Vapor-phase synthesis of nanoparticles

Current Opinion in Colloid and Interface Science

Volumn 8, Issue 1, 2003, Pages 127-133

  Swihart, Mark T ^a  

^a State University of New York   (United States)

Author keywords

Aerosol; Nanocrystal; Nanoparticle

Indexed keywords

AGGLOMERATION; COALESCENCE; SYNTHESIS (CHEMICAL); VAPOR PHASE EPITAXY;

VAPOR PHASE SYNTHESIS;

NANOSTRUCTURED MATERIALS;

INERT GAS; NANOPARTICLE;

AEROSOL; ANALYTICAL PARAMETERS; INSTRUMENTATION; IONIZATION; LASER SURGERY; LIQUID; LOW TEMPERATURE PROCEDURES; NANOTECHNOLOGY; POLYMERIZATION; PROCESS MONITORING; PYROLYSIS; REVIEW; SYNTHESIS; THERMAL ANALYSIS; VAPORIZATION;

EID: 0037931895     PISSN: 13590294     EISSN: None     Source Type: Journal    
DOI: 10.1016/S1359-0294(03)00007-4     Document Type: Review

References (53)

1. Kammler HK, Mädler L, Pratsinis SE. Flame synthesis of nanoparticles. Chem Eng Technol 2001;24:583-96.
2. Kruis FE, Fissan H, Peled A. Synthesis of nanoparticles in the gas phase for electronic, optical, and magnetic applications - A review. J Aerosol Sci 1998;29:511-35.
3. Hahn H. Gas phase synthesis of nanocrystalline materials. NanoStruct Mater 1997;9:3-12.
4. Grieve K, Mulvaney P, Grieser F. Synthesis and electronic properties of semiconductor nanoparticles/quantum dots. Curr Opin Colloid Interf Sci 2000;5:168-72.
5. Trindade T, O'Brien P, Pickett NL. Nanocrystalline semiconductors: Synthesis, properties, and perspectives. Chem Mater 2001;13:3843-58.
6. Murray CB, Kagan CR, Bawendi MG. Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies. Annu Rev Mater Sci 2000;30:545-610.
7. Wegner K, Walker B, Tsantilis S, Pratsinis SE. Design of metal nanoparticle synthesis by vapor flow condensation. Chem Eng Sci 2002;57:1753-62. This is the most through study of evaporation/condensation synthesis of nanoparticles of which I am aware, systematically combining flow and aerosol dynamics simulations, experimental flow characterization, and particle synthesis experiments to provide a complete picture of the particle formation process and design diagrams that can guide future experiments.
8. Maisels A, Kruis FE, Fissan H, Rellinghaus B, Zähres H. Synthesis of tailored composite nanoparticles in the gas phase. Appl Phys Lett 2000;77:4431-3. This paper presents a general means for preparing bi-component particles of uniform size and composition in the vapor phase.
9. Ohno T. Morphology of composite nanoparticles of immiscible binary systems prepared by gas-evaporation technique and subsequent vapor condensation. J Nanoparticle Res 2002;4:255-60.
10. Nakaso K, Shimada M, Okuyama K, Deppert K. Evaluation of the change in the morphology of gold nanoparticles during sintering. J Aerosol Sci 2002;33:1061-74. This work goes beyond simply making observations about particle sintering to identify the mechanism responsible for sintering in different regimes and extract rate parameters for the particles restructuring processes.
11. Nanda KK, Kruis FE, Fissan H, Acet H. Band-gap tuning of PbS nanoparticles by in-flight sintering of size classified aerosols. J Appl Phys 2002;91:2315-21.
12. Marine W, Patrone L, Luk'yanchuk B, Sentis M. Strategy of nanocluster and nanostructure synthesis by conventional pulsed laser ablation. Appl Surf Sci 2000;154-155:345-52.
13. Nakata Y, Muramoto J, Okada T, Maeda M. Particle dynamics during nanoparticle synthesis by laser ablation in a background gas. J Appl Phys 2002;91:1640-3. By combining different spectroscopic imaging technique, these authors were able to obtain time-resolved images of both atoms and clusters during laser ablation synthesis of silicon nanoparticles and to directly observe the effects of background gas on particle formation and the dynamics of the plume of ablated material.
14. Shinde SR, Kulkarni SD, Banpurkar AG, Nawathey-Dixit R, Date SK, Ogale SB. Magnetic properties of nanosized powders of magnetic oxides synthesized by pulsed laser ablation. J Appl Phys 2000;88:1566-75.
15. 2 ultrafine particles prepared by laser ablation of solid rods. J Nanoparticle Res 2002;4:215-9.
16. Makimura T, Mizuta T, Murakami K. Laser ablation synthesis of hydrogenated silicon nanoparticles with green photoluminescence in the gas phase. Jpn J Appl Phys 2002;41:L144-L146.
17. Weber AP, Seipenbusch M, Kasper G. Application of aerosol techniques to study the catalytic formation of methane on gasborne nickel nanoparticles. J Phys Chem A 2001;105:8958-63. This work demonstrates how carefully prepared and characterized nanoparticles can be used to study catalytic processes, many of which are carried out commercially on supported metal nanoparticles, in the absence of a support material and with a continuous supply of fresh nanoparticles.
18. Rexer EF, Wilbur DB, Mills JL, DeLeon RL, Garvey JF. Production of metal oxide thin films by pulsed arc molecular beam deposition. Rev Sci Instrum 2000;71:2125-30.
19. Urban FK III, Hosseini-Tehrani A, Griffiths P, Khabari A, Kim Y-W, Petrov I. Nanophase films deposited from a high-rate, nanoparticle beam. J Vasc Sci Technol B 2002;20:995-9.
20. Ostraat ML, De Blauwe JW, Green ML, Bell LD, Atwater HA, Flagan RC. Ultraclean two-stage aerosol reactor for production of oxide-passivated silicon nanoparticles for novel memory devices. J Electrochem Soc 2001;148:G265-G270. This and related papers by this group demonstrate the integration of vapor-phase synthesis of nanoparticles into a conventional semiconductor procesing environment to produce high-purity (less than one contaminant transition metal atom per 100 nanoparticles) nanoparticles that can be incorporated as an active part of a real microelectronic (flash memory) device.
21. Magnusson MH, Deppert K, Malm J-O. Single-crystalline tungsten nanoparticles produced by thermal decomposition of tungsten hexacarbonyl. J Mater Res 2000;15:1564-9.
22. Nasibulin AG, Richard O, Kauppinen EI, Brown DP, Jokiniemi JK, Altman IS. Nanoparticle synthesis by copper(II) acetylacetonate vapor decomposition in the presence of oxygen. Aerosol Sci Technol 2002;36:899-911.
23. 3+ in different host materials. J Appl Phys 2001;89:1679-86.
24. Senter AA, Chen Y, Coffer JL, Tessler LR. Synthesis of silicon nanocrystals with erbium-rich surface layers. Nano Lett 2001;1:383-6.
25. Srdić VV, Winterer M, Moller A, Miehe G, Hahn H. Nanocrystalline zirconia surface-doped with alumina: Chemical vapor synthesis, characterization, and properties. J Am Ceram Soc 2001;84:2771-6.
26. Ehrman SH, Aquino-Class MI, Zachariah MR. Effect of temperature and vapor-phase encapsulation on particle growth and morphology. J Mater Res 1999;14:1664-71. The sodium metal/metal halide chemistry studied in this paper provides a new means of controlling nanoparticle size and morphology by modifying particle coagulation and coalescence.
27. 2 particles. J Aerosol Sci 2001;32:615-30.
28. Kim JH, Germer TA, Mulholland GW, Ehrman SH. Size-monodisperse metal nanoparticles via hydrogen-free spray pyrolysis. Adv Mater 2002;14:518-21.
29. 2 nanoparticles produced by laser induced synthesis from gaseous precursors. J Mater Sci Lett 2001;20:187-91.
30. Kamlag Y, Goossens A, Colbeck I, Schoonman J. Laser CVD of cubic SiC nanocrystals. Appl Surf Sci 2001;184:118-22.
31. Ledoux G, Gong J, Huisken F, Guillois O, Reynaud C. Photoluminescence of size-separated silicon nanocrystals: Confirmation of quantum confinement. Appl Phys Lett 2002;80:4834-6.
32. Ledoux G, Amans D, Gong J, Huisken F, Cichos F, Martin J. Nanostructured films composed of silicon nanocrystals. Mater Sci Eng C 2002;19;215-8.
33. Heberlein J, Postel O, Girshick SL, et al. Thermal plasma deposition of nanophase hard coatings. Surf Coat Technol 2001;142-144:265-71. These authors, in this previous work, have developed plasma synthesis methods for preparing nanoparticles of hard, non-oxide ceramics and of depositing these as nanophase hard coatings and coarsely patterned coatings 'written' with a focused nanoparticle beam.
34. 3 in a low pressure flame, including modeling the flame structure and aerosol dynamics and particles size distribution measurements using a particle mass spectrometer.
35. Lee D, Choi M. Coalescence enhanced synthesis of nanoparticles to control size, morphology, and crystalline phase at high concentrations. J Aerosol Sci 2002;33:1-16. The infrared laser heating approach described here and in other recent papers by these authors provides a new means to slow coagulation of flame-produced particles, Flame-synthesized particles generally form fractal aggregates that coagulate much faster than spheres of the same volume. So, by spheroidizing the particles, the coagulation rate and, therefore, final particles size can be reduced and spherical particles can be obtained.
36. Wegner K, Stark WJ, Pratsinis SE. Flame-nozzle synthesis of nanoparticles with closely controlled size, morphology, and crystallinity. Mater Lett 2002;55:318-21.
37. Kammler HK, Pratsinis SE, Morrison PW Jr., Hemmerling B. Flame temperature measurements during electrically assisted aerosol synthesis of nanoparticles. Combust Flame 2002;128:369-81. This work shows quantitatively how the application of an electric field changes the structure of a particle-producing flame, and how this can be used to influence the size and morphology of the particles.
38. Mädler L, Kammler HK, Mueller R, Pratsinis SE. Controlled synthesis of nanostructured particles by flame spray pyrolysis. J Aerosol Sci 2002;33:369-89. This combined experimental and modeling study is the most thorough and systematic investigation and description of flame spray pyrolysis in the literature. It shows how the surface area (primary particle size) can be controlled via the oxidant flow rate and precursor/fuel composition.
39. Sarigiannis D, Peck JD, Kioseoglou G, Petrou A, Mountziaris TJ. Characterization of vapor-phase-grown ZnSe nanoparticles. Appl Phys Lett 2002;80:4024-6.
40. 2 flames: Gas and particle concentrations. AIChE J 2002;48:59-68. This paper describes a rare situation in which a flame nanoparticle synthesis reactor has been probed to determine temperature, gas-phase species concentrations, and particle concentration simultaneously.
41. Cho J, Choi M. Determination of number density, size and morphology of aggregates in coflow diffusion flames using light scattering and local sampling. J Aerosol Sci 2000;31:1077-95. This is one of very few papers in which particle size, morphology, and concentration have been simultaneously determined in a particle producing flame.
42. Janzen C, Kleinwechter H, Knipping J, Wiggers H, Roth P. Size analysis in low-pressure nanoparticle reactors: Comparison of particle mass spectrometry with in situ probing transmission electron microscopy. J Aerosol Sci 2002;33:833-41.
43. Bhandarkar UV, Swihart MT, Girshick SL, Kortshagen UR. Modeling of silicon hydride clustering in a low pressure silane plasma. J Phys D: Appl Phys 2000;33:2731-46.
44. Girshick SL, Swihart MT, Suh S-M, Mahajan MR, Nijhawan S. Numerical modeling of gas-phase nucleation and particle growth during chemical vapor deposition of silicon. J Electrochem Soc 2000;147:2303-11.
45. Suh S-M, Zachariah MR, Girshick SL. Numerical modeling of silicon oxide particle formation and transport in a one-dimensional low-pressure chemical vapor deposition reactor. J Aerosol Sci 2002;33:943-59.
46. Mühlenweg H, Gutsch A, Schild A, Pratsinis SE. Process simulation of gas-to-particle-synthesis via population balances: Investigation of three models. Chem Eng Sci 2002;57:2305-22. This is a thorough a valuable comparison of the capabilities of monodisperse, extended 1-dimensional, and fully two-dimensional (in particle size and surface area) sectional models of aerosol dynamics that shows that the more computationally manageable extended 1-D approach performs well.
47. Tsantilis S, Kammler HK, Pratsinis SE. Population balance modeling of flame synthesis of titania nanoparticles. Chem Eng Sci 2002;57:2139-56. A moving sectional model for the dynamics of flame synthesis of titania particles is presented here. The authors attain quantitative agreement with experiment, without using adjustable parameters, and are able to distinguish between different possible particle growth mechanisms.
48. Lee BW, Oh S, Choi M. Simulation of growth of nonspherical silica nanoparticles in a premixed flat flame. Aerosol Sci Technol 2001;35:978-89.
49. Jeong JI, Choi M. A sectional model for the analysis and growth of polydisperse non-spherical particles undergoing coagulation and coalescence. J Aerosol Sci 2001;32:565-82.
50. Rosner DE, Pyykönen JJ. Bivariate moment simulation of coagulating and sintering nanoparticles in flames. AIChE J 2002;48:476-91. This paper applies a bivariate extension of the quadrature method of moments to treat the evolution of particle size and surface area in flame-synthesis of alumina particles. This is a computationally efficient approach, compared to sectional methods described in the papers cited above. It shows that this method can usefully capture the main features of the particle size distribution and morphology, and provides a thoughtful discussion of future directions in the application of these methods.
51. Rosner DE, Yu S. MC simulation of aerosol aggregation and simultaneous spheroidization. AIChE J 2001;47:545-61.
52. Efendiev Y, Struchtrup H, Luskin M, Zachariah MR. A hybrid sectional-moment model for coagulation and phase segregation in binary liquid droplets. J Nanoparticle Res 2002;4:61-72. This paper describes a formulation and solution method for the situation of two-phase particle synthesis in which there is a distribution of 'enclosures' of one phase within another phase, as in the experimental work described by Ehrman et al. [26].
53. Efendiev Y, Zachariah MR. Hybrid Monte Carlo method for simulation of two-component aerosol coagulation and phase segregation. J Colloid Interf Sci 2002;249:30-43.