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Volumn 118, Issue 50, 1996, Pages 12683-12695

Linear oligo(ferrocenyldimethylsilanes) with between two and nine ferrocene units: Electrochemical and structural models for poly(ferrocenylsilane) high polymers

Author keywords

[No Author keywords available]

Indexed keywords

FERROCENE DERIVATIVE; SILANE DERIVATIVE;

EID: 0030467453     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja962470s     Document Type: Article
Times cited : (342)

References (80)
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    • note
    • 4Li). Attempts to achieve ROP by use of small quantities of anionic initiator were, however, unsuccessful (see ref 20).
  • 33
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    • and references cited therein
    • Reaction of the silicon-bridged [1]ferrocenophane 5 with small amounts of anionic initiators yields living poly(ferrocenylsilanes). See Ni, Y.; Rulkens, R.; Manners, I. J. Am. Chem. Soc. 1996, 118, 4102 and references cited therein.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 4102
    • Ni, Y.1    Rulkens, R.2    Manners, I.3
  • 43
    • 12644315835 scopus 로고    scopus 로고
    • note
    • Seyferth et. al. reported on the isolation of a pentaferrocenylphosphine, but no electrochemical studies on this compound were reported. (see ref 20).
  • 45
    • 12644276246 scopus 로고    scopus 로고
    • note
    • 2Cl was reported: see ref 47.
  • 49
    • 12644291780 scopus 로고    scopus 로고
    • note
    • 3 has been independently reported previously by ourselves (see ref 48) and by Pannell et. al. (see ref 47).
  • 50
    • 12644270050 scopus 로고    scopus 로고
    • note
    • 2 = -158°. For a perfect trans planar zigzag conformation all angles φ, ψ, and χ would be 180°.
  • 54
    • 12644290100 scopus 로고    scopus 로고
    • note
    • 1/2C*, where F is the Faraday constant, A is electrode area, and D and C* are the diffusion coefficient and bulk concentration, respectively, of the electrochemical reactant.
  • 57
    • 12644255514 scopus 로고    scopus 로고
    • note
    • 1/2 for an oxidation process.
  • 66
    • 0000544154 scopus 로고
    • Recent papers containing leading references to the IT bands of biferrocenium and related ions: (a) Blackbourn, R. L.; Hupp, J. T. J. Phys. Chem. 1990, 94, 1788 (b) Sinha, U.; Lowery, M. D.; Hammack, W. S.; Hendrickson, D. N.; Drickamer, H. G. J. Am. Chem. Soc. 1987, 109, 7340.
    • (1990) J. Phys. Chem. , vol.94 , pp. 1788
    • Blackbourn, R.L.1    Hupp, J.T.2
  • 68
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    • Cotton, F. A., Ed.; John Wiley and Sons: New York
    • max is energy at maximum absorption. See Hush, N. S. in Progress in Inorganic Chemistry; Cotton, F. A., Ed.; John Wiley and Sons: New York, 1967; Vol 8, p 391.
    • (1967) Progress in Inorganic Chemistry , vol.8 , pp. 391
    • Hush, N.S.1
  • 70
    • 12644305720 scopus 로고    scopus 로고
    • note
    • 2, where d = metal-metal separation (see ref 66).
  • 72
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    • note
    • + adopts a similar conformation in the solid state; see ref 12.
  • 79
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    • Program for Absorption Correction; University of Göttingen, Germany
    • Sheldrick, G. M. SHELXA-90, Program for Absorption Correction; University of Göttingen, Germany.
    • SHELXA-90
    • Sheldrick, G.M.1
  • 80
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    • Siemens Analytical X-ray; Instruments Inc., Madison, WI, U. S. A.
    • Sheldrick, G. M. SHELXTL\PC V5.0, Siemens Analytical X-ray; Instruments Inc., Madison, WI, U. S. A.
    • SHELXTL\PC V5.0
    • Sheldrick, G.M.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.