Cyclopentadienyl-hydrazido titanium complexes: Tuning of coordination modes of hydrazido ligands to the titanium center

Organometallics

Volumn 18, Issue 11, 1999, Pages 2049-2051

  Yoon, Sung Cheol ^a   Bae, Byoung Jae ^a   Suh, Il Hwan ^b   Park, Joon T ^a  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

^b Chungnam National University   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000102813     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990093x     Document Type: Article

References (32)

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14. 2).
15. 4-SiTi: C, 54.82; H, 9.74; N, 15.04. Found: C, 54.51; H, 9.34; N, 14.64.
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19. 3).
20. 2SiTi: C, 57.31; H, 9.62; N, 8.91. Found: C, 57.26; H, 9.37; N, 8.87.
21. w = 0.132, and GOF = 1.073 for 415 parameters refined against 4161 reflections that had I > 2σ(I). There are two equivalent molecules (2-A and 2-B) in the crystallographic asymmetric unit.
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26. w = 0.109, and GOF = 1.054 for 343 parameters refined against 2474 reflections that had I > 2σ(I). There are two equivalent molecules (3-A and 3-B) in the crystallographic asymmetric unit.
27. Details of structural characterization of 4 and 5 are described in the Supporting Information and will be reported in a full paper.
28. 4: C, 50.48; H, 8.15; N, 9.06. Found: C, 50.11; H, 7.98; N, 8.81.
29. w = 0.115, and GOF = 1.078 for 667 parameters refined against 7338 reflections that had I > 2σ(I).
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