Kinetics of the BpCu-catalyzed carbene transfer reaction (Bp = dihydridobis(1-pyrazolyl)borate). Is a 14-electron species the real catalyst for the general copper-mediated olefin cyclopropanation?

Organometallics

Volumn 18, Issue 14, 1999, Pages 2601-2609

  Díaz Requejo, M Mar ^a   Belderrain, Tomás R ^a   Nicasio, M Carmen ^a   Prieto, Francisco ^a   Pérez, Pedro J ^a  

^a UNIVERSITY OF HUELVA   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000619512     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om990270u     Document Type: Article

References (30)

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27. 7 (c) When NaOTf is added to the catalytic mixture, the reaction with adventitious water (despite the efforts to dry the solvent) produces HOTf that further reacts with EDA to give an unidentified product.
28. See the Supporting Information.
29. 2 fluxionality in Tp-metal derivatives see: Trofimenko, S. Chem. Rev. 1993, 93, 943-980.
30. 17