Application of NMR spectroscopy and LC-NMR/MS to the identification of carbohydrates in beer

Journal of Agricultural and Food Chemistry

Volumn 51, Issue 17, 2003, Pages 4847-4852

  Duarte, Iola F ^a   Godejohann, Markus ^b   Braumann, Ulrich ^b   Spraul, Manfred ^b   Gil, Ana M ^a  

^a UNIVERSITY OF AVEIRO   (Portugal)

^b BRUKER BIOSPIN GMBH   (Germany)

Author keywords

Beer; Carbohydrate; Composition; Dextrins; LC NMR MS; NMR

Indexed keywords

DEXTRIN;

ARTICLE; BEER; CARBOHYDRATE ANALYSIS; FOOD ANALYSIS; FOOD COMPOSITION; FOOD QUALITY; LIQUID CHROMATOGRAPHY; MASS SPECTROMETRY; PROTON NUCLEAR MAGNETIC RESONANCE;

BEER; CARBOHYDRATES; CHROMATOGRAPHY, LIQUID; MAGNETIC RESONANCE SPECTROSCOPY; MASS SPECTROMETRY; OLIGOSACCHARIDES;

EID: 0043062919     PISSN: 00218561     EISSN: None     Source Type: Journal    
DOI: 10.1021/jf030097j     Document Type: Article

References (19)

1. Hughes, P. S.; Baxter, E. D. Beer Quality, Safety, and Nutritional Aspects; The Royal Society of Chemistry: Cambridge, UK, 2001.
2. Shanta-Kumara, H. M. C.; Iserentant, D.; Verachtert, H. Comparative analysis of malto-oligosaccharides in different beer types by thin-layer chromatography, chemical and enzymatical analysis. Cerevisia: Belgian J. Brew. Biotechnol. 1995, 20, 47-53.
3. Uchida, M.; Nakatani, K.; Ono, M.; Nagami, K. Carbohydrates in brewing. I. Determination of fermentable sugars and oligosaccharides in wort and beer by partition high-performance liquid chromatography. J. Am. Soc. Brew. Chem. 1991, 49, 665-673.
4. Corradini, C.; Canali, G.; Nicoletti, I. Application of HPAEC-PAD to carbohydrate analysis in food products and fruit juices. Sem. Food Anal. 1997, 2, 99-111.
5. Désévaux, S.; Daems, V.; Delvaux, F.; Derdelinckx, G. Analysis of fermentable sugars and dextrins in beer by anion exchange chromatography with electrochemical detection. Sem. Food Anal. 1997, 2, 113-117.
6. Pascual-Teresa, S.; Treutter, D.; Rivas-Gonzalo, J. C.; Santos-Buelga, C. Analysis of flavonols in beverages by high-performance liquid chromatography with chemical reaction detection. J. Agric. Food Chem. 1999, 46, 4209-4213.
7. Andrés-Lacueva, C.; Mattivi, F.; Tonon, D. Determination of riboflavin, flavin mononucleotide, and flavin-adenine dinucleotide in wine and other beverages by high-performance liquid chromatography with fluorescence detection. J. Chromatogr. A 1998, 823, 355-363.
8. Klampfl, C. Analysis of organic acids and inorganic anions in different types of beer, using capillary zone electrophoresis. J. Agric. Food Chem. 1999, 47, 987-990.
9. Stevens, J. F.; Taylor, A. W.; Deinzer, M. L. Quantitative analysis of xanthohumol and related prenylflavonoids in hops and beer by liquid chromatography-tandem mass spectrometry. J. Chromatogr. A 1999, 832, 97-107.
10. Whittle, N.; Eldridge, H.; Bartley, J. Identification of polyphenols in barley and beer by HPLC/MS and HPLC/electrochemical detection. J. Inst. Brew. 1999, 105, 89-99.
11. Vinogradov, E.; Bock, K. Structural determination of some new oligosaccharides and analysis of the branching patterns of isomaltooligosaccharides from beer. Carbohydr. Res. 1998, 309, 57-64.
12. Pusecker, K.; Albert, K.; Bayer, E. Investigation of hop and beer bitter acids by coupling of high-performance liquid chromatography to nuclear magnetic resonance spectroscopy. J. Chromatogr. A 1999, 836, 245-252.
13. Duarte, I.; Barros, A.; Belton, P. S.; Righelato, R.; Spraul, M.; Humpfer, E.; Gil, A. M. High-resolution NMR spectroscopy and multivariate analysis for the characterization of beer. J. Agric. Food Chem. 2002, 50, 2475-2481.
14. Jeener, J.; Meier, B. H.; Bachmann, P.; Ernst, R. R. Investigation of exchange processes by two-dimensional NMR spectroscopy. J. Chem. Phys. 1979, 71, 4546-4553.
15. Bax, A.; Davis, D. G. MLEV-17 based two-dimensional homonuclear magnetization transfer spectroscopy. J. Magn. Reson. 1985, 65, 355-360.
16. Bax, A. A spatially selective composite 90-degrees radio frequency pulse. J. Magn. Reson. 1985, 65, 142-145.
17. Smallcombe, S. H.; Patt, S. L.; Keifer, P. A. WET solvent suppression and its applications to LC-NMR and high-resolution-NMR spectroscopy. J. Magn. Reson. A 1995, 117, 295-303.
18. Jodelet, A.; Rigby, N. M.; Colquhoun, I. J. Separation and NMR structural characterisation of singly branched α-dextrins which differ in the location of the branch point. Carbohydr. Res. 1998, 312, 139-151.
19. Careri, M.; Mangia, A.; Musci, M. Overview of the applications of liquid-chromatography-mass spectrometry interfacing systems in food analysis: Naturally occurring substances in food. J. Chromatogr. A 1998, 794, 263-297.