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Volumn 35, Issue 21, 1996, Pages 6273-6281

[FeIII(PMA)]2-: A Mononuclear Non-Heme Iron Complex That Catalyzes Alkane Oxidation

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Indexed keywords


EID: 0001634379     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic960400g     Document Type: Article
Times cited : (84)

References (91)
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    • III system) accelerates the alkane oxidation reactions (from hours to minutes). See: Barton, D. H. R.; Doller, D. Acc. Chem. Res. 1992, 25, 504.
    • (1992) Acc. Chem. Res. , vol.25 , pp. 504
    • Barton, D.H.R.1    Doller, D.2
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    • Alkane functionalization with simple iron (and ruthenium) salts in combination with heptanal, molecular oxygen, and a catalytic amount of acetic acid has also been reported: Murahashi, S.; Oda, Y.; Naota, T. J. Am. Chem. Soc. 1992, 114, 7913.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 7913
    • Murahashi, S.1    Oda, Y.2    Naota, T.3
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    • note
    • 3 = hydrotris(pyrazolyl)borate; OAc = acetate; PA = picolinic acid; py = pyridine; bpy = bipyridine; phen = 1,10-phenanthroline; tmima = tris((l-methylimidazol-2-yl)methyl)amine.
  • 56
    • 2542462504 scopus 로고    scopus 로고
    • U.S. Patent 3,549,712, 1970
    • Hay, A. S.; Becker, H.-D. U.S. Patent 3,549,712, 1970.
    • Hay, A.S.1    Becker, H.-D.2
  • 57
    • 2542453224 scopus 로고    scopus 로고
    • In the case of substrates with limited solubility/miscibility, 70 equiv was used
    • In the case of substrates with limited solubility/miscibility, 70 equiv was used.
  • 58
    • 2542464415 scopus 로고    scopus 로고
    • Interestingly, when cyclohexanol is used as the substrate, the 3 + TBHP mixture converts it into cyclohexanone
    • Interestingly, when cyclohexanol is used as the substrate, the 3 + TBHP mixture converts it into cyclohexanone.
  • 59
    • 85088224788 scopus 로고    scopus 로고
    • 2O afford very low yields of cyclohexanol and cyclohexanone
    • 2O afford very low yields of cyclohexanol and cyclohexanone.
  • 63
    • 85088232599 scopus 로고    scopus 로고
    • note
    • + and hence the yields of cyclohexanol and cyclohexanone.
  • 70
    • 0001405073 scopus 로고
    • - ligand cannot stabilize the Fe(V) center since the ligand contains H atoms on adjacent carbon atoms. The amide group in such cases is known to undergo reductive elimination to form imine and in the process causes reduction of the iron center. For more discussion, see: Collins, T. J. Acc. Chem. Res. 1994, 27, 279.
    • (1994) Acc. Chem. Res. , vol.27 , pp. 279
    • Collins, T.J.1
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    • Kochi, J. K.; Ed.; Wiley: New York
    • Kochi, J. K. In Free Radicals; Kochi, J. K.; Ed.; Wiley: New York, 1973; Vol. II, pp 689-690.
    • (1973) Free Radicals , vol.2 , pp. 689-690
    • Kochi, J.K.1
  • 76
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    • Ready oxidation of benzyl alcohol to benzaldehyde under our reaction conditions does not allow us to detect benzyl alcohol in such reactions
    • Ready oxidation of benzyl alcohol to benzaldehyde under our reaction conditions does not allow us to detect benzyl alcohol in such reactions.
  • 82
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    • 4 medium always afford much lower yields of the three oxidation products (Table 1)
    • 4 medium always afford much lower yields of the three oxidation products (Table 1).
  • 83
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    • 16
    • 16
  • 86
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    • note
    • + intermediate will be a sufficiently strong oxidant to abstract an H atom from cyclohexane.
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    • note
    • 55 a value of 6.5 hardly tells us anything about the nature of the oxidant.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.