Polymers with very low polydispersities from atom transfer radical polymerization

Science

Volumn 272, Issue 5263, 1996, Pages 866-868

  Patten, Timothy E ^a   Xia, Jianhui ^a   Abernathy, Teresa ^a   Matyjaszewski, Krzysztof ^a  

^a CARNEGIE MELLON UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ATOMS; COPPER COMPOUNDS; ESTERS; MOLECULAR WEIGHT; MOLECULAR WEIGHT DISTRIBUTION; MONOMERS; REACTION KINETICS; STYRENE;

ACRYLATES; ATOM TRANSFER RADICAL POLYMERIZATION; COPPER HALIDES; LIGANDS; LINEAR SEMILOGARITHMIC KINETIC PLOTS; POLYDISPERSITY;

ANIONIC POLYMERIZATION;

EID: 0030148869     PISSN: 00368075     EISSN: None     Source Type: Journal    
DOI: 10.1126/science.272.5263.866     Document Type: Article

References (17)

1. M. Szwarc and M. Levy, J. Am. Chem. Soc. 78, 2657 (1956).
2. M. Stwarc, Nature 178, 1168 (1956).
3. O. W. Webster, Science 251, 887 (1991).
4. D. Greszta, D. Mardare, K. Matyjaszewski, Macromolecules 27, 638 (1994).
5. E. Rizzardo, Chem. Aust. 1987, 32 (1987).
6. M. K. Georges, R. P. N. Veregin, P. M. Kazmaier, G. K. Hamer, M. Saban, Macromolecules 27, 7228 (1994).
7. H. J. Harwood, L. D. Arvanitopoulos, M. P. Greuel, Polym. Prepr. Am. Chem. Soc. Div. Polym. Chem. 35, 549 (1994).
8. B. B. Wayland, G. Pszmik, S. L. Mukerjee, M. Fryd, J. Am. Chem. Soc. 116, 7943 (1994).
9. D. Mardare and K. Matyjaszewski, Macromolecules 27, 645 (1994).
10. S. Gaynor, J. S. Wang, K. Matyjaszewski, ibid. 28, 8051 (1995).
11. J. S. Wang and K. Matyjaszewski, J. Am. Chem. Soc. 117, 5614 (1995).
12. _, Macromolecules 28, 7901 (1995).
13. M. Kato, M. Kamigaito, M. Sawamoto, T. Higashimura, ibid., p. 1721.
14. T. B. Hadda and H. L. Bozec, Polyhedron 7, 575 (1988).
15. Synthesized according to the procedure in R. Kramer, J. M. Lehn, A. D. Cian, J. Fisher, Angew. Chem. Intl. Ed. Engl. 32, 703 (1993).
16. K. Matyjaszewski et al., U.S. patent pending.
17. This work was funded in part by the Office of Naval Research.