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Volumn 21, Issue 19, 2002, Pages 3947-3954

Photolytic zirconium benzyl bond cleavage and subsequent aryl C-F activation in zirconium complexes of fluorinated aryl diamides

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; DIMERS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLYSIS; THERMODYNAMIC STABILITY; X RAY CRYSTALLOGRAPHY;

EID: 0038682658     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0204181     Document Type: Article
Times cited : (23)

References (123)
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    • note
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  • 91
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    • Harris, R. K. Mann, B. E., Eds.; Academic Press: London
    • 3F): (a) Mann, B. E. In NMR of the Periodic Table; Harris, R. K. Mann, B. E., Eds.; Academic Press: London, 1978.
    • (1978) In NMR of the Periodic Table
    • Mann, B.E.1
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    • Mason, J., Plenum Press: New York
    • (b) Jameson, C. J. In Multinuclear NMR; Mason, J., Ed.; Plenum Press: New York, 1987.
    • (1987) Multinuclear NMR
    • Jameson, C.J.1
  • 101
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    • There is more convincing evidence for ligand-induced thermal reductive elimination from Zr(IV) dialkyls: (a) Gell, K. I.; Harris, T. V.; Schwartz, J. Inorg. Chem. 1981, 20, 481.
    • (1981) Inorg. Chem. , vol.20 , pp. 481
    • Gell, K.I.1    Harris, T.V.2    Schwartz, J.3
  • 106
    • 0001111530 scopus 로고
    • b) has been presented, although the possible involvement of radical pathways was not investigated: (a) Miller, F. D.; Sanner, R. D. Organometallics 1988, 7, 818.
    • (1988) Organometallics , vol.7 , pp. 818
    • Miller, F.D.1    Sanner, R.D.2
  • 118
    • 0037802772 scopus 로고    scopus 로고
    • note
    • Given the long photolysis time required to convert all of the starting material (as monitored by NMR), the steady state concentration of benzyl radicals is likely to be very low, making observation difficult.
  • 119
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    • note
    • 2).
  • 120
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    • note
    • -1. Unlike the methyl derivative, this absorption tails significantly into the visible region, resulting in the yellow color of the complex.
  • 121
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    • 4 unit. However, this seems unlikely to us as it necessitates C-N bond cleavage and the formation of two high-energy intermediates. (a) Edlebach, B. L.; Kraft, B. M.; Jones, W. D. J. Am. Chem. Soc. 1999, 121, 10327.
    • (1999) J. Am. Chem. Soc. , vol.121 , pp. 10327
    • Edlebach, B.L.1    Kraft, B.M.2    Jones, W.D.3


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.