Self-assembled structures from an amphiphilic multiblock copolymer containing rigid semiconductor segments

Macromolecules

Volumn 33, Issue 22, 2000, Pages 8289-8294

  Sommerdijk, Nico A J M ^a,c   Holder, Simon J ^b,c   Hiorns, Roger C ^b   Jones, Richard G ^b   Nolte, Roeland J M ^a,c  

^a EINDHOVEN UNIVERSITY OF TECHNOLOGY   (Netherlands)

^b UNIVERSITY OF KENT   (United Kingdom)

^c RADBOUD UNIVERSITY NIJMEGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

AMPHIPHILIC MULTIBLOCK COPOLYMER; MICELLAR RODS; POLYMETHYL PHENYLSILANE; VESICLES;

AGGLOMERATION; COMPOSITION EFFECTS; CONFORMATIONS; ELECTRONIC PROPERTIES; MICELLES; MOLECULAR STRUCTURE; MORPHOLOGY; OPTICAL PROPERTIES; POLYETHYLENE OXIDES; POLYSILANES; SOLVENTS;

BLOCK COPOLYMERS;

EID: 0034292209     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0011385     Document Type: Article

References (85)

1. (a) Stupp, S. I.; LeBonheur, V.; Walker, K.; Li, L. S.; Huggins, K.; Keser, M.; Amstutz, A. Science 1997, 276, 384-389.
2. (b) Frontiers in Materials Science: special section in Science 1997, 277, 1213-1253.
3. (c) Stupp, S. I. Curr. Opin. Colloid Interface Sci. 1998, 3, 20-26.
4. (d) Zubarev, E. R.; Pralle, M. U.; Li, L.; Stupp, S. I. Science 1999, 283, 523-526.
5. (e) Ruokolainen, J.; Mäkinen, R.; Torkkeli, M.; Mäkelä, T.; Serimaa, R.; ten Brinke, G.; Ikkala, O. Science 1998, 280, 557.
6. (f) Ruokolainen, J.; Saariaho, M.; Ikkala, O.; ten Brinke, G.; Thomas, M.; Torkkeli, M.; Serimaa, R. Macromolecules 1999, 32, 1152.
7. (g) Ruokolainen, J.; ten Brinke, G.; Ikkala, O. Adv. Mater. 1999, 11, 777.
8. (h) Lee, M.; Cho, B.-Ki.; Kim, H.; Yoon, J.-Y.; Zin, W.-C. J. Am. Chem. Soc. 1998, 120, 9168-9179.
9. (i) Lee, M.; Cho, B.-Ki.; Kim, H.; Zin, W.-C. Angew. Chem., Int. Ed. Engl. 1998, 37, 638-640.
10. (a) François, B.; Pitois, O.; François, J. Adv. Mater. 1995, 7, 1041-1044.
11. (b) Chen, J. T.; Thomas, E. L.; Ober, C. K.; Mao, G.-P. Science 1996, 273, 343.
12. (c) Kumaki, J.; Hashimoto, T. J. Am. Chem. Soc. 1998, 720, 423-424.
13. (d) Werts, M. P. L.; van der Vegte, E. W.; Grayer, V.; Esselink, E.; Tsitsilianis, C.; Hadziiouannou, G. Adv. Mater. 1998, 10, 452.
14. (e) Liu, G.; Ding, J.; Stuart, S. Angew. Chem., Int. Ed. Engl. 1999, 38, 835-838.
15. (a) Price, C. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p 39. Selb, J.; Gallot, Y. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1985; Vol. 2, p 327.
16. (a) Price, C. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p 39. Selb, J.; Gallot, Y. In Developments in Block Copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1985; Vol. 2, p 327.
17. (b) Tuzar, Z.; Kratochvil, P. In Surface and Colloid Science; Matijevic, E., Ed.; Plenum Press: New York, 1993; Vol. 15, p 1.
18. (a) Osaheni, J. A.; Jenekhe, S. A. J. Am. Chem. Soc. 1995, 117, 7389-7398.
19. (b) Jenekhe S. A.; Chen, X. L. Science 1998, 279, 1903-1907.
20. (c) Jenekhe, S. A.; Chen, X. L. Science 1999, 283, 372-375.
21. (d) Hempenius, M. A.; Langeveld-Voss, B. M. W.; van Haare, A. E. H.; Janssen, R. A. J.; Sheiko, S. S.; Spatz, J. P.; Möller, M. J. Am. Chem. Soc. 1998, 120, 2798-7398.
22. (e) Sanji, T.; Nakatsuka, Y.; Kitayama, F.; Sakurai, H. Chem. Commun. 1999, 2201.
23. (f) Fossum, E.; Matyjaszewski, K.; Sheiko, S. S.; Möller, M. Macromolecules 1997, 30, 1765-1767.
24. (a) Holder, S. J.; Hiorns, R. C.; Sommerdijk, N. A. J. M.; Williams, S. J.; Jones, R. G.; Nolte, R. J. M. Chem. Commun. 1998, 1443.
25. (b) Sommerdijk, N. A. J. M.; Holder, S. J.; Hiorns, R. C.; Jones, R. G.; Nolte, R. J. M. Polym. Mater. Sci. Eng. 1999, 80, 29.
26. Cornelissen, J. J. L. M.; Fischer, M.; Sommerdijk, N. A. J. M.; Nolte, R. J. M. Science 1998, 280, 1477.
27. (a) van Hest, J. C. M.; Delnoye, D. A. P.; Baars, M. W. P. L.; van Genderen, M. H. P.; Meijer, E. W. Science 1995, 268, 1592-1595.
28. (b) van Hest, J. C. M.; Delnoye, D. A. P.; Baars, M. W. P. L.; Elissen-Román, C.; van Genderen, M. H. P.; Meyer, E. W. Chem. Eur. J. 1996, 2, 1616-1626.
29. (c) Zhang, L.; Eisenberg, A. Science 1995, 268, 1728-1731.
30. (d) Zhang, L.; Bartels, C.; Shen, H.; Eisenberg, A. Phys. Rev. Lett. 1997, 79, 5034-5037.
31. (e) Zhang, L.; Eisenberg, A. J. Am. Chem. Soc. 1996, 118, 3168.
32. (f) Zhang, L.; Yu, K.; Eisenberg, A. Science 1996, 272, 1777-1779.
33. (g). Zhang, L.; Eisenberg, A. Macromolecules 1999, 32, 2239-2249.
34. (h) Förster, S.; Antonietti, M. Adv. Mater. 1998, 10, 195-217.
35. (i) Discher, B. M.; Won, Y.-Y.; Ege, D. S.; Lee, J. C.-M.; Bates, F.; Discher, D. E.; Hammer, D. A. Science 1999, 284, 1143.
36. (a) Miller, R. D.; Michl, J. Chem. Rev. 1989, 89, 1359-1410.
37. (b) Inorganic Polymers; Mark, J. E., Allock, H. R., West, R., Eds.; Prentice Hall: Englewood Cliffs, NJ, 1992.
38. (c) West, R. Organopolysilanes. In Comprehensive Organometallic Chemistry; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Elmsford, NY, 1994.
39. (a) Song, K.; Kuzmany, H.; Wallraf, G. M.; Miller, R. D.; Rabolt, J. F. Macromolecules 1990, 23, 3870-3872.
40. (b) Hsiao, Y. L.; Waymouth, R. M. J. Am. Chem. Soc. 1994, 116, 9779-9780.
41. (c) Yuan, C. H.; West, R. Macromolecules 1994, 27, 629-630.
42. (d) Kani, R.; Nakano, Y.; Majima, Y.; Hayase, S.; Yuan, C.-H.; West. R. Macromolecules 1994, 27, 1911-1914.
43. (e) Herrrema, J. K.; van Hutten, P. F.; Gill, R. E.; Wildeman, J.; Wieringa, R. H.; Hadziiouannou, G. Macromolecules 1995, 28, 8102-8116.
44. (f) Oka, K.; Fujiue, N.; Nakanishi, S.; Takata, T.; Dohmaru, T.; Yuan, C. H.; West, R. Chem. Lett. 1995, 875-876.
45. (g) Bukalov, S. S.; Leites, L. A.; West, R.; Asuke, T. Macromolecules 1996, 29, 907-912.
46. (h) van der Laan, G. P.; de Haas, M. P.; Hummel, A. J. Phys. Chem. 1996, 100, 5470-5480.
47. (i) Fujiki, M. J. Am. Chem. Soc. 1996, 118, 7424-7425.
48. (j) Oka, K.; Fujiue, N.; Dohmaru, T. J. Am. Chem. Soc. 1997, 119, 4074-4075.
49. (k) Obata, K.; Kira, M. Chem. Commun. 1998, 1309-1310.
50. (l) Ebata, K.; Furukawa, K.; Matsumoto, N. J. Am. Chem. Soc. 1998, 120, 7367-7368.
51. 2: Fossum, E.; Love, J. A.; Matyjaszewski, K. J. Organomet. Chem. 1995, 253, 449.
52. Jones, R. G.; Holder, S. J. Macromol. Chem. Phys. 1997, 198, 3571-3579.
53. A polydispersity of 1.6 (recorded by SEC) corresponds to an extent of reaction, p, of 0.6 in terms of the kinetics of the linear step-reaction polymerization involved in the block copolymer formation. This in turn specifies a number average degree of polymerisation (DP) of 2.5, in excellent agreement with the expected Flory distribution. See: Flory, P. J. Principles of Polymer Chemistry; Cornell University Press: Ithaca, NY, 1953; Chapter 8.
54. Fendler, J. M. Membrane Mimetic Chemistry; Wiley: New York, 1982.
55. max = 339 nm; for the homopolymer PMPS in solution Amax has been reported to be between 337 and 340 nm; see also ref 8.
56. Schreiber, M. Synth. Met. 1993, 55-57, 50-55.
57. The conductivity of the polymer was sufficient to allow imaging of the helices by SEM without the application of a conducting film.
58. (a) Fujiki, M. J. Am. Chem. Soc. 1994, 116, 11976-11981.
59. (b) Ebihara, K.; Koshihara, S.-y.; Yoshimoto, M.; Maeda, T.; Ohnishi, T.; Koinuma, H.; Fujiki, M. Jpn. J. Appl. Phys. 1997, 36, L 1211-L 1213.
60. (c) Fujiki, M. Appl. Phys. Lett. 1994, 65, 3251-3253.
61. (d) Obata, K.; Kabuto, C.; Kira, M. J. Am. Chem. Soc. 1997, 119, 11345-11346.
62. (e) Terunuma, D.; Nagumo, K.; Kamata, N.; Matsuoka, K.; Kuzuhara, H. Chem. Lett. 1998, 681-682.
63. (f) Fujiki, M.; Toyoda, S.; Yuan, C.-H.; Takigawa, H. Chirality 1998, 10, 667-675.
64. (g) Obata, K.; Kira, M. Macromolecules 1998, 31, 4666.
65. (a) Schilling, F. C.; Bovey, F. A.; Lovinger, A. J.; Zeigler, J. M. Macromolecules 1989, 22, 3655-3063.
66. (b) Schilling, F. C.; Lovinger, A. J.; Zeigler, J. M.; Davis, D.; Bovey, F. A. Macromolecules 1989, 22, 4645-4650.
67. (c) Miller, R. D.; Farmer, B. L.; Flemming, W.; Sooriyakumaran, R.; Rabolt, J. F. J. Am. Chem. Soc. 1987, 109, 2509-2510.
68. (d) Furukawa, S. Thin Solid Films 1998, 331, 222-228.
69. Calculations have indicated that PMPS could possibly exist as a loosely wound 107 helix see: Sundararajan, P. R. Macromolecules 1988, 21, 1256-1261. More recently, a helical conformation was calculated and demonstrated after doping with poly[(s)-2-methylbutylphenylmethyl]silane: Toyoda, S.; Fujiki, M. Chem Lett. 1999, 699-700.
70. Calculations have indicated that PMPS could possibly exist as a loosely wound 107 helix see: Sundararajan, P. R. Macromolecules 1988, 21, 1256-1261. More recently, a helical conformation was calculated and demonstrated after doping with poly[(s)-2-methylbutylphenylmethyl]silane: Toyoda, S.; Fujiki, M. Chem Lett. 1999, 699-700.
71. Teramae, H.; Takeda, K. J. Am. Chem. Soc. 1989, 111, 1281-1282.
72. Chan, H. S.; Bromberg, S.; Dill, K. A. Philos. Trans. R. Soc. London B 1995, 348, 61-70.
73. Draper, D. E. Trends Biochem. Sci. 1996, 21, 145-146.
74. (a) Nelson, J. C.; Saven, J. G.; Moore, J. S.; Wolynes, P. G. Science 1997, 277, 1793-1796.
75. (b) Prince, R. B.; Saven, J. G.; Wolynes, P. G.; Moore, J. S. J. Am. Chem. Soc. 1999, 121, 3114-3121.
76. Challa, G. Stereoregular Interpolymer Complexes. In Integration of Fundamental Polymer Science and Technology; Lemstra, P. J., Kleintjes, L. A., Eds.; Elsevier: London, 1991; Vol. 5, pp 85-95.
77. Akagi, K.; Piao, G.; Kaneko, S.; Sakamaki, K.; Shinakawa, H.; Kyotami, M. Science 1998, 282, 1683-1686.
78. Some examples of supercoiling in selfassembled nanostructures have appeared in the literature: (a) Sommerdijk, N. A. J. M.; Buynsters, P. J. J. A.; Akdemir, H.; Geurts, D. G.; Feiters, M. C.; Nolte, R. J. M.; Zwanenburg, B. Chem. Eur. J. 1998, 4, 127-136. (b) Yang, W.; Chai, X.; Chi, L.; Liu, X.; Cao, Y.; Lu, R.; Jiang, Y.; Tang, X.; Fuchs, H.; Li, T. Chem. Eur. J. 1999, 5, 1144-1149. (c) Engelkamp, H.; Middelbeek, S.; Nolte, R. J. M. Science 1999, 284, 785-788.
79. Some examples of supercoiling in selfassembled nanostructures have appeared in the literature: (a) Sommerdijk, N. A. J. M.; Buynsters, P. J. J. A.; Akdemir, H.; Geurts, D. G.; Feiters, M. C.; Nolte, R. J. M.; Zwanenburg, B. Chem. Eur. J. 1998, 4, 127-136. (b) Yang, W.; Chai, X.; Chi, L.; Liu, X.; Cao, Y.; Lu, R.; Jiang, Y.; Tang, X.; Fuchs, H.; Li, T. Chem. Eur. J. 1999, 5, 1144-1149. (c) Engelkamp, H.; Middelbeek, S.; Nolte, R. J. M. Science 1999, 284, 785-788.
80. Some examples of supercoiling in selfassembled nanostructures have appeared in the literature: (a) Sommerdijk, N. A. J. M.; Buynsters, P. J. J. A.; Akdemir, H.; Geurts, D. G.; Feiters, M. C.; Nolte, R. J. M.; Zwanenburg, B. Chem. Eur. J. 1998, 4, 127-136. (b) Yang, W.; Chai, X.; Chi, L.; Liu, X.; Cao, Y.; Lu, R.; Jiang, Y.; Tang, X.; Fuchs, H.; Li, T. Chem. Eur. J. 1999, 5, 1144-1149. (c) Engelkamp, H.; Middelbeek, S.; Nolte, R. J. M. Science 1999, 284, 785-788.
81. Cooperative effects of monomer units resulting in a preferred handedness of the helix have been described for polymeric as well as for supramolecular systems. See: (a) Green, M. M.; Reidy, M. P. J. Am. Chem. Soc. 1989, 111, 8850. (b) Green, M. M.; Peterson, N. C.; Sato, T.; Teramoto, A.; Cook, R.; Lifson, S. Science 1996, 268, 1860. (c) Palmans, A. R. A.; Vekemans, J. A. J. M.; Havinga, E. E.; Meijer, E. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 2648-2651. (d) Langeveld-Vos, B. M. W.; Waterval, R. J. M.; Janssen, R. A. J.; Meijer, E. W. Macromolecules 1999, 32, 227-230.
82. Cooperative effects of monomer units resulting in a preferred handedness of the helix have been described for polymeric as well as for supramolecular systems. See: (a) Green, M. M.; Reidy, M. P. J. Am. Chem. Soc. 1989, 111, 8850. (b) Green, M. M.; Peterson, N. C.; Sato, T.; Teramoto, A.; Cook, R.; Lifson, S. Science 1996, 268, 1860. (c) Palmans, A. R. A.; Vekemans, J. A. J. M.; Havinga, E. E.; Meijer, E. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 2648-2651. (d) Langeveld-Vos, B. M. W.; Waterval, R. J. M.; Janssen, R. A. J.; Meijer, E. W. Macromolecules 1999, 32, 227-230.
83. Cooperative effects of monomer units resulting in a preferred handedness of the helix have been described for polymeric as well as for supramolecular systems. See: (a) Green, M. M.; Reidy, M. P. J. Am. Chem. Soc. 1989, 111, 8850. (b) Green, M. M.; Peterson, N. C.; Sato, T.; Teramoto, A.; Cook, R.; Lifson, S. Science 1996, 268, 1860. (c) Palmans, A. R. A.; Vekemans, J. A. J. M.; Havinga, E. E.; Meijer, E. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 2648-2651. (d) Langeveld-Vos, B. M. W.; Waterval, R. J. M.; Janssen, R. A. J.; Meijer, E. W. Macromolecules 1999, 32, 227-230.
84. Cooperative effects of monomer units resulting in a preferred handedness of the helix have been described for polymeric as well as for supramolecular systems. See: (a) Green, M. M.; Reidy, M. P. J. Am. Chem. Soc. 1989, 111, 8850. (b) Green, M. M.; Peterson, N. C.; Sato, T.; Teramoto, A.; Cook, R.; Lifson, S. Science 1996, 268, 1860. (c) Palmans, A. R. A.; Vekemans, J. A. J. M.; Havinga, E. E.; Meijer, E. W. Angew. Chem., Int. Ed. Engl. 1997, 36, 2648-2651. (d) Langeveld-Vos, B. M. W.; Waterval, R. J. M.; Janssen, R. A. J.; Meijer, E. W. Macromolecules 1999, 32, 227-230.
85. Nakayama, Y.; Hirooka, K.; Oka, K.; West, R. Solid State Commun. 1999, 109, 45-49.