Supercritical carbon dioxide as a green reaction medium for catalysis

Accounts of Chemical Research

Volumn 35, Issue 9, 2002, Pages 746-756

  Leitner, Walter ^a,b  

^a RWTH AACHEN UNIVERSITY   (Germany)

^b MAX PLANCK INSTITUT FÜR KOHLENFORSCHUNG   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CARBON DIOXIDE; ORGANOMETALLIC COMPOUND;

ARTICLE; CATALYSIS; CATALYST; CHEMICAL REACTION; DANGEROUS GOODS; ENVIRONMENT; MEDICAL RESEARCH; METHODOLOGY; SYNTHESIS;

CARBON DIOXIDE; CATALYSIS; CHEMICAL INDUSTRY; CHEMISTRY, ORGANIC; ENVIRONMENTAL POLLUTION; MOLECULAR STRUCTURE;

EID: 0036739980     PISSN: 00014842     EISSN: None     Source Type: Journal    
DOI: 10.1021/ar010070q     Document Type: Article

References (76)

1. Clean and green ... but are they mean?
2. Separation with supercritical gases: Practical applications
3. 2 technology platform: An important tool for environmental problem solving
4. 2 as solvent
5. Cleaning up Hydrogenations
6. Homogeneous Catalysis in Supercritical Fluids
7. 2)
8. Perfluoralkyl substituted Arylphosphanes as Ligands for Homogeneous Catalysis in Supercritical Carbon Dioxide
9. The use of supercritical fluids in synthetic organic chemistry
10. 2 using dendrimer-encapsulated palladium nanoparticles
11. Palladium-catalysed cross-coupling reactions in supercritical carbon dioxide
12. 2 as catalyst
13. Olefin metathesis in supercritical carbon dioxide
14. Polymerisation of olefins catalysed by a palladium complex in supercritical carbon dioxide
15. Novel nickel-(II) complexes for the catalytic copolymerization of ethylene and carbon monoxide: Polyketone synthesis in supercritical carbon dioxide
16. Rhodium-catalyzed phenylacetylene polymerization in compressed carbon dioxide
17. Dispersion polymerizations in supercritical carbon dioxide
18. 2 down to low pressures
19. Carbon dioxide gas accelerates solventless synthesis
20. 6-BINAPHOS
21. 2 expanded methanol - An application of Gas Anti-Solvent Reactions (GASR)
22. 2-expanded phases
23. 2]
24. Photochemical carbonylation of ethane under supercritical conditions
25. C-H bond activation in dense carbon dioxide rhodium-catalyzed methane carbonylation and alkane dehydrogenation
26. Hydroformylation reactions in supercritical carbon dioxide using insoluble metal complexes
27. Rhodium-catalyzed hydroformylation in supercritical carbon dioxide
28. Homogeneous reactions in supercritical carbon dioxide using a catalyst immobilized by a Microporous silica membrane
29. 2 and diethylamine
30. 2 catalysed by a supported rhodium complex
31. Continuous, selective hydroformylation in supercritical carbon dioxide using an immobilised homogeneous catalyst
32. Ionic liquids-new "solution" for transition metal catalysis
33. 2
34. Phase-separable catalysis using room-temperature ionic liquids and supercritical carbon dioxide
35. Asymmetric hydrogenation and catalyst recycling using ionic liquid and supercritical carbon dioxide
36. Continuous flow homogeneous catalysis: Hydroformylation of alkenes in supercritical fluid ionic liquid biphasic mixtures
37. 2 continuous flow system
38. Nickel-catalysed enantioselective hydrovinylation of styrenes in liquid or supercritical carbon dioxide
39. Colloid-catalysed arene hydrogenation in aqueous/supercritical fluid biphasic media
40. Multiphase catalysis using water-soluble metal complexes in supercritical carbon dioxide
41. Enhanced catalyst reactivity and separations using water/carbon dioxide emulsions
42. 2 as the solvent
43. 2/aqueous biphase media
44. Steel-promoted oxidation of olefins in supercritical carbon dioxide
45. Selective oxidation of cyclooctane to cyclooctanone with molecular oxygen in the presence of compressed carbon dioxide
46. 2
47. Homogeneous catalytic hydrogenation of supercritical carbon dioxide
48. Iridium-catalyzed enantioselective hydrogenation of imines in supercritical carbon dioxide
49. Propylene hydroformylation in supercritical carbon dioxide
50. Hydroformylation of propylene in supercritical carbon dioxide
51. Hydroformylation of hex-1-ene in supercritical carbon dioxide catalysed by rhodium trialkylphosphine complexes
52. Enhanced regioselectivity of rhodium-catalysed alkene hydroboration in supercritical carbon dioxide
53. Sulfur oxidation in supercritical carbon dioxide: Dramatic pressure dependent enhancement of diastereoselectivity for sulfoxidation of cysteine derivatives
54. Asymmetric catalytic hydrogenation reactions in supercritical carbon dioxide
55. The mechanism of dihydorgen activation and transfer during asymmetric hydrogenation in supercritical carbon dioxide
56. Mechanistic aspects of the hydrogen addition during enantioselective rhodium-catalysed ruction of C=C double bonds with formic acid/triethylamine or molecular hydrogen
57. The photophysics of 6-(1-pyrenyl)hexyl-11(1-pyrenyl)undecanoate dissolved in neat liquids and supercritical carbon dioxide: Impact on olefin metathesis
58. Rhodium-catalyzed hydroaminomethylation using supercritical carbon dioxide as solvent and temporary protecting group
59. Supercritical carbon dioxide as a reaction medium and reaction partner
60. Selective conversion of carbon dioxide to dimethyl carbonate by molecular catalysis
61. High-Pressure routes to dimethyl carbonate from supercritical carbon dioxide
62. Reactivity of carbon dioxide with n-butyl(phenoxy)-, (alkoxy)-, and (oxo)stannanes: Insight into dimethyl carbonate synthesis
63. 2 in the presence of zeolites and ion-exchange resins
64. Catalytic production of urethanes from amines and alkyl halides in supercritical carbon dioxide
65. Halogen-free process for the conversion of carbon dioxide to urethanes by homogeneous catalysis
66. Chemical fixation of carbon dioxide to styrene carbonate under supercritical conditions with DMF in the absence of any additional catalysts
67. Supercritical carbon dioxide as solvent for the copolymerization of carbon dioxide and propylene oxide using a heterogeneous zinc carboxylate catalyst
68. Copolymerization of 1,2-epoxycyclohexane and carbon dioxide using carbon dioxide as both reactant and solvent
69. 2-soluble chromium porphyrin catalyst
70. 2 and 1,3-butadiene
71. Übergangsmetall-Organoverbindungen in superkritischem kohlendioxid: Löslichkeiten, reaktionen, katalysen