Chemical and spectroscopic definition of the peroxide-level intermediate in the multicopper oxidases: Relevance to the catalytic mechanism of dioxygen reduction to water

Journal of the American Chemical Society

Volumn 118, Issue 13, 1996, Pages 3202-3215

  Shin, Woonsup ^a   Sundaram, Uma M ^a   Cole, James L ^a   Zhang, Hua H ^a   Hedman, Britt ^a   Hodgson, Keith O ^a   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

COPPER COMPOUNDS; MASS SPECTROMETRY; OXYGEN; PEROXIDES; PH EFFECTS; REDUCTION;

CHARGE TRANSFER ABSORPTION SPECTRUM; CIRCULAR DICHROISM; DIOXYGEN; INTERMEDIATES; MAGNETIC CIRCULAR DICHROISM; MULTICOPPER OXIDASE;

ENZYMES;

LACCASE; OXIDOREDUCTASE;

ARTICLE; ENZYME MECHANISM; REACTION ANALYSIS; REDUCTION; SPECTROPHOTOMETRY;

EID: 0030567363     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja953621e     Document Type: Article

References (3)

1. Malkin, R.; Malmström, B. G. Adv. Enzymol. Relat. Areas Motl Biol. 1970, 33, 177.
2. Malmström, B. G.; Andréasson, L.-E.; Reinhammar, B. In Enzymes, 3rd ed.; Boyer, P. D., Ed.; Academic: New York, NY, 1975; Vol. 12, p 507.
3. Solomon, E. I.; Baldwin, M. J.; Lowery, M. D. Chem. Rev. 1992, 92, 521.