Supramolecular organometallic polymer chemistry: Multiple morphologies and superstructures from the solution self-assembly of polyferrocene-block-polysiloxane-block-polyferrocene triblock copolymers

Chemistry - A European Journal

Volumn 7, Issue 11, 2001, Pages 2414-2424

  Resendes, Rui ^a   Massey, Jason A ^a   Temple, Karen ^a   Cao, Lan ^a   Power Billard, K Nicole ^a   Winnik, Mitchell A ^a   Manners, Ian ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

Micelles; Nanostructures; Organometallic polymers; Polyferrocene; Self assembly; Triblock copolymers

Indexed keywords

ATOMIC FORCE MICROSCOPY; BLOCK COPOLYMERS; GEL PERMEATION CHROMATOGRAPHY; GLASS TRANSITION; MICELLES; MORPHOLOGY; SELF ASSEMBLY; SOLUTIONS; TRANSMISSION ELECTRON MICROSCOPY;

ULTRACENTRIFUGATION;

ORGANOMETALLICS;

COPOLYMER; ORGANOMETALLIC COMPOUND; POLY(FERROCENYLDIMETHYLSILANE) BLOCK POLY(DIMETHYLSILOXANE) BLOCK POLY(FERROCENYLDIMETHYLSILANE); POLY(FERROCENYLMETHYLETHYLSILANE) BLOCK POLY(DIMETHYLSILOXANE) BLOCK POLY(FERROCENYLMETHYLETHYLSILANE); POLY(FERROCENYLMETHYLPHENYLSILANE) BLOCK POLY(DIMETHYLSILOXANE) BLOCK POLY(FERROCENYLMETHYLPHENYLSILANE); POLYMER; UNCLASSIFIED DRUG;

ARTICLE; ATOMIC FORCE MICROSCOPY; CHEMICAL COMPOSITION; CRYSTAL; GEL PERMEATION CHROMATOGRAPHY; MACROMOLECULE; MICELLE; MORPHOLOGY; STAINING; STRUCTURE ANALYSIS; TEMPERATURE; TRANSMISSION ELECTRON MICROSCOPY; ULTRACENTRIFUGATION;

EID: 0035354663     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/1521-3765(20010601)7:11<2414::AID-CHEM24140>3.0.CO;2-1     Document Type: Article

References (75)

1. C. Price, Pure Appl. Chem. 1983, 55, 1563.
2. M. Antionetti, C. Göltner, Angew. Chem. 1997, 109, 944
3. Angew. Chem. Int. Ed. Engl. 1997, 36, 910.
4. J. P. Spatz, S. Mössmer, M. Möller, Angew. Chem. 1996, 108, 1673
5. Angew. Chem. Int. Ed. Engl. 1996, 35, 1510.
6. For recent work on nonspherical micellar aggregates of organic block copolymers in solution, see: a) L. Zhang, A. Eisenberg, Science 1995, 268, 1728
7. b) L. Zhang, K. Yu, A. Eisenberg, Science 1996, 272, 1777
8. c) Y. Yu, A. Eisenberg, J. Am. Chem. Soc. 1997, 119, 8383
9. d) J. Tao, S. Stewart, G. Liu, M. Yang, Macromolecules 1997, 30, 2738
10. e) C. G. Göltner, B. Berton, E. Krämer, M. Antonietti, Adv. Mater. 1999, 11, 395
11. f) L. Chen, H. Shen, A. Eisenberg, J. Phys. Chem. B 1999, 103, 9488
12. g) Y.-Y. Won, H. T. Davis, F. S. Bates, Science, 1999, 283, 960
13. h) B. M. Discher, Y.-Y. Won, D. S. Ege, J. C.-M. Lee, F. S. Bates, D. E. Discher, D. A. Hammer, Science, 1999, 284, 1143
14. i) H. Shen, A. Eisenberg, Macromolecules 2000, 33, 2561
15. j) T. K. Bronich, A. M. Popov, A. Eisenberg, V. A. Kabanov, A. V. Kabanov, Langmuir, 2000, 16, 481
16. k) S. A. Jenekhe, X. L. Chen, Science 1998, 72, 864
17. l) H. Wang, H. H. Wang, V. S. Urban, K. C. Littrell, P. Thiyagarajan, L. Yu, J. Am. Chem. Soc. 2000, 122, 6855
18. m) G. Liu, J. Ding, L. Qiao, A. Guo, B. P. Dymov, J. T. Gleeson, H. K. Saijo, Chem. Eur. J. 1999, 5, 2740.
19. Other routes to amphiphilic block copolymers include: Atom-transfer radical polymerization, see: a) T. E. Patten, J. H. Xia, T. Abernathy, K. Matyjaszewski, Science 1996, 272, 866
20. b) M. Cassebras, S. Pascual, A. Polton, M. Tardi, J.-P. Vairon, Macromol. Rapid. Commun. 1999, 20, 261
21. c) P. K. Tsolakis, E. G. Koulouri, J. K. Kallitsis, Macromolecules 1999, 32, 9054
22. for nitroxide-mediated free-radical polymerization, see: d) N. A. Listigovers, M. K. Georges, P. G. Odell, B. Keoshkerian, Macromolecules 1996, 29, 8992
23. for living cationic polymerization, see: e) E. Yoshida, A. Sugita, J. Polym. Sci. Polym. Chem. A. 1998, 36, 2059
24. for ring-opening metathesis polymerization, see: f) C. W. Bielawski, T. Morita, R. H. Grubbs, Macromolecules 2000, 33, 678.
25. For recent intriguing examples of nanostructured materials based on block copolymers, see: a) C. C. Cummins, R. R. Schrock, R. E. Cohen, Chem. Mater. 1992, 4, 27
26. b) G. Liu, J. Ding, Adv. Mater. 1998, 10, 69
27. c) G. Liu, Adv. Mater. 1997, 9, 437
28. d) K. L. Wooley, Chem. Eur. J. 1997, 3, 1397
29. e) M. Moffitt, H. Vali, A. Eisenberg, Chem. Mater. 1998, 10, 1021
30. f) J. Spatz, S. Mössmer, M. Möller, M. Kocher, D. Neher, G. Wegner, Adv. Mater. 1998, 10, 473
31. g) L. Qi, H. Cölfen, M. Antonietti, Angew. Chem. 2000, 112, 617
32. Angew. Chem. Int. Ed. 2000, 39, 604
33. h) R. Ulrich, A. Du Chesne, M. Templin, U. Wiesner, Adv. Mater. 1999, 11, 141.
34. For some recent work in the field of pluronics, see: a) C. Wu, T. Liu, H. White, B. Chu, Langmuir 2000, 16, 656
35. b) C. Olivia, H. Caldararu, A. A. Caragheorgheopol, Langmuir 1999, 15, 1891
36. c) K. Schillén, K. Bryskhe, Y. S. Mel'nikova, Macromolecules 1999, 32, 6885
37. d) Y. Chengzhong, Y. Yu, D. Zhao, Chem. Commun. 2000, 575
38. e) A. Kyritsis, P. Polycarpos, S.-M. Mai, C. Booth, Macromolecules, 2000, 33, 4581.
39. For insight into the factors which govern the self-assembly of triblock copolymers see, for example: a) V. Balsamo, R. Stadler, Macromolecules 1999, 32, 3994
40. b) O. F. Olaj, B. Neubauer, G. Zifferer, Macromolecules 1998, 31, 4350
41. c) S. Phan, G. H. Fredrickson, Macromolecules 1998, 31, 59
42. d) M. V. D. Banez, K. L. Robinson, S. P. Armes, Macromolecules 2000, 33, 451.
43. For some recent work on non-spherical micelles obtained from amphiphilic triblock copolymers, see: a) G. Yu, A. Eisenberg, Macromolecules 1998, 31, 5546
44. b) S. Stewart, G. Liu, Angew. Chem. 2000, 112, 348
45. Angew. Chem. Int. Ed. 2000, 39, 340.
46. G. ten Brinke, G. Hadziioannou, Macromolecules 1987, 20, 486.
47. A. N. Semenov, J.-F. Joanny, A. R. Khokhlov, Macromolecules 1995, 28, 1066.
48. A. Halperin, Macromolecules 1991, 24, 1418.
49. Y. Wang, W. L. Mattice, D. H. Napper, Macromolecules 1992, 25, 4073.
50. M. A. Hempenius, B. M. W. Langeveld-Voss, J. A. E. H. van Haare, R. A. J. Janssen, S. S. Sheiko, J. P. Spatz, M. Möller, E. W. Meijer, J. Am. Chem. Soc. 1998, 120, 2798.
51. G. N. Tew, M. U. Pralle, S. I. Stupp, J. Am. Chem. Soc. 1999, 121, 9852.
52. L. A. Schwegler, S. S. Sheiko, M. Möller, E. Fossum, K. Matyjaszewski, Macromolecules 1999, 32, 5901.
53. Y. Heischkel, H.-W. Schmidt, Macromol. Chem. Phys. 1998, 199, 869.
54. R. Rulkens, Y. Ni, I. Manners, J. Am. Chem. Soc. 1994, 116, 12121.
55. Y. Ni, R. Rulkens, I. Manners, J. Am. Chem. Soc. 1996, 118, 4102.
56. J. Massey, K. N. Power, I. Manners, M. A. Winnik, J. Am. Chem. Soc. 1998, 120, 9533.
57. J. Massey, K. N. Power, I. Manners, M. A. Winnik, Adv. Mater. 1998, 10, 1559.
58. R. Peterson, D. A. Foucher, B.-Z. Tang, A. J. Lough, N. P. Raju, J. E. Greedan, I. Manners, Chem. Mater. 1995, 7, 2045.
59. M. MacLachlan, M. Ginzberg, N. Coombs, T. W. Coyle, N. P. Raju, J. E. Greedan, G. A. Ozin, I. Manners, Science 2000, 287, 1460.
60. I. Manners, Chem. Commun. 1999, 857.
61. R. Resendes, A. Berenbaum, G. Stojevic, F. Jäkle, A. Bartole, F. Zamanian, G. Dubois, C. Hersom, K. Balmain, I. Manners, Adv. Mater. 2000, 12, 327.
62. P. Gómez-Elipe, R. Resendes, P. M. Macdonald, I. Manners, J. Am. Chem. Soc. 1998, 120, 8348.
63. K. Temple, F. Jäkle, J. B. Sheridan, I. Manners, J. Am. Chem. Soc. 2001, in press.
64. R. Resendes, J. A. Massey, H. Dorn, K. N. Power, M. A. Winnik, I. Manners, Angew. Chem. 1999, 111, 2738
65. Angew. Chem. Int. Ed. 1999, 38, 2570.
66. a) J. Rasburn, R. Peterson, T. Jahr, R. Rulkens, I. Manners, G. J. Vancso, Chem. Mater. 1995, 7, 871
67. b) V. S. Papkov, M. V. Gerasimov, I. I. Dubovik, S. Sharma, V. V. Dementiev, K. H. Pannell, Macromolecules 2000, 33, 7107.
68. a) S. J. Holder, R. C. Hiorns, N. A. J. M. Sommerdijk, S. J. Williams, R. G. Jones, R. J. M. Nolte, Chem. Commun. 1998, 14, 1445
69. b) N. A. J. M. Sommerdijk, S. J. Holder, R. C. Hiorns, R. G. Jones, R. J. M. Nolte, Macromolecules 2000, 33, 8289.
70. Similar flower-like structures have been seen in materials obtained from the directed precipitation of calcium phosphate in the presence of amphiphilic block copolymers, see: M. Antonietti, M. Breulmann, G. Göltner, H. Cölfen, K. K. W. Wong, D. Walsh, S. Mann, Chem. Eur. J. 1998, 4, 2493.
71. M. A. Hayat, S. E. Miller, Negative Staining, McGraw-Hill, New York, 1990.
72. S. N. Magonov, M.-H. Whangbo, Surface Analysis with STM and AFM: Experimental and Theorectical Aspects of Image Analysis, Wiley, Toronto, 1996.
73. K. Temple, J. A. Massey, Z. Chen, N. Vaidya, A. Berenbaum, M. D. Foster, I. Manners, J. Inorg. Organomet. Polym. 1999, 9, 189.
74. R. Rulkens, A. J. Lough, I. Manners, S. R. Lovelace, C. Grant, W. E. Geiger, J. Am. Chem. Soc. 1996, 118, 12683.
75. In parallel studies we have shown that crystallinity appears to play a similar role in the the formation of cylindrical rather than spherical micelles for the diblock copolymers PFDMS-b-PDMS and PFDMS-b-PI (PI = polyisoprene); see: J. A. Massey, K. Temple, L. Cao, Y. Rharbi, J. Raez, M. A. Winnik, I. Manners, J. Am. Chem. Soc. 2000, 122, 11577.