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2 stream, but 3 is isolated together with the products 1a-e and 5a-e. Upon selective extraction, it is contained preferentially in the intermediate fractions. Although the separation of 1a-e from 3 is readily achieved using established techniques (e. g., hydrolysis/extraction), future optimization should be directed toward the use of stoichiometric amounts of the acylating agent.
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http://solvent-innovation.de.
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GC: 2-octanol (1a), 25 m LIPODEX A; 2-octyl laureate (5a), 25m PER ME-BCD/OV 225/ FS 611; 1-phenylethanol (1b), 1-phenylethyl acetate (4b), and 3-methyl-2-butanol (1c), 25 m TBBCD/OV1701/ FS 610; 3-methyl-2-butyl laureate (5c), 25 m IVADEX 1/PS086; 1-(2-naphthyl)ethyl acetate (4e), 25m IVADEX-7/O V-1701. HPLC: 1-phenylethyl laureate (5b) and 4-phenyl-2-butyl laureate (5d), 250 mm; Chiralcel OD-H, 4.6 mm i. d.; 4-phenyl-2-butanol (1d), 1-(2-naphthyl)ethanol (1e), and 1-(2-naphthyl)ethyl laureate (5e), 250 mm, Chiralcel OD-R, 4 mm i.d.
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