Generation of Perfluoropolyphenylene Oligomers via Carbon-Fluorine Bond Activation by Cp2Zr(C6F5)2: A Dual Mechanism Involving a Radical Chain and Release of Tetrafluorobenzyne

Journal of the American Chemical Society

Volumn 121, Issue 44, 1999, Pages 10327-10331

  Edelbach, Brian L ^a   Kraft, Bradley M ^a   Jones, William D ^a  

^a UNIVERSITY OF ROCHESTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUND; CARBON; FLUORINE; FLUOROBENZENE; OLIGOMER; TETRAHYDROFURAN;

ARTICLE; DECOMPOSITION; REACTION ANALYSIS;

EID: 0033544311     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991805d     Document Type: Article

References (11)

1. There are several recent reviews on C-F activation by metal reagents, see: (a) Kiplinger, J. L.; Richmond, T. G.; Osterberg, C. E. Chem. Rev. 1994, 94, 373.
2. (b) Burdeniuc J.; Jedlicka, B.; Crabtree, R. H. Chem. Ber./ Recl. 1997, 130, 145.
3. (c) Richmond, T. G. In Topics in Organometallic Chemistry; Murai, S., Ed.; Springer: New York, 1999; Vol. 3, p 243.
4. Weydert, M.; Andersen, R. A.; Bergman, R. G. J. Am. Chem. Soc. 1993, 115, 8837.
5. Burk, M. J.; Staley, D. L.; Tumas, W. J. J. Chem. Soc., Chem. Commun. 1990, 809.
6. Burger, B. J.; Ph.D. Thesis, California Institute of Technology, 1987.
7. (a) Kiplinger, J. L.; Richmond, T. G. Chem. Commun. 1996, 1115.
8. (b) Kiplinger, J. L.; Richmond, T. G. J. Am. Chem. Soc. 1996, 118, 1805.
9. (a) Deacon, G. B.; Koplick, A. J.; Raverty, W. D.; Vince, D. G. J. Organomet. Chem. 1979, 182, 121.
10. (b) Deacon, G. B.; Mackinnon, P. I.; Tuong, T. D. Aust. J. Chem. 1983, 36, 43.
11. Edelbach, B. L.; Rahman, A. K. F.; Lachicotte, R. J.; Jones, W. D. Organometallics 1999, 18, 3170-3177.