study. Angewandte Chemie - International Edition, 41, 2341.
121. Nghiem, P., Tordeux, M.A. and Level, M.P. (2002) Study on Coupling and Coupling Correction for the SOLEIL Ring. NIM A, 480, 339.
122. Ciret, J.C., Congretel, G., Evesque, C. and Gros, P. (2000) Eddy Current Septum Magnet Prototype for SOLEIL Light Source Project. IEEE Transactions on Applied Super-conductivity, 10, 244.
123. http://www.soleil.u-psud.fr
124. Gailhanou, M., Dubuisson, J.M., Ribbens, M., Roussier, L., Bétaille, D., Créoff, C., Lemonnier, M., Denoyer, J., Bouillot, C., Jucha, A., Lena, A., Idir, M., Bessière, M., Thiaudière, D., Hennet, L., Landron, C., Coutures, J.P. (2001) H10: a Materials and High Temperature Beamline at LURE/DCI. NIM A, 467-468, 745.
125. Adora, S., Soldo-Olivier, Y., Faure, R., Durand, R., Dartyge, E., Baudelet, F. (2001) Electrochemical Preparation of Platinum Nanocrystallites on Activated Carbon Studied by X-ray Absorption Spectroscopy. J. Phys. Chem. B., 105, 10489.
126. III Edges. Studies on Metallic Elements, Compounds and Catalysts. J. Chem. Phys., 70, 4849.
127. Mansour, A.N., Cook, J.W. and Sayers, D.E. (1984) Quantitative Technique for the Determination of the Number of Unoccupied d-Electron States in a Platinum Catalysts using the LII JII X-Ray Absorption Edge Spectra. J. Phys. Chem., 88, 2330.
128. Bazin, D., Maire, F., Schneider, S., Meunier, G., Maire, G. (1997) A Detailed Study of the Metallic Function of Bimetallic PtRh Post Combustion Catalyst by Xas, Met: Correlation with their Catalytic Activity. J. de Phys. IV, C2, 841.
129. Koningsberger, D.C. and Mojet, L. (2000) Role an Contributions of Xafs Spectroscopy in Catalysis.
130. III Edge White Line Relative to Nanometer Scale Clusters. J. of Phys. Chem., 101, 5332.
131. Fernandez-Garcia, M., Marquez Alvarez, C. and Haller, G.L. (1995) XANES-TPR Study of Cu-Pd Bimetallic Catalysts: Application of Factor Analysis. J. Phys. Chem., 99, 12565.
132. Fernandez-Garcia, M., Martinez-Arias, A., Rodriguez-Ramos, I., Ferreira-Aparicio, P. and Guerrero-Ruiz, A. (1999) Genesis of Surface and Bulk Phases in RhCo Catalysts. Langmuir, 15, 5295.
133. Bazin, D. and Rehr, J.J. Limits and Advantages of X-Ray Absorption Near Edge Structure for Nanometer Scale Metallic Clusters, accepted in J. Phys. Chem.
134. Bazin, D., Bensaddik, A., Briois, V. and Saintavict, Ph. (1996) M. S. Calculation of Xas and XRD Calculations: Application to Nanometer Scale Cu Metallic Particle. J. de Physique. C4, 481.
135. Stern, E.A. (1975) Extended X-Ray Absorption Fine Structure Techniquez. II - Experimental Practice and Selected Results. Phys. Rev B, 11, 4825.
136. Szaloki, I., Torok, S.B., Injuk, J. and Van Grieken, R.E. (2002) X-Ray Spectrometry. Anal. Chem., 74, 2895.
137. Michalowicz, A. and Vlaic, G. (1998) Multiple Solutions in Data Fitting: a Trap in EXAFS Structural Analysis and Some Ideas to Avoid It. J. Synch. Rad., 5, 1317.
138. Koningsberger D.C., Mojet, B.L., van Dorssen, G.E. and Ramaker, D.E (2000) XAFS Spectroscopy: Fundamental Principles and Data Analysis. Topics in Catalysis, 10, 143.
139. 3 Catalysts in the First Stages of Preparation. J. of Cat., 110, 209.
140. Douidah, A., Marécot, P., Szabo, S. and Barbier, J. (2002) Evaluation of the Metal-Support Interactions - Case of Platinum-Supported Catalysts: Effect of the Support Nature and the Metallic Dispersion. Applied Catalysis A: General, 225, 21.
141. 2: a Combination of HRTEM, mass Spectrometry, and quick EXAFS. J. of Catalysis, 205, 135.
142. Koningsberger, D.C., De Graaf, J., Van Dillen, A.J. and De Jong, K.P. (2001) Preparation of Highly Dispersed Pt Particles in Zeolite Y with a Narrow Particle Size Distribution: Characterization by Hydrogen chemisorption, TEM. EXAFS Spectroscopy, and Particle Modeling. Journal of Catalysis, 203, 307.
143. 3. J. of Catalysis, 163, 294.
144. 12]: Characterization by EXAFS and Catalysis of Methylcyclohexane Dehydrogenation. J. Am. Chem. Soc., 119, 5877.
145. 3 bimetallic catalysts prepared by surface redox reactions. Journal of Molecular Catalysis A: Chemical, 164, 253.
146. 3. System. J. of Syn. Rad., 6, 465.
147. Stachs, O., Petkov, V., Himmel, B. and Gerber, T. (1999) Secondary Graphite Crystal Spectrometer for Anomalous X-Ray Diffraction Experiments. NIM A, 434, 473.
148. Ramos, S., Neilson, G.W., Barnes, A.C. and Mazuelas, A. (2001) An Anomalous X-Ray Diffraction Study of Yttrium (III) Hydration. J. Phys. Chem. B., 105, 2694.
149. Serimaa, R., Etelaniemi, V., Laitalainen, T., Bienenstock, A., Vahvaselka, S. and Paakkari, T. (1997) Structure of Amorphous Platinum Uridine Green Sulfate by AWAXS and EXAFS. Inorg. Chem., 36, 5574.
150. Sayers, D.E., Renevier, H., Hodeau, J.L., Berar, J.F., Tonnerre, J.M., Raoux, D., Chester, A., Bazin, D. and Bouldin, C. (1997) On the Way to Understanding Platinum in a Pt-Zeolite Catalyst. ESRF NewsLetter, 27.
151. Bazin, D., Revel, R., Dexpert, H., Elkaim, E., Lauriat, J., Garin, F., Maire, F. and Guczi, L. (1998) Aspects complémentaires entre Xas et Awaxs dans le cas d'entités de taille nanométrique supportés sur un oxide léger : agrégats métalliques et spinelle. J. de Phys., IV/8, 263.
152. Balerna, A., Liotta, L., Longo, A., Martorana, A., Meneghini, C., Mobilio, S. and Pipitone, G. (1999) Structural Characterization of Pumice-Supported Silver-Palladium Metal Clusters by Means of XAFS and AWAXS. Eur. Phys. J. D, 7, 89.
153. Samant, M.G., Bergeret, G., Meitzner, G. and Boudart, M. (1988) Anomalous Wide Angle X-Ray Scattering and X-Ray Absorption Spectroscopy of Supported PtMobimetallic Clusters. l - Experimental Technique. J. Phys. Chem., 92, 3542.
154. Samant, M.G., Bergeret, G., Meitzner, G., Gallezot, P. Boudart, M. (1988) Anomalous Wide Angle X-Ray Scattering and X-Ray Absorption Spectroscopy of Supported PtMo Bimetallic Clusters. 2 - Atomic and Electronic structure. J. Phys. Chem., 92, 3547.
155. Liang, K.S., Chien, F.Z., Hughes, G.J., Meitzner, G.D. and Sinfelt, J.H. (1991) The Nature of Rhenium in Silica Supported PtRe Clusters: Synchrotron X-Ray Diffraction Studies. J. Phys. Chem., 95, 9974.
156. Bellotto, M., Rebours, B., Clause, O., Lynch, J., Bazin, D. and Elkaim, E. (1996) Hydrotalcite Decomposition Mechanism: A Clue to the Structure and Reactivity of Spinel-like Mixed Oxides. J. Phys. Chem., 100, 8535.
157. Bellotto, M., Rebours, B., Clause, O., Lynch, J., Bazin, D. and Elkaim, E. (1996) A Reexamination of Hydrotalcite Crystal Chemistry. J. Phys. Chem., 100, 8527.
158. 2O. NIMB, 97, 180.
159. Creux, S., Bouchet-Fabre, B. and Gaskell, P.H. (1995) Anomalous Wide Angle X-Ray Scattering Study of Strontium Silicate and Aluminosilicate Glasses. Journal of Non-Crystalline Solids, 192, 360.
160. Bazin, D. and Revel, R. (1999) Improvement in the Structural Characterization of Nanometer Scale Metallic Oxide. The Xas-Awaxs Combined Approach. J. Syn. Rad., 6, 483.
161. Waseda, Y. (1984) Novel Application of Anomalous (resonance) X-Ray Scattering for Structural Characterization of Disordered Material. Ed. Springer-Verlag, Series: Lecture Notes in Physics, 204.
162. Materlik, G., Sparks, C.J. and Fisher, K. (1994) Resonant Anomalous X-Ray Scattering, Ed. North Holland.
163. Stuck, J.B., Raoux, D., Chieux, P. and Riekel, C. (1993) Methods in the Determination of Partial Structure Factors, Ed. World Scientific.
164. Bergeret, G. and Gallezot, P. (1993) In Détermination de la structure atomique des catalyseurs solides par difffraction des rayons X, Ed. Dunod.
165. Gnutzmann, V. and Vogel, W. (1990) Structural Sensitivity of the Standard Platinum/Silica Catalyst EuroPt-I to Hydrogen and Oxygen Exposure by In Situ X-Ray Diffraction. J. Phys. Chem., 94, 4991.
166. Sasaki, S. (1983) KEK Report 83-82, Nat. Lab. for High Energy Physics, Tsukuba, Japan.