Reactions of azines with titanocene: C-H activation, C-C coupling, and N-N cleavage to heterobimetallic complexes

Organometallics

Volumn 17, Issue 9, 1998, Pages 1649-1651

  Ohff, Andreas ^a   Zippel, Thorsten ^a   Arndt, Perdita ^a   Spannenberg, Anke ^a   Kempe, Rhett ^a   Rosenthal, Uwe ^a  

^a UNIVERSITY OF ROSTOCK   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001005818     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9801251     Document Type: Article

References (25)

1. Reviews: Collman, J. P.; Hegedus, L. S.; Norton, J. R.; Finke, R. G. Principles and Applications of Organotransition Metal Chemistry; University Science Books: Mill Valley, CA, 1987.
2. (a) Rosenthal, U.; Ohff, A.; Baumann, W.; Kempe, R.; Tillack, A.; Burlakov, V. V. Angew. Chem., Int. Ed. Engl. 1994, 33, 1605.
3. (b) Ohff, A.; Kosse, P.; Baumann, W.; Tillack, A.; Kempe, R.; Görls, H.; Burlakov, V. V.; Rosenthal, U. J. Am. Chem. Soc. 1995, 117, 10399.
4. (c) Pulst, S.; Arndt, P.; Heller, B.; Baumann, W.; Kempe, R.; Rosenthal, U. Angew. Chem., Int. Ed. Engl. 1996, 35, 1112.
5. (d) Ohff, A.; Pulst, S.; Lefeber, C.; Peulecke, N.; Arndt, P.; Burlakov, V. V.; Rosenthal, U. Synlett 1996, 111 and references therein.
6. Burlakov, V. V.; Polyakov, A. V.; Yanovsky, A. I.; Struchkov, Y. T.; Shur, V. B.; Vol'pin, M. E.; Rosenthal, U.; Görls, H. J. Organomet. Chem. 1994, 476, 197.
7. +).
8. (a) Chamberlain, L. R.; Durfee, L. D.; Fanwick, P. E.; Kobriger, L. M.; Latesky, S. L.; McMullen, A. K.; Steffey, B. D.; Rothwell, I. P.; Folting, K.; Huffman, J. C. J. Am. Chem. Soc. 1987, 109, 6068.
9. (b) Hey-Hawkins, E. Chem. Rev. 1994, 94, 1661 and references therein.
10. (a) Erker, G.; Frömberg, W.; Krüger, C.; Raabe, E. J. Am. Chem. Soc. 1988, 110, 2400.
11. (b) Carofiglio, T.; Stella, S.; Floriani, C.; ChiesiVilla, A.; Guastini, C. J. Chem. Soc., Dalton Trans. 1989, 1957.
12. +).
13. 2 (all data) = 0.126, GOF (all data) = 0.922.
14. Reviews: (a) McMurry, J. E. Acc. Chem. Res. 1983, 16, 405. (b) Dang, Y.; Geise, H. J. J. Organomet. Chem. 1991, 405, 1. (c) Eisch. J. J.; Shi, X.; Alila, J. R.; Thiele, S. Chem. Ber. 1997, 130, 1175.
15. Reviews: (a) McMurry, J. E. Acc. Chem. Res. 1983, 16, 405. (b) Dang, Y.; Geise, H. J. J. Organomet. Chem. 1991, 405, 1. (c) Eisch. J. J.; Shi, X.; Alila, J. R.; Thiele, S. Chem. Ber. 1997, 130, 1175.
16. Reviews: (a) McMurry, J. E. Acc. Chem. Res. 1983, 16, 405. (b) Dang, Y.; Geise, H. J. J. Organomet. Chem. 1991, 405, 1. (c) Eisch. J. J.; Shi, X.; Alila, J. R.; Thiele, S. Chem. Ber. 1997, 130, 1175.
17. (a) Pasquali, M.; Floriani, C.; Chiesi-Villa, A.; Guastini, C. Inorg. Chem. 1981, 20, 349.
18. (b) De Angelis, S.; Solari, E.; Gallo, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C. Inorg. Chem. 1996, 35, 5995.
19. Jonas, K.; Deffense, E.; Habermann, D. Angew. Chem., Int. Ed. Engl. 1983, 22, 716.
20. +).
21. 2 (all data) = 0.172. GOF (all data) = 1.025.
22. (a) Selent, D.; Beckhaus, R.; Pickardt, J. Organometallics 1993, 12, 2857.
23. (b) Schmidt, G.; Stutte, B.; Boese, R. Chem. Ber. 1978, 111, 1239.
24. For example: (a) Evans, W. J.; Meadows, J. H.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1984, 106, 1291. (b) Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123.
25. For example: (a) Evans, W. J.; Meadows, J. H.; Hunter, W. E.; Atwood, J. L. J. Am. Chem. Soc. 1984, 106, 1291. (b) Klose, A.; Solari, E.; Floriani, C.; Chiesi-Villa, A.; Rizzoli, C.; Re, N. J. Am. Chem. Soc. 1994, 116, 9123.